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MAJOR TEST (MT)

Code

(JEE ADVANCED PATTERN)


TARGET : JEE (MAIN+ADVANCED) 2016

PAPER-2

COURSE : VIJETA (JP)

P18A-15

Date : 30-12-2015

Time: 3 Hours

Maximum Marks : 240

Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
1.
2.
3.
4.
5.
6.

The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
The question paper CODE is printed on the right hand top corner of this sheet.
Use the Optical Response Sheet (ORS) provided separately for answering the question.
Blank spaces are provided within this booklet for rough work.
Write your Name and Roll Number in the space provided on the below cover.
After the open booklet, verify that the booklet contains all the 72 questions along with the options are legible.

QUESTION PAPER FORMAT AND MARKING SCHEME :


7.

The question paper has three parts : Mathematics, Physics and Chemistry. Each part has three sections.

8.

Carefully read the instructions given at the beginning of each section.

9.

Section 1 contains 4 multiple Choice question with one or more than one correct option.
Marking scheme: +4 for correct answer, 0 if not attempted and 2 in all other cases.

10.

Section 2 contains 3 "paragraph" type questions. Each paragraph describes an experiment, a situation or a problem. Two
multiple choice questions will be asked based on this paragraph. Only one option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and 2 in all other cases.

11.

Section 3 contains 14 questions. The answer to each question is a single digit integer ranging from 0 to 9 (both inclusive).
There are 14 Questions & you have attempt any 10 Questions. If a student attempts more than 10 questions, then
only first 10 questions which he has attempted will be checked.

Marking scheme: +4 for correct answer, 0 in all other cases.


OPTICAL RESPONSE SHEET :
12.
13.
14.
15.

Darken the appropriate bubbles on the original by applying sufficient pressure.


The original is machine-gradable and will be collected by the invigilator at the end of the examination.
Do not tamper with or mutilate the ORS.
Write your name, roll number and the name of the examination centre and sign with pen in the space provided for
this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble
under each digit of your roll number.

DARKENING THE BUBBLES ON THE ORS :


16.
17.
18.

Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
Darken the bubble COMPLETELY.
Darken the bubble ONLY if you are sure of the answer.

19.

The correct way of darkening a bubble is as shown here :

20.
21.

There is NO way to erase or "un-darkened bubble.


The marking scheme given at the beginning of each section gives details of how darkened and not darkened
bubbles are evaluated.

NAME OF THE CANDIDATE : ..


ROLL NO. : ..
I have read all the instructions
I have verified the identity, name and roll number
and shall abide by them
of the candidate.
------------------------Signature of the Candidate

------------------------Signature of the Invigilator

Resonance Eduventures Ltd.


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DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

GENERAL %

MATHEMATICS

SECTION 1 : (Maximum Marks : 16)

This section contains FOUR questions


Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
2 In all other cases

1.

If |z| = 1, then

z 1
does not lie on
z

(A) circle (x 1)2 + y2 = 1


(B) a parabola with focus (1, 0) and length of latus rectum 1.
(C) circle with centre (2, 0) and radius 2.
(D) a parabola with focus (1, 0) and length of latus rectum 1.

2.

a b c
If abc = p and A = c a b and AA' = then a, b, c are roots of the equation
b c a
3

(A) x p = 0

(B) x x p = 0

(C) x + x p = 0

(D) x + 3x + 3x p = 0

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P2JPMTADV301215C0-1

MATHEMATICS

PART : I MATHEMATICS

3.


Let f : R , be defined as f(x) = tan1
4 4

(are) TRUE ?
(A) f(x) is not surjective.
(B) f(x) is continuous but non-derivable on R.
(C)

lim f(x) =
x

12

(D) f(x) is both even and non-periodic function.

4.

Three points are selected on the curve 8x3 + 27y3 + 18xy = 1 such that they form an equilateral
triangle. Which of these is/are INCORRECT ?
1
1
(A) One of the vertices is , .
3
2

(C) Area of triangle is

3
.
4

1 1
(B) One of the vertices is , .
2 3

(D) Centroid of triangle is (0, 0).

