Test #B1

Name _________________________

Chemistry 11100

Section ____________

FINAL EXAM

TA ___________________________

Friday, 8:00 AM

Total Points = 300

December 18, 2015

Directions:
1.

Each student is responsible for following directions. Read this page carefully.

2.

Write your name and other requested information on this page and on the separate answer sheet.

3.

CODE your name on the answer sheet using an ordinary (#2) pencil.

4.

CODE your correct 10-digit identification number (PUID) on the answer sheet. THIS IS VERY
IMPORTANT!

5.

CODE your section number on the answer sheet. Please use all four digits, 0034, 0035, 0036, etc. This
is also very important!

6.

CODE the test number shown in the upper right-hand corner on the answer sheet in the block labeled
Test/Quiz Number. This is Test #B1.

7.

Put all calculations on the examination pages. DO NOT PUT ANY EXTRA MARKS ON THE
COMPUTER ANSWER SHEET!

8.

This exam consists of 47 multiple-choice questions worth 6.38 points each. Choose the one best or
correct answer for each question and write it both on your exam paper and on the computer answer
sheet. The computer answer sheet is the only one that will be graded!

9.

This exam consists of 15 pages plus two pages of Useful Information, a Periodic Table and a sheet of
scratch paper. Please check to be sure that you have them all!

END OF EXAM
1)

Please make sure that you have entered 47 answers on your scan sheet.

2)

Make sure that you have entered your name, ID number, and lab section number (4 digits).

3)

You MUST turn the scan sheet in to your TA before leaving the exam!

KEEP YOUR ANSWERS AND WORK COVERED TO PROTECT

THE INTEGRITY OF YOUR WORK!!

CHM 11100 Final Exam -- Test #B1 12/18/15

________

1.

Convert 25.54 mL to L.
(a)
(b)
(c)
(d)

________

2.

25,540 L
2.554 L
0.2554 L
0.02554 L

Molarity is defined as __________________.

(a)
(b)
(c)
(d)
(e)

moles of solute per liter of solution

moles of solute per liter of solvent
moles of solvent per liter of solution
moles of solute per kilogram of solvent
total moles present per liter of solution

_________3. What is the molarity of a sodium chloride solution created from 6.30 g NaCl dissolved into
785 mL of solution? (NaCl 58.44 g/mol)
(a)
(b)
(c)
(d)
________

1.25 M
0.137 M
8.03 x 103 M
1.37 x 104 M

4. Convert 0.458 kg to mg.

3

(a) 4.58 10 mg
1

(b) 4.58 10 mg
4

(c) 4.58 10 mg
5

(d) 4.58 10 mg
6

(e) 4.58 10 mg
________

5. Give the number of protons, electrons, and neutrons in one atom of calcium42.
(a)
(b)
(c)
(d)
(e)

42 protons, 42 electrons, 20 neutrons

20 protons, 20 electrons, 42 neutrons
20 protons, 20 electrons, 22 neutrons
42 protons, 20 electrons, 20 neutrons
20 protons, 22 electrons, 22 neutrons

CHM 11100 Final Exam -- Test #B1 12/18/15

________

6. Isotopes are ___________________.

(a)
(b)
(c)
(d)
(e)

________

7. What is the mass percent carbon in C2H5OH?

(a)
(b)
(c)
(d)
(e)

________

65.5 g
495 g
1.66 1024 g
2.98 1026 g

9. What is the chemical formula for calcium carbonate?

(a)
(b)
(c)
(d)
(e)

________

46%
52%
35%
24%
13%

8. Determine the mass in grams of 2.75 moles of glucose (C6H12O6, 180.16 g/mol).
(a)
(b)
(c)
(d)

________

atoms of different elements having the same mass numbers.

atoms and ions having the same number of electrons.
atoms of the same element having different atomic numbers.
atoms of the same element having different numbers of neutrons.
atoms of the same element having different numbers of electrons.

CaC
CaCO2
CaCO3
CaCO4
Ca(CO3)2

10. A granola bar has 4.5 grams of fat, 28.5 grams of carbohydrates, and 3 grams of protein. How
many kcal are in the granola bar? (nutritional information on useful info sheet)
(a)
(b)
(c)
(d)

36 kcal
167 kcal
191 kcal
291 kcal

CHM 11100 Final Exam -- Test #B1 12/18/15

_______ 11. Ammonium chloride has what chemical formula?

(a) AlCl3
(b) NH3Cl
(c) NH4Cl
(d) NCl
_______ 12. In the How hard is hard water? lab you made a calibration curve where you titrated four
calcium standards with EDTA. Imagine a lab group made the curve below. The trendline is on
the graph. If a sample of tap water required 21.55 mL of EDTA to titrate, what is the
concentration of calcium in the water?

Volume EDTA vs. Concentration Ca2+

40

y = 0.0802x + 0.4775
R = 0.9996

Volume EDTA (mL)

35
30
25
20
15
10
5
0
0

100

200

300

Concentration Ca2+ (ppm)

(a)
(b)
(c)
(d)

1.69 ppm
220 ppm
263 ppm
275 ppm

_______ 13. The name of H3PO4 (aq) is ___________________.

(a)
(b)
(c)
(d)

phosphoric acid
carbonic acid
sulfuric acid
trihydrogen tetraoxic acid

400

500

CHM 11100 Final Exam -- Test #B1 12/18/15

_______ 14. How many grams of NH3 are produced when 2.79 g of H2 reacts with excess N2?
N2(g)
Molar mass (g/mol)
(a)
(b)
(c)
(d)
(e)

28.02

3 H2(g)
2.016

2 NH3(g)
17.03

35.4
15.7 g
0.163 g
0.122 g
0.108 g

_______ 15. What is the molar mass of Mg(NO3)2?

(a)
(b)
(c)
(d)

172.64 g/mol
148.33 g/mol
134.32 g/mol
86.32 g/mol

_______ 16. If 0.035 grams of Cu(NO3)2 is dissolved in 100.0 grams of H2O, what is the concentration of
Cu2+ in the resulting solution, in parts per million? (density of water is 1.00 g/ml)
(a)
(b)
(c)
(d)

3.5 104 ppm

0.035 ppm
3.5 ppm
350 ppm

_______ 17. What is the correct name for CCl4?

(a)
(b)
(c)
(d)

carbon tetrachloride
carbon chloride
carbon(IV) chloride
carbon chlorate

_______ 18. The formula for iron(II) sulfate is

(a)
(b)
(c)
(d)
(e)

FeSO4
Fe2SO4
Fe(SO4)2
FeS2
FeS

CHM 11100 Final Exam -- Test #B1 12/18/15

_______ 19. What is the molarity of a solution prepared by diluting 1.85 L of 6.5 M KOH to 11.0 L?
(a) 0.28 M
(b) 0.91 M
(c) 1.1 M
(d) 3.1 M
(e) 3.9 M
_______ 20. What is the formula for chlorine gas