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S1 TITAN 500 Alloy Calibration
S1 TITAN 500 Alloy Calibration
S1 TITAN 500 Alloy Calibration
0160)
Ti
Cr
Mn
Fe
Co
Ni
Cu
Nb
Mo
Pb
Analysis range, %
LLD (Fe pure)
SEC %
Typical accuracy: %
LLD - 0.25
160
0.02
0.03
0.05 - 1.8
162
0.01
0.02
0.02 - 18.1
90
0.03
0.03
0.1 - 2.0
133
0.03
0.05
69 - 100
N.A.
1.5
0.4
LLD - 8
146
0.25
0.03
LLD - 9.6
154
0.03
0.06
LLD - 0.4
98
0.01
0.03
LLD- 0.14
32
0.002
0.02
LLD - 4.8
33
0.01
0.04
LLD - 6
115
0.02
0.04
LLD-0.4
121
0.009
Ti
Cr
Mn
Fe
Co
Ni
Cu
Nb
Mo
Sn
Pb
Analysis range, %
LLD (AISI1045-200A)
SEC %
Typical accuracy: %
LLD - 0.01
160
0.002
0.03
0.05 - 9.5
157
0.04
0.02
0.02 - 8.7
100
0.05
0.03
0.1 - 2.0
176
0.05
0.05
69 - 100
N.A.
1.2
0.4
LLD - 8
71
0.09
0.2
LLD - 3.3
170
0.02
0.06
LLD - 1.5
88
0.02
0.03
LLD- 0.14
41
32
0.02
LLD - 8.5
35
0.02
0.04
LLD-350
71
0.006
LLD - 19
256
0.03
0.04
LLD-0.4
127
0.009
Ti
Cr
Mn
Fe
Co
Ni
Cu
Nb
Mo
Ta
0.05 - 2
271
0.03
0.03
0.05 - 0.3
139
0.03
0.02
0.02 - 26
117
0.2
0.03
0.1 - 2
148
0.08
0.05
30 - 95
N.A.
1.0
0.4
0.25 - 18
132
0.08
0.03
0.1 - 36
165
0.15
0.06
0.05 - 5.7
72
0.06
0.03
0.02 - 0.65
32
0.003
0.02
0.05 - 3.5
290
0.02
Ti
Cr
Mn
Fe
Co
Ni
Cu
Zr
Nb
Mo
Hf
Ta
0.05 - 3.2
235
0.06
0.03
0.05 - .2
109
0.03
0.02
0.02 - 30
207
0.5
0.03
0.02 - 2
67
0.06
0.05
0.02 - 80
92
0.5
0.4
0.1 - 18
120
0.03
0.03
32 - 100
N.A.
0.5
0.06
0.1 - 32.4
84
0.09
0.1
LLD-0.6
10
0.005
0.02 - 5.2
38
0.015
0.02
0.02 - 28
45
0.05
0.04
0.05 - 1.5
252
0.03
0.05 - 4.5
200
0.02
0.1 - 13.5
331
0.07
Ti
Cr
Mn
Fe
Co
Ni
Cu
Nb
Mo
Pb
Analysis range, %
LLD (pure Co)
SEC %
Typical accuracy: %
LLD-0.9
68
0.07
0.03
LLD-0.04
170
0.02
0.04
0.05 - 31
144
0.3
0.05
0.02 - 1.8
62
0.03
0.05
0.1 - 30
123
0.09
0.1
42 - 100
N.A.
0.6
0.3
0.1 - 35
96
0.3
0.13
LLD-0.25
25
0.045
LLD- 4.0
54
0.006
0.01
LLD - 10
34
0.04
0.04
0.1 - 15.1
295
0.1
0.1
LLD-0.4
90
0.009
Al
Ti
Fe
Cu
Zn
Pb
Bi
Analysis range, %
LLD (pure Zn)
SEC %
Typical accuracy: %
up to 25%
N.A.
N.A.
N.A.
LLD-0.015
50
0.003
0.006
0.1 - .5
128
0.005
0.01
LLD-2.5
200
0.03
0.05
68-100
N.A.
2
1
LLD-0.15
160
0.009
LLD-0.03
100
0.006
Ti
Cr
Mn
Fe
Co
Ni
Cu
Zn
As (KB1)
Zr
Ag
Sn
Pb (LB1)
Bi
Analysis range, %
LLD (pure Cu)
SEC %
Typical accuracy: %
LLD-0.26
120
0.0096
0.01
0.05 - 2.2
22
0.05
0.02
0.02 - 5.2
88
89
0.03
0.02 - 4.5
60
0.05
0.06
LLD-0.3
43
0.01
0.02
0.05 - 30
100
0.04
0.06
58 - 100
N.A.
0.8
1
0.1 - 40
59
0.2
0.2
0.02 - 0.25
546
0.02
0.03
0.02 - 0.41
44
0.01
0.02
0.1 - 3.0
150
0.009
0.02
0.1 - 10
225
0.08
0.1
0.1 - 10
178
0.17
0.2
LLD-0.05
100
0.01
0.03
Low Alloy
Tool Steel
Stainless Steels
Analysis range, %
LLD (AISI1045-200A)
SEC %
Typical accuracy: %
Nickels
Analysis range, %
LLD (pure Ni)
SEC %
Typical accuracy: %
Cobalts
Zincs
Coppers
Al, Si Bronzes
Analysis range, %
LLD (pure Cu)
SEC %
Typical accuracy: %
Light Alloys - Titaniums
Si
Ti
Cr
Mn
Fe
Co
Ni
Cu
Zn
As (KB1)
up to 4 %
N.A.