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P2JPMTADV301215C0-2

MATHEMATICS

MATHEMATICS

2 | x |

. Which of the following statement(s) is


2 | x |

SECTION 2 : (Maximum Marks : 24)

This section contains THREE paragraphs


Based on each paragraph, there will be TWO questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct
For each question, darken the bubble corresponding to the correct option in the ORS
Marking scheme :
+4 If only the bubble corresponding to the correct option is darkened
0 If none of the bubbles is darkened
2 In all other cases
Paragraph for Question Nos. 5 to 6
Let A, B, C, D, E represent vertices of a regular pentagon ABCDE. Given the position vectors of

these vertices be a , a b , b , a and b respectively

5.

AD
is equal to
BC

The ratio

2
2
(C) cos
5
5

The area of pentagon ABCDE is k | a b |, then k is equal to
(A) 1 cos

6.

(A) 4 cos
(C) cos

3
5

(B) 1 + 2cos

4
+ cos
5
5

(B) 1 + cos

2
3
4
+ cos
+ cos
5
5
5

(D) 1 cos

2
5

2
4
+ cos
5
5

(D) 2 + 2 cos

2
5

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MATHEMATICS

MATHEMATICS

MATHEMATICS

n numbers are selected from the numbers 0, 1, 2, ., 8 randomly with repetition being
Now answer the following:

7.

The probability that at least one 0 is selected, is

1
(A)
9
8.

allowed.

8
(B)
9

8
(C) 1
9

1
(D) 1
9

If three numbers are selected from the given set. It was found that even number were selected
then the probability that no multiple of 3 is selected, is

3
(A)
5

2
(B)
3

2
(C) 1
3

3
(D) 1
5

Paragraph for Question Nos. 9 to 10


Let F1(3, 0), F2(3, 0) be focii and 3x + 4y
9.

10.

Eccentricity of the ellipse is


25
(A)
(B)
281

15
281

Radius of director circle of ellipse is


337
337
(A)
(B)
5
25

137 = 0 be a tangent to ellipse.

(C)

(C)

1
2

337
5

(D)

(D)

2
5

337
36

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MATHEMATICS

Paragraph for Question Nos. 7 to 8

SECTION 3 : (Maximum Marks : 40)

This section contains FOURTEEN questions

The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive

There are 14 Questions & you have attempt any 10 Questions. If a student attempts more
than 10 questions, then only first 10 questions which he has attempted will be checked.

For each question, darken the bubble corresponding to the correct integer in the ORS

Marking scheme :
+4 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
0 In all other cases

11.

a b
2
6
Suppose a matrix A satisfies A 5A + 7= 0, If A = aA + b, find the value of
(where [.]
150
denotes greatest integer function)

12.

If sum of the series 1.n + 2(n 1) + 3(n 2) + 4(n 3) + ........ + (n 1) . 2 + n . 1 is

n(n a)(n b)
c

, then find the value of a + b + c.

13.

Number of polynomials of the form x3 + ax2 + bx + c that are divisible by x2 + 1 where


a, b, c {1,2,....9,10} is equal to 2k then k is equal to

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MATHEMATICS

MATHEMATICS

14.

If 212 . nC0 . nC12 211 . nC1 .

n1

C11 + 210 . nC2 .

n2

C10 ..... + nC12 .

n12

C0 = nCk , n N, n > 12,

where k is a fixed natural number n, then find the value of k/2.

15.

All the three vertices of an equilateral triangle lie on the parabola y = x2 and one of its sides has a
slope of 2. If sum of x-coordinates of the three vertices of triangle is

16.

, then value of is
11

Two whole numbers are randomly selected & multiplied. If the probability that the units place in
their product is "Even" is p & the probability that the units place in their product is "Odd" is q, then
find the value of

17.

p
.
q

If ( z1 , z2 ) and ( z3 , z4 ) are two pairs of non zero conjugate complex numbers.

z
z k
If arg 1 + arg 2 =
, then find the value of k.
2
z4
z3

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MATHEMATICS

MATHEMATICS

MATHEMATICS

18.

