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Academic Writing Audit-1
Academic Writing Audit-1
The 5th Sriwijaya International Seminar on Energy and Environmental Science & Technology
Palembang, Indonesia
September 10-11, 2014
JalanRayaPalembangPrabumulihKm32IndralayaOISumateraSelatan
Indonesia
Correspondingauthor:haryati_djoni@yahoo.co.id
ABSTRACT
Hydrogenisviewedasoneofthemostpotentialenergysourceinthefuture.Oneofmethodstoproduce
hydrogenisbyelectrolysisofwater.Variablesthatwasappliedinthisworkwereelectricalcurrent(0.5A
and0.9A),pH(13.47and13.69),andelectrolyteadditions(namelyNaOHandKOH)withprocessing
timesfor30minutes.Theresultofthisworkwerevariationsofelectricalcurrentat0.9A,pHat13.69and
electrolyteNaOHisat278.394Lwithvolumerate154.663mL/sproducedmostamountofhydrogen,
whereasconditionof0.5A,pH13.47andelectrolyteKOHwas75.122Lwithvolumerateof41.734mL/s
yieldedthelowestamount.
Keywords:Hydrogen,ElectrolysisofWater,Current,pH,Electrolyte
gasification,partialoxidationofoil,
thermochemicalprocess,fermentation,andthe
electrolysisofwater(Winter,2009).Electrolysis
ofwaterisanenvironmentallyfriendlywayto
producehydrogenwithoutemissions.Inthis
work,electrolysisofwatertoproducehydrogen
usedvariationsofelectricalcurrent(0.5Aand
0.9A),pH(13.47and13.69)andelectrolyte
addition(NaOHandKOH).
1. INTRODUCTION
Astheworldpopulationincreases,soisthe
energyconsumption.However,tomet1theenergy
demand,mostcountriesutilizesfossilfuelbased
processes,thatarerelativelyinefficientand
environmentallyunfriendly.Alternativeenergy
isneededtobedevelopedtoovercomeproblems
incurredbytheconsumptionandusageoffossil
fuel.Oneoftheseoptionsisbyusinghydrogen
asnewenergysource.Thereareseveral
considerationsthataretakenintoaccountto
choosehydrogenasanalternativeenergy
includes:anoverwhelmingamountthatcanbe
obtainedeasily,thepotentialhighenergycontent
comparedtootherfuels,whichisequalto120
MJ/kg.Thisamountisalmosttwotimesas
muchastheenergycontentofthegasoline,
whichaccountsonly45.6MJ/kg(KellyYong
etal.,2007).
Thereareseveralmethodsforproducing
hydrogen:steamreformingofnaturalgas
(SMR),thermalcrackingofnaturalgas,coal
2. METHODS
2.1. Preparation of Electrolyte Solution
ElectrolytesolutionsusedwereNaOHand
KOHwhichwerepreparedbydissolvingthe
solidcompoundinto2500mLofdistilledwater
toobtainsolutionswithpH13.47and13.69.
2.2. Electrolysis Process
Electrolytesolutionwasentered2intothe
reactorintothecenterofthereactor3.Electrolysis
processwasundertakenfor30minutes.
Measurementsoftheparameterswereconducted
every5minutes.Theappliedcurrentwere0.5A
92
Proceedings of
The 5th Sriwijaya International Seminar on Energy and Environmental Science & Technology
Palembang, Indonesia
September 10-11, 2014
Whenthehydrogenmoleobtained,thenthe
volumeofhydrogengascanbeobtainedby
usingidealgasequation:
PV=nRT
Description:
P=pressure(atm)
V=volumeofgas(L)
n=numberofmoles(mol)
R=theidealgasconstant0.082(L.atm/molK)
T=temperature(K)
and0.9A.Duringthisprocess,hydrogengas
wouldappearatthecathodewhileoxygengasat
theanodeintheformofgasbubbles.Produced4
hydrogenandoxygenproducedwerecollectedin
thegasstorageafterwards.Equipmentsetupof
electrolysisprocessisshowninFigure1.
3. RESULTS
a. Effects of current to hydrogen production
Effectsofcurrenttohydrogenproductionis
showninFigure25:
>
d
Figure 2. Effect of current to hydrogen
production in NaOH solution pH 13.47
2.3. Analysis
Analysisofhydrogenproductionweredone
bycalculatingwatervolumereduction5duringthe
electrolysisprocess.Stagesoftheanalysiswere:
1.CalculationofWaterMassReduction.
Reducedmassofwatercanbedetermined
throughtheequation:
m= xV
Where: H2O(30oC)=995.647kg/m3(Perry
andGreen,1997)
2.CalculationofWaterMoles
>
Molesofwatercanbeobtainedusingthe
followingequation:
whereMWisMolecularWeightofwater(18
g/mol)
3.CalculationofHydrogenMoles
Molesofhydrogenwereobtainedfromthe
stoichiometricratiothroughthefollowing
stoichiometricequation:
2H2O 2H2+O2
4.HydrogenVolumeCalculation
93
Proceedings of
The 5th Sriwijaya International Seminar on Energy and Environmental Science & Technology
Palembang, Indonesia
September 10-11, 2014
>
Fromtheaforementionedreactionsatthe
electrodes,theincreasingofcurrentwould
increasehydrogenproduction.Underthe
conditionofpH13.47,electrolyteNaOHwith
current0,5Ahydrogenproduced101,636L
withvolumerate56,464mL/s.Atthesame
conditionswithcurrent0,9A,hydrogen
productionis170,130Lwithvolumerate94,516
mL/s.
