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Experiment 1 CHM 171 L
Experiment 1 CHM 171 L
ABSTRACT
Electrochemistry is a branch of chemistry that studies chemical reactions which take place in a solution at the
interface of an electron and an ionic conductor. In electrolytic cell, the quantitative determination of products is
governed by Faradays Law of Electrolysis. This law states that the quantity of electricity, that passes the solution
is directly proportional to the amount of electron transferred and that proportionality factor is called the Faradays
constant. The main apparatus used for this experiment is the Electrolytic analyzer equipment while the reagents
used are copper sulfate solution and concentrated nitric acid. The reduction of copper and oxidation of water
occurred when the electricity flowed in the aqueous solution. In the electrolysis the copper produced that was
deposited in the platinum and the bubbles formed showing that the oxygen was produced. A total of 6 runs were
made and all of these have given a value of Faradays constant by equation two equations of electricity measured
in Coulomb. The calculated Faradays constant for each run were close to each other and gives a percentage
error of more than 1%.
Keywords: electrochemistry, faraday, electron, copper, electricity
INTRODUCTION
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(Equation 1)
ItMW
mf
(Equation 2)
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Figure 3
.Electroanalyzer
First, the two working electrodes were weighed
then the copper sulfate was poured into the beaker.
The working electrodes, stirring rod and beaker were
placed to their respective positions and the power
was switched on along with the timer simultaneously.
After two minutes, the power of the electro analyzer
was switched off and the electrode with copper
deposits was weighed. Immediately as the timer
starts, the current control knob was adjusted to three
different settings. The electrodes were cleaned with
1:3 nitric acid and were dried in order to be used for
the next trial / run. There were 3 trials done for this
experiment.
RESULTS AND DISCUSSION
Reduction:Cu 2+(aq)+2 e
+++4
e
*
Oxidation:2 H 2O O 2(g)+4 H
The electrolyte solution used in the experiment was
copper (II) sulfate. The reduction of copper and
B. Faradays Constant
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Table 3.
Trial
Run
Faradays Constant
94742.7444
94835.3634
102657.58
97779.3708
94835.3634
104270.0031
Average
98186.737
% error
(TV=96500)
1.75%
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REFERENCES
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