19.

If im

t2

te dt
e 4x

= then find the value of 2

Sum of the values of k for which planes kx + 4y + z = 0, 4x + ky + 2z = 0 and 2x + 2y + z = 0


intersect in a straight line is

20.

If a, b are two unit vectors such that a a b c , where | c | = 2, then value of a b c is

21.

If the differential equation of a curve, passing through 0, and (t, 0) is


4

dy
e x
e t
dy

cos y
e x + sin y e x
then find the value of t . e
= e
dx
dx

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P2JPMTADV301215C0-7

MATHEMATICS

2x

22.

If the equation of common tangent to the parabola x2 y + 2 = 0 and ellipse 4x2 + 9y2 = 36 is
y = k, then value of k is

8 ) then cos z = ?

23.

If z = i loge(3 +

24.

Let f : R R be a twice differentiable function satisfying f(2) = 1, f '(2) = 4 and

(3 x) f"(x) dx = 7,
2

then the value of (f(3) 3) is equal to

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MATHEMATICS

MATHEMATICS

PHYSICS

SECTION 1 : (Maximum Marks : 16)


This section contains FOUR questions
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct

For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS

Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
2 In all other cases

25.

Three men P, Q & R are standing at corner A, B & D of square ABCD of side 8 m. They start
moving along the track with constant speed 2 m/s, 10 m/s & 4 m/s respectively.

(A) P & Q will meet 3 sec after start.

(B) P & R will meet 4 sec after start.

(C) P & R will meet at point B.

(D) P & R will never meet.

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PHYSICS

PART - II : PHYSICS

In given circuit key is closed at t = 0. If Inductor is ideal then select correct statements :
R1
E

R2

R3

27.

(A) At t = 0 the current through cell is

E
R1 R 2

(B) At t = 0 the current through cell is

E
R1 R 2 R3

(C) At t the current through cell is

E
R1 R3

(D) At t the current through cell is

E
R1 R 2

A disk of mass 3M and radius R is made by two semicircular disks of mass M and 2M
(as shown in figure) if x,y and z are moment of inertia about x, y and z axis respectively then.
y

R
M

2M
x

(A)

Ix

3MR 2
4

(B)

3
I x MR 2
2

(C)

3
I z MR 2
2

(D)

I z 3MR 2

Space for Rough Work

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P2JPMTADV301215C0-10

PHYSICS

PHYSICS

26.

28.

An iron block and a wooden block are positioned in a vessel containing water as shown in the
figure. The iron block () hangs from a massless string with a rigid support from the top while the
wooden block (W) floats being tied to the bottom through a massless string. If now the vessel
starts accelerating upwards

(A) tension in the string 1 will increase.


(B) tension in both the strings will increase
(C) tension in the string 2 will decrease
(D) tension in the string 2 will increase
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PHYSICS

PHYSICS

SECTION 2 : (Maximum Marks : 24)

This section contains THREE paragraphs

Based on each paragraph, there will be TWO questions.

Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct

For each question, darken the bubble corresponding to the correct option in the ORS

Marking scheme :
+4 If only the bubble corresponding to the correct option is darkened
0 If none of the bubbles is darkened
2 In all other cases

Paragraph for Questions 29 and 30


Two particles A and B are performing simple harmonic motion with amplitude A0 about their mean
positions x = 0 and x = A0 respectively. Both have time period T. At time t = 0 the particle A is at x
=

29.

3A 0
and moving towards +ve x axis which B is at x = A0 and moving towards +ve x-axis :
2
t=0
A
B
x
3A
0
x = A0
x=0
x=
2

Find minimum and maximum reparation between A and B :


(A) 0 & 2A0

30.