>
,
/
dtD
>
Figures25showthatincreasingcurrent
wouldmakepotentialdifferencebecomehigher,
accordingtoformula:
V=IR
where:
V=potentialdifference(Volt)
I=Current(A)
R=resistance(ohm)
Potentialdifferencewouldcausemigration
ofioncomingfromdissosiation12ofNaOHand
KOHinwater,wherebyionNa+andK+would
movetocathodeandOHtoanode.The
migrationsofionwouldmakereduction
oxidationreactionwherebyincathodewater
reducedtohydrogenandinanodeionOHwill6
beoxidizedtobeoxygen.
Cathode:4H2O+4e 2H2+4OH
Anode:4OH O2+2H2O+4e
94
Proceedings of
The 5th Sriwijaya International Seminar on Energy and Environmental Science & Technology
Palembang, Indonesia
September 10-11, 2014
volumerate56.464mL/s.Meanwhileat0.9A,
thehydrogenproductionatpH13.69is278.394
Lwithvolumerate154.663mL/sandpH13.47is
170.130Lwithvolumerate94.516mL/s.
thegreaterpHconditionindicatesthemostOH
ionsdissolved.Itcanbedeterminedfromthis
equation:
pH=14+log[OH]
IfthemosttotalOHiondissolved,the8little
resistancecausedbywater,sothatelectronswill
movequicklyandreductionoxidationreaction
(redox)occurred.Asaresult,waterwouldbe
reducedatcathodeproduceshydrogenwhileOH
ionwill13beoxidizedtooxygenatanode.
>
Ecell=EreductionEoxidation
NahaspotentialcellvaluehigherthanK,
causingNatobe9easilyreducedandmigrateto
cathodetoproducehydrogen.Electrolysis
processwithelectrolyteNaOHwould10
subsequentlyproducemorehydrogenthanKOH.
d
Figure 8. Effect of pH to hydrogen production
>
>
E K,
<K,
,
s
>
E K,
<K,
InpH13.69,additionsofNaOHandKOH
increasedhydrogenproduction,comparedtopH
condition13.47.Fromthemeasurementof
NaOHsolution0.5A,hydrogenproductionat
pH13.69is114.893Lwithvolumerate63.829
mL/s,higherthanatpH13.47is101.636Lwith
d
Figure 11. Effect of Electrolyte to Hydrogen
Production at 0.5 A pH 13.69
95
Proceedings of
The 5th Sriwijaya International Seminar on Energy and Environmental Science & Technology
Palembang, Indonesia
September 10-11, 2014
Carolina,M.,Harto,A,W.,&Kusnanto.
Pengaruh
>
[3]
[4]
E K,
s
<K,
[5]
[6]
d
Figure 12. Effect of Electrolyte to Hydrogen
Production at 0.9 A pH 13.47
[7]
>
[8]
E K,
s
[9]
<K,
[10]
d
[11]
[11]
[12]
4. CONCLUSION
1.Currentinfluenceshydrogenproduction
wherebyhighercurrentwillincrease
hydrogenobtained.
2.ThegreaterpHwillincreasethehydrogen
obtained,
3.ElectrolyteNaOHproducehydrogenhigher
thanelectrolyteKOHatthesameconditions.
4.Thehighesthydrogenobtainedatcondition
current0.9A,pH13.69,andelectrolyte
NaOHis278.394Lwithvolumerate11
154.663mL/s.
5.Thelowesthydrogenobtainedatcondition
current0.5A,pH13.47andelectrolyteKOH
is75.122Lwithvolumerate41.734mL/s
[13]
[2]
661666.
Mulyono,P.(2009). Prospek dan Potensi Hidrogen
sebagai Energi Terbarukan.Yogyakarta:Universitas
GajahMada.
Muradov,NazimZ.(1995). Production of Hydrogen by
Thermocatalytic Cracking of Natural Gas. Annual
Report.
PerryandGreen(1997);HRPerry,DWGreen;Perry's
ChemicalEngineersHandbook(7thedition),
Vol.26McGrawHill,NewYork,USA(1997)7884.
Shahid,M.dkk.(2010). Enhancement of Hydrogen by
Laser Focusing during Plasma Electrolysis of Water .
OptoelectronicsandAdvancedMaterialsRapid
CommunicationsVol4:16701675
Steinberg,M. Hydrogen Production from Fossil Fuels.
EnergyCarriersandConversionSystem
Winter,C,J.(2009). Hydrogen energy d Abundant,
efficient, clean: A debate over the energy-system-ofchange.InternationalJournalofEnergy34:152
Correction:
1. Meet
2. Fed
3. Centerofthereactor
4.
5. Reductionofvolumwater
6. Would
7. More
8. A
9. Is
10. Wouldbe
11. Volumerate
12. Dissociation
13. Would
14. Additions
REFERENCES
[1]
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