1. One hundred mililitres of the saturated solution of BaF2 , contains 17.5 mg of precipitation after evaporated.

Determine the Ksp for BaF2 , given that the relative atomic mass of Ba and F are 137 and 19.
2. Calculate the pH of the saturated solution of Al(OH) 3 , if Ksp for Al(OH)3 = 1,6. 10-35
3. The pH of saturated solution of Zn(OH)2 is 8, determine Ksp for Zn(OH)2.
4. Given that Ksp for AgCl = 1 x 10-10 determine the solubility of AgCl in:
a. water
b. Na2SO4 0.1 M
c. NaCl 0.01 M
d. CaCl2 0.005 M
e. AgNO3 0.01 M
5. The solubility of Mg(OH)2 in water is 2 x 10-4 M. Determine the solubility of Mg(OH)2 in :
a. Mg(NO3)2 0.01 M
b. NaOH 0.0001 M
c. The solution that has pH = 10
6. The solubility of AgX in AgNO3 0.001 M is 4 x 10-5 M. Determine :
a. Ksp for AgX
b. The solubility of AgX in water
7. Predict whether the following compounds are more soluble in acidic solution than in pure water
a. PbI2
b. AgCN
c. CaF2
d. BaSO4
8. The solubility of Al(OH)3 will ..... when pH of solution increase.
9. The solution of FeBr3 0.2 M is dropped by NH3 solution, determine the pH when start precipitation of Fe(OH) 3,
Ksp for Fe(OH)3 = 1.6 x 10-36 (assume that the volume of mixture doesnt change by ammonia addition)
10. Ksp for BaSO4 = 1 x 10-10. If barium hydroxide that its pH= 11 is mixed with sulfuric acid that its pH = 3 so the
volume of mixture 1 Litre.
a. predict ! Should precipitation occurs?
b. if precipitation occurs, calculate the mass of BaSO 4 that precipited (Mr=233)
c. calculate the concentration of Ba2+ and SO42- in solution!.
11. One litre of MgCl2 0.0001 M is added drop by drop with KOH 2 M, if Ksp for Mg(OH) 2 = 9 x 10-12, how many
drops of KOH required to start precipitation of Mg(OH) 2 ?
12. Tetapan hasil kali kelarutan dari perak azida, AgN3, timbal azida, Pb(NO)3, dan stronsium fluorida, SrF2 adalah
sama pada suhu yang sama. Jika kelarutannya dinyatakan dengan s, maka ....
13. Hasil kali kelarutan dari Mg(OH)2 adalah 1,2x10-11. Bila larutan MgCl2 0,2 M dinaikkan pH-nya dengan jalan
penambahan NaOH, maka endapan akan mulai terbentuk pada saat pH larutan....
14. Ke dalam tiga gelas kimia yang berbeda terdapat 100 mL larutan KCl (10 -3 mol), K2CrO4 (10-3 mol), dan K2SO4
(10-3 mol). Masing-masing gelas kimia ditambah dengan 100 mL larutan Pb(NO3)2 2x10-8 mol. Jika diketahui Ksp
PbCl2 = 1,7x10-5, Ksp PbCrO4 = 2x10-14, Ksp PbSO4 = 2x10-8, endapan yang terjadi adalah....
15. Kedalam masing-masing larutan yaitu 500 mL CaCl2 0,001 M, 500 mL SrCl2 0,001 M, dan 500 mL BaCl2 0,001 M
ditambahkan 500 mL K2SO4 0,001 M. Jika Ksp CaSO4 = 2 x 10-5, SrSO4 = 3 x 10-7, BaSO4 = 1x 10-10, maka secara
teoritis endapan zat yang akan terjadi adalah....