(B) A0 & 2A0

(C) A0 & 3A 0

(D) 0 & A0

Find the time at which minimum separation occurs for the first time :
(A)

11T
12

(B)

5T
2

(C)

77
12

(D) None of these

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PHYSICS

PHYSICS

PHYSICS
2

A long string having a cross-sectional area 0.80 mm and density 12.5 g/cm is subjected to a
tension of 64N along the x-axis. One end (at x = 0) of this string is attached to a vibrator moving in
transverse direction at a frequency of 20 Hz. At t = 0, the source is at a maximum displacement y =
1.0 cm.

31.

Find the speed of the wave travelling on the string


(A) 20 m/s

32.

(B) 10 m/s

(C) 80 m/s

(D) 40 m/s

Write the equation for the wave


(A) y = (1.0 cm) cos 40s1 t m1 x
2


(B) y = (1.0 cm) sin 40s1 t m1 x
2


(C) y = (1.0 cm) cos 40s1 t m1 x
4


(D) y = (1.0 cm) cos 20s1 t m1 x
4

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PHYSICS

Paragraph for Questions 31 and 32

PHYSICS

A brilliant student of physics Mr. Naraynan visited you at your house. After completing the formalities
of tea you started talking to him on the electrical measurement. He told you that he has devised a
method to find unknown resistance using potentiometer and asked you to check the next day in the
lab. You are impressed . Next day you check his design experimentally. The circuit is shown in Fig
When resistance between terminal PQ (= 5) is in the circuit, balance point is obtained at X1 so that
AX1 = 1 and when galvanometer is connected at R, the balance point is obtained at X2 so that
AX2 = 2.
1
2
X2
1
X
1
5 G
G
R
Q X
2

A
P

33.

Unknown resistance X =

l
(A) 5 2
l1
34.

l l
(B) 5 2 1
l1

l
(C) 5 1
l2

l l
(D) 2 1
l2

When 1 and 2 are interchanged (keeping same polarity) no balance point was obtained when
galvanometer is connected at R. One concludes
(A) 1 > 2

(B) 2 > 1

(C) X > 5

(D) X < 5

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PHYSICS

Paragraph for Questions 33 and 34

SECTION 3 : (Maximum Marks : 40)


This section contains FOURTEEN questions
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive

There are 14 Questions & you have attempt any 10 Questions. If a student attempts more
than 10 questions, then only first 10 questions which he has attempted will be checked.

For each question, darken the bubble corresponding to the correct integer in the ORS

Marking scheme :
+4 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
0 In all other cases

35.

The given circuit in steady state. Change on capacitor is qs = 16C. If the emf of the battery 6k volt
then find the value of k.
2

4F

D
+

36.

A metal surface has work function 1.1 eV. Photon of wavelength 6200 is absorbed by an
electron which makes a collision with lattice before coming to surface. If it is observed that it
comes out with kinetic energy 0.4 eV then percentage loss of kinetic energy during collision with
lattice is x% (approximately). Then find x/5:

37.

A projectile is projected with initial speed 10 3 m/s at an angle of 60 with the horizontal. Find the
time after which its velocity becomes perpendicular to initial velocity.
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PHYSICS

PHYSICS

38.

A pendulum bob 0.5 kg is raised to a height of 15 cm before it is released. At the bottom of its
path, it makes a perfectly elastic collision with a 1 kg mass that is connected to the horizontal
spring of spring constant 1.5 N/m. Maximum compression in spring is

280
cm. Find the value of x.
x

m1
h

39.

m2

One end of an iron chain is fixed to a sphere of mass M = 10 kg and of diameter D = 0.3 m
3

(the volume of such a sphere is V = 0.0141m ), while the other end is free. The length of the
chain is 3 metre and its mass m is 9 kg. The sphere with the chain is in a water reservoir (see fig.)
The length of floating part of chain is approximately

40.

water

meter. Find

iron

7.85

Two particles of different masses projected from a tower with same speed horizontally but in
opposite direction. One particle of mass 3kg follows a path y =
also follows a path y =

x2
and C.O.M. of the system
20

5 2
x in the same direction as 3kg particle. Then find unknown mass (in kg)
4

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PHYSICS

PHYSICS

41.

