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Kul 1 Introduction - Reguler
Kul 1 Introduction - Reguler
TEKNIK SIPIL
Cindy Rianti Priadi
Week I Semester 4 2014/2015
Introduction
Background
Positioning on chemistry
Why Chemistry?
zh.wikipedia.org
blogs.nvcc.edu
Why?
en.wikipedia.org
Diagnose
Why is this happening to the concrete?
Material Properties
Raw
Material
Pre-requisite
Advanced
chemistry
Built
Material
Material Protection
Introduced in
Advanced Chemistry
Deterioration
Material
Material Innovation
www.smooth-on.com
Questions to be answered
Course Structure
Advanced chemistry
Total credits
: 2 (two)
Kompetensi akhir:
mahasiswa diharapkan mampu
mengaplikasikan dan melaporkan
pengetahuan tentang kimia dasar dan
lingkungan untuk menyelidiki interaksi antara
material dengan lingkungannya
Untuk lengkapnya lihat BPKM
What it is not
Building physics
Advanced solid chemistry
- Mineralogy, cristallography
- Density, solidity, and porosity
- Thermal properties
- Mechanical properties (tensile, tension, etc)
Oxidation Reduction
Thermodynamics
Define
1. Oxidation and Reduction
2. Acid Base Reaction
3. What does it mean for a reaction to be
exotherm?
4. What do you know about entropy?
Galvanic Cell
8. Write the balanced net ionic equation, and
calculate Eo for the following galvanic cell: Al
(s) and Cu (s)
The half-reactions and their standard reduction
potentials are:
- Al3+ (aq) + 3 e- Al (s)
Eo = - 1,66V
- Cu2+ (aq) + 2 e- Cu (s) Eo = +0,34 V
Nernst?
9. Calculate the equilibrium constants for the
reaction involving copper and tin (solid and
ionic) using the standard reduction potential
table
EoCu2+/Cu = 0,34 V
EoSn2+/Sn=-0,14 V
Note:
-RT ln K = -nFEo
F = 96500 Coulomb/mol
R = 8.314 J/mol
Introduction to spontaneity
Discuss
What are their characteristics?
Messy is spontaneous
Disorder is fate
Iron Corrosion
Redox spontaneous
in room temperature
Spontaneity
A spontaneous change is any change that
happens freely in time without intervention.
It is important to know how a reaction can
occur spontaneously to avoid /make the
reaction occur?
What are the conditions for a reaction to take
place spontaneously?
Review
http://sd.keepcalm-o-matic.co.uk/i/keepcalm-and-study-chemistry-17.png
QUESTIONS?
-RT ln K = -nFEo
Ln K = nFEo/RT
= 2 *96500 Coulomb/mol*0,48 V/8,314 J/mol
K*298 K = 37
K= 1,7 * 1016