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Equacao de Brettschneider
Equacao de Brettschneider
[] + 0.79[]2 + 0.21[]2
[2]2 + [] + [] 2+2 + [ ] + [2 ]2 + [2 ]2
+ [2 ]2 + [2 ]2
Carbon balance
[] = [2 ] + [] + []
Oxygen balance
[] + 2 0.21[] = 2[2 ] + [] + [ ] + [2 ] + 2[2 ]
Hydrogen balance
[] = (2 + 2)[] + 2[2 ] + 2[2 ]
CO/CO2 equilibrium
2 + 2 + 2
=
[][2 ]
= 3.5 1750 ( )
[2 ][2 ]
Developing equations
Molecular Hydrogen concentration
[2 ] =
[] [2 ] ( + 1)[]
2
Water concentration
[2 ] =
[2 ]
[2 ]
[2 ] =
{ [] [2 ] ( + 1)[]}
[]
[] 2
[]
[]
3.5 []
2
2
2
[2 ] =
=
=
[]
[]
[]
{1 +
} { +
} {3.5 +
}
[2 ]
[2 ]
[2 ]
J E Mautone Barros
emautone@terra.com.br
Pgina 1 de 17
[2 ] + [] + []
Air concentration
0.21[] =
{2[2 ] + [] + [ ] + [2 ] + 2[2 ]} []
2
2
[] [ ] 1 3.5 2 []
0.21[] = [2 ] +
+
+
+ [2 ] []
[]
2
2
2
2
{3.5 +
}
[2 ]
0.21[] = [2 ] +
[]
[ ]
+ [2 ] +
+
2
2
0.21[] = [2 ] +
3.5
[] []
[]
4
2
{3.5 +
}
[2 ]
[]
[ ]
+ [2 ] +
+{
2
2
0.21[] = [2 ] +
+{
3.5
} []
[]
4 2
{3.5 +
}
[2 ]
[]
[ ]
+ [2 ] +
2
2
3.5
[2 ] + [] + []
}
[]
4 2
{3.5 +
}
[2 ]
Defining,
J E Mautone Barros
emautone@terra.com.br
Pgina 2 de 17
[]
[ ]
+ [2 ] +
2
2
3.5
} {[2 ] + [] + []}
[]
4
2
{3.5 +
}
[2 ]
[] =
[]
[ ]
1
[2 ] +
+ [2 ] +
+{
0.21
2
2
{
3.5
} {[2 ] + []}
[]
4
2
{3.5 +
}
[2 ]
[2 ] +
[ ]
0.21
2 + 2 + 2 +{
[]
=
[]
3.5
4 2 } {[2 ] + []}
[]
{3.5 +
}
[2 ]
{[2 ] + [] + []}
(1 +
)
0.21
4
2
= 12 + + 16 /
=
J E Mautone Barros
emautone@terra.com.br
[]
=
[]
Pgina 3 de 17
|
|
[] []
[2 ] +
[]
[ ]
[ ]
2 + 2 + 2 +{
={
J E Mautone Barros
emautone@terra.com.br
3.5
4 2 } {[2 ] + []}
[]
{3.5 +
}
[2 ]
(1 + 4 2 ) {[2 ] + [] + []}
Pgina 4 de 17