N.A.
N.A.
LLD-0.26
120
0.0096
0.01
0.05 - 2.2
22
0.05
0.02
0.02 - 5.2
88
0.018
0.03
0.02 - 4.5
60
0.065
0.06
LLD-0.3
43
0.01
0.02
0.05 - 30
100
0.04
0.06
58 - 100
N.A.
0.8
1
0.1 - 40
59
0.2
0.2
0.02 - 0.25
546
0.03
0.03
Zr
0.02 - 0.41
44
0.01
0.02
Ag
0.1 - 3.0
150
0.009
0.02
Sn
0.1 - 10
225
0.08
0.1
Sn
0.02 -4
150
0.07
0.1
Ta
LLD-1
90
0.006
0.02
W
LLD-0.5
65
0.01
0.04
Al
Ti
Cr
Mn
Fe
Cu
Zr
Nb
Mo
Pd
Analysis range, %
LLD (pure Ti)
SEC %
Typical accuracy: %
up to 10%
N.A.
N.A.
N.A.
68 - 100
N.A.
1.45
1.3
0.04 -15.0
296
0.1
0.15
0.02 -13.0
347
0.09
0.15
0.02 - 1.5
141
0.029
0.3
0.02 - 1.9
103
0.05
0.1
0.02 - 3.9
40
0.02
0.04
0.02 - 5
16
0.05
0.1
0.02 - 2
16
0.01
0.02
0.02 -6
18
0.07
0.1
0.03 -0.15
75
0.004
0.01
Al/Mg
Ti
Cr
Mn
Fe
Co
Ni
Cu
Zn
Zr
Analysis range, %
LLD (pure Mg)
SEC %
Typical accuracy: %
Balancee
N.A.
N.A.
N.A.
0.04 -0.25
131
0.01
0.03
0.02 -0.05
34
0.007
0.015
0.02 -0.3
52
0.006
0.02
0.01 -0.88
35
0.005
0.015
0.02 -0.65
19
0.021
0.04
0.02 -0.45
15
0.001
0.03
0.02 - 2.5
9
0.005
0.02
0.02 - 5
8
0.02
0.05
0.02 -7
6
0.03
0.05
LLD-0.15
7
0.001
0.01
Sn
LLD-0.05
44
0.007
0.02
Pb
0.02 -0.05
17
0.002
0.02
Bi
LLD-0.05
12
0.004
0.01
Nb
Full MultiMatrix FP
Al
up to 10%
N.A.
N.A.
N.A.
Ti
Analysis range, % LLD-100%
SEC % 0.1
Rh
Analysis range, % LLD-100%
SEC % 0.04
Pb (LB1)
0.1 - 10
178
0.17
0.2
Bi
LLD-0.05
100
0.01
0.03
Mo
Ru
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
Zr
LLD-100%
0.05
LLD-100%
0.3
LLD-100%
0.15
LLD-100%
0.6
LLD-100%
0.2
LLD-100%
0.2
LLD-100%
0.7
LLD-100%
0.3
LLD-100%
0.3
LLD-100%
0.1
LLD-100%
0.03
Pd
Ag
Cd
In
Sn
Sb
Hf
Ta
Re
Ir
Pt
LLD-100%
0.05
LLD-100%
0.1
LLD-100%
0.1
LLD-100%
3.00%
LLD-100%
0.3
LLD-100%
0.07
LLD-100%
0.1
LLD-100%
0.2
LLD-100%
0.7
LLD-100%
0.4
LLD-100%
0.13
Au
Pb
Calibration: FP based (with empirical corrections), with normalization based on BRUKER Intensity scaling when sample is smaller than mask
Analysis range: Concentration range covered by reference samples in the calibration of the application. Can be extened by 15% with FP based calibrations. Empirical calibrations should only be used within the range.
Lower Limit of Detection (LLD): The smallest concentration which can be detected.
a) In this document LLD is specified for a given matrix in three sigma 99.7% confidence level (3 sigma) and 60 second analysis time.
b) Individual elemental LLD's improve as a function of the square root of the analysis time.
Actual lower limit of detection range depends on several factors such as matrix interferences, overlapping elements, level of statistical confidence and testing time. Measurement of concentration close to the low
analysis range requires typically long measurement time > 60s
Standard Error of Calibration (SEC): Average error (deviation) between certified and XRF value of the samples used for the calibration expressed as an absolute value in weight %.
Typical accuracy: Typical average error within the analysis range when large set of reference samples are measured. Notice that error of the individual sample may differ
significantly from this value. Measurement time: 10s or less.
Bi
H
Li Be
Na Mg
He
B C N O
Al Si P
F Ne
S Cl Ar
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Fr Ra Ac
Phase 1: 40 kV, TiAl filter
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Th Pa U N p Pu Am Cm Bk Cf Es Fm Md No Lr