(Study Material) Salt Analysis of Cations and Anions (Chemistry) - CBSE PORTAL - CBSE, ICSE, NIOS, JEE-MAIN, AIPMT Students Community

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(StudyMaterial)SaltAnalysisofCationsandAnions

(Chemistry)

SaltAnalysis
Cations
Group

GroupReagent

Radicals

ZeroGroup

O.S.+NaOH+Heat

NH4+

IGroup

O.S.+HCl

Pb2+

IIGroup

O.S.+HCI+H2S

Cu2+

IIIGroup

O.S.+NH4Cl+NH4OH

AI2+,Fe3+

IVGroup

O.S.+NH4CI+NH4OH+H2S

Ni2+,Mn2+,Zn2+

,Co2+

O.S.+NH4CI+NH4OH+(NH4)2CO3

Ba2+,Ca3+,Sr2+

VGroup

VIGroup

O.S+NH4CI+NH4OH+NaH2PO4

Mg2+

Anions
Group

GroupReagent

Radicals

IGroup

Salt+dil.H2SO4

CO32,SO32,S2,
NO2

IIGroup

Salt+conc.H2SO4

Cl,Br,I,CH3COO

AddCupieceandheat

NO

AddKMnO4soln.

c2o42

IIIGroup

O.S.+BaC!2

so42

IVGroup

O.S+Conc.HNO3+Heat+(NH4)24

PO43

MoO

PreliminaryTests
Test

Observation

Inference

PhysicalAppearance

Colour

White

NH4+,Pb2+,Al3+,Zn2+,Ba2+,
Ca2+,Sr2+andMg2+

Blue

Cu2+

Green

Ni2+

Brown

Fe3+

Red

Co2+

Lightpink

Mn2+

Odour

SmellofNH3

NH4+

Smellofvinegar

CH3COO

Smellofrotteneggs

H2

DryHeating

Colourlessgasevolved

CO32,SO32,S2andCl

Blowngasevolved

Br,NO3

Violetgasevolved

Cracklingsound

Pb(NO3)2andBa(NO3)2

Brownresidue

Cu2+

FlameTest

Greenishblue

Cu2+

Lightgreen

Ba2+

Brickred

Ca2+

Crimsonred

Sr2+

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