A long capillary glass tube of uniform diameter of 1mm is filled completely with water and then held
vertically in air. It is now opened at both ends. Find the length of the water column remaining in the
glass tube. Surface tension of water is 0.075 N/m. (g = 10 m/s2) and density of water is 103 Kg/m3.

42.

An LCR series circuit with 100 resistance is connected to an AC source of 200 V and angular
frequency 300 radians per second. When only the capacitance is removed, the current lags behind
the voltage by 60. When only the inductance is removed, the current leads the voltage by 60.
The average power dissipated in LCR circuit is 50x watts. Find the value of x.

43.

A conductor carries a current of 6.0 A along the closed path abcdefgha involving 8 out of the
12 edges of a cube of side of 10 cm as shown in figure. If the system is in a uniform field of

B (100 tesla) i , then find the magnitude of torque on the system (in N.m.) at this instant :

44.

In the circuit shown steady state is already reached. EMF of the cell v = 12 volt. Now the
inductance is suddenly doubled. The potential difference across 'R' just after this is :

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PHYSICS

PHYSICS

45.

Two thin symmetrical lenses of different nature have equal radii of curvature (R = 20 cm) of all
faces. The lenses are kept in contact and immersed in water (= 4/3). The difference in the
refractive indices of the two lenses is 5/9. The focal length of the system is f in cm. Find the value
of

46.

f
.
3

A liquid of density 0.8 gm/cm3 flows through a thermally insulated container at the rate of
5 cm3/sec. Heat is added to the liquid by means of a 210W heating coil and a temperature
difference of 15C is established in steady state between inflow and outflow. If specific heat of
liquid is

47.

x
cal/gm-C. Then find the value of x ? (1 cal = 4.2 J)
6

The emissivity of tungsten is approximately 0.35. A tungsten sphere 1 cm in radius is suspended within
a large evacuated enclosure whose walls are at 300 K. What power input is required to maintain the
sphere at a temperature of 3000 K if heat conduction along the supports is neglected ? Express your
answer in kW after rounding off the integer. Take =

48.

17
213
10 8 S.I. units and =
3
68

In Bohr's model, If 'B' and 'a' denote the magnetic field at centre and centripetal acceleration,
where electron is in nth orbit, then it is found that

a n

, where z = atomic no., then + is :


B z

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PHYSICS

PHYSICS

CHEMISTRY

Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION 1 : (Maximum Marks : 16)

This section contains FOUR questions


Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
2 In all other cases

49.

If m1 g of benzoic acid is dissolved in m2 g of benzene solvent, boiling point of the solution is

observed to be increased by TC with respect to solvent. If it is known that benzoic acid


dimerises in benzene solvent upto an extent of y %, then molecular weight of benzoic acid
(observed) in this case from given data (M) can be obtained from the following relation(s) :
(Given that Kb for benzene = X K Kg/mol)

1 y
m1 M
(A) T 1 1
X
m2 1000
2 100
1
m1 M
(B) T 1 1 y X
m2 1000
2
1 y
m1 M
(C) T 273.15 1 1
X
m2 1000
2 100
(D) T = X

m1 M
m2 1000

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CHEMISTRY

PART : III CHEMISTRY

CHEMISTRY

Which of the following will release energy upon addition of an electron ?

(A) O (g)

(B) N (g)

(C) Na (g)

(D) K (g)

H
CH3MgBr
CH3MgBr
CH3MgBr
H3O
(w)

(x)
(y)
(z)
)
)
)

51.

(1eq

(1eq

(1eq

Which of the following is/are correct ?


H

OMgBr

(A) x =

CH3

(B) z =

MgBr

CH3
MgBr

BrMgO

HO

CH3

CH3
OH

(C) y =

(D) w =

CH3

MgBr

52.

Which of the following reactions can give aldehyde.


HgSO 4
(A) CH3CCH

dil. H2SO 4

(B) (C6H5CH2)2Cd + 2CH3COCl

CH3

(C)

1. CrO2Cl2

2. H3O

1. SnCl2 HCl
(D) CH3CN

2. H3O

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CHEMISTRY

50.

CHEMISTRY

This section contains THREE paragraphs

Based on each paragraph, there will be TWO questions.

Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct

For each question, darken the bubble corresponding to the correct option in the ORS

Marking scheme :
+4 If only the bubble corresponding to the correct option is darkened
0 If none of the bubbles is darkened
2 In all other cases

Paragraph for Question Nos. 53 to 54


An inorganic compound (A) loses water of crystallization on heating. It gives golden yellow flame
test.
Its aqueous solution, (A) :
(a) Gives white turbidity with HCl.
(b) Decolourizes 2 in K solution.
(c) Gives white precipitate with AgNO3 which turns yellow, brown & finally black on standing.
Now answer the following questions.
53.

Select correct statement(s) regarding compound (A) :


+

(A) It contains Na cation

(B) It is water soluble

(C) It is a reducing agent

(D) It turns red litmus blue

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CHEMISTRY

SECTION 2 : (Maximum Marks : 24)

CHEMISTRY

When added to Pb(NO3)2, (A) produces a white precipitate (P) that turns black on boiling due to
(Q). (Q) turns white on adding (R). (R) may be :
(A) Na2SO3

(B) Conc. HNO3

(C) Conc. HCl

(D) H2O2

Paragraph for Question Nos. 55 to 56


ZnS crystallizes in zinc blende as well as wurtzite structure.
On the basis of this, answer the following questions.
55.

Select the correct statement(s) regarding zinc blende structure :


2+

ions form fcc lattice while S

2+

ions as its next nearest neighbours.

(A) It can be said that Zn


2+

(B) A Zn

(C) A S

ion has 12 Zn
2+

ion has 4 Zn

ions occupy alternate tetrahedral voids.

ions as its nearest neighbours with

3a
as the distance between centre
2

of ions.
(D) None of these

56.

a
from that face passes
4

A plane parallel to one of the faces of a zinc blende unit cell at a distance
2+

through the centres of ____ Zn

ions & ____ S

ions. Which of the following numbers can be

used to fill the two blanks ?


(A) 4

(B) 0

(C) 6

(D) 2

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CHEMISTRY

54.

CHEMISTRY

The azoproducts obtained have extenderd conjugated system having both the aromatic rings
joined through the N=N- bond. These compounds are often coloured and are used as dyes.
Benzene diazonium chloride reacts with phenol to form P-hydroxyazobenzene. This type of
reaction is known as coupling reaction.
57.

Which of the following is/are correct statements:


(A) Coupling reaction is an example of electrophilic substitution reaction.
(B) Azo compounds are coloured due to extended conjugation
(C) Phenol gives coupling reaction in mild basic medium
(D) Aniline gives coupling reaction in mild basic medium

58.

Find correct statement :


(A) ArN
2 with

G can undergo azocoupling reaction if G = NH2, NMe2, OH

(B) If EDG (electron donating group), is attached to

G then it will make coupling reaction

faster.
(C) For the coupling of phenol, mild acidic medium is most suitable.
(D) EWG (electron withdrawing group) at the ring of diazonium ion increases rate of coupling
reaction.

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CHEMISTRY

Paragraph for Question Nos. 57 to 58

CHEMISTRY

This section contains FOURTEEN questions

The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive

There are 14 Questions & you have attempt any 10 Questions. If a student attempts more
than 10 questions, then only first 10 questions which he has attempted will be checked.

For each question, darken the bubble corresponding to the correct integer in the ORS

Marking scheme :
+4 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
0 In all other cases

59.

14

A saturated solution in AgA (Ksp = 3 10


10

10

14

) and AgB (Ksp = 1 10


+

) has conductivity of 375

S cm . Limiting molar conductivity of Ag and A are 60 S cm mol and 80 S cm mol

respectively. What will be the limiting molar conductivity of B (in S cm mol ) ?


Report your answer after dividing it by 100 and then rounding it off to the nearest whole number.

60.

For the complex with formula [Pt(gly)2BrCl] :


Total number of stereoisomers = 'a'
Total number of geometrical isomers = 'b'
Report your answer as (a b).

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CHEMISTRY

SECTION 3 : (Maximum Marks : 40)

CHEMISTRY

20 % of surface sites are occupied by N2 molecules. Number of surface sites per unit area is
6.023 10

14

cm and total area of catalyst surface is 1000 cm . Now when catalyst is heated to
3

300 K, N2 gas desorbs and evolved gas occupied 2.46 cm at 0.001 atm. Find the number of sites
ocupied by each molecule of N2.

62.

The activity per mL of a solution of radioactive substance is x. 100 mL water is added to 200 mL of
this solution, so that the activity falls to x/48 per mL after n half-lives. Find n.

63.

A hypothetical metal chloride undergoes reduction reaction with Mg producing metal and MgCl2.
Experiments show that 52.4 g of metal chloride reacts with 9.6 g of Mg according to above
reaction. Then, determine the equivalent weight of the given metal. Report your answer after
dividing it by 10.

64.

Determine the sum of number of unpaired electrons in KO2, NO, ClO2, O2, ClO3, BaO2, NO2, B2,
CO and O3.

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CHEMISTRY

61.

CHEMISTRY

An electron is continuously accelerated in vacuum tube by applying potenital difference. If its


de-broglie wavelength is decreased by 4 %. Determine the approx % change in kinetic energy of
the electron.
Report your answer by adding '1' if kinetic energy increases and subtracting '1' if kinetic energy
decreases.

66.

Boron exist in different allotropic forms. All allotropic form contains icosahedral units (icosahedral
is a regular shape with 12 corners & 20 faces) with boron atoms at all 12 corners and all bonds are
equivalent.

B (g)

(g)

Calculate heat evolved at constant pressure (in KJ) per mole of boron atoms undergoing above
change if HBE(BB) = 200 KJ/mol. Report you answer after dividing by 100.

67.

How many position isomers of dibromonaphthalene is possible if each ring of naphthalene has one
halogen?

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CHEMISTRY

65.

CHEMISTRY

How many of the following reactions will produce colourless gas which can turn limewater milky,

CHEMISTRY

68.

when passed through lime water.


electrolys is
(i) CH3COOK (aq)

(ii) CH3CH2OH + Thionylchloride

OH

(iii)

+ NaHCO3

(iv) CH3MgBr + CH3COOH

(v) Oxalic acid + conc. H2SO4

(vi)
COOH

69.

(y) and (z) both give ve iodoform test and +ve Tollens test.
(i) O3

C8H16
(x)

C5H10O

(ii) Zn / H2O

HBr

W
(major product)

(y)

C3H6O
(z)

HCN

Diastereomeric mixture

HCN

Enantiomeric mixture

What is the number of position of Br in IUPAC name of compound W ?

70.

X is the molecular weight of smallest, optically active natural amino-acid then value of

x 1
10

will

be:

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CHEMISTRY

How many molecules given below are more basic than aniline ?

NH
H 2N

NH

NH 2

CH 3

NH 2

CH3

II

NH 2

CH2

NH 3

III

IV

CH3

CH 3

NH 2

NH 2

CH 3

NH 2

O
V

CH3

VI

CH 3

CH3

IX
KMnO4 / OH

C9H10O
(x)

CH 3

CH3

VIII

72.

VII

Tollen's test
ZnHg
HCl

Benzoic acid
+ve
(y)

(i) O2
+
(ii) H3O

(z) + (w)

Br2 (aq)

(V)

Compound (z) is an important organic solvent and compound (x) has one methyl group.
What is the maximum number of moles of Br2, Which can react with 1 mole of (W)

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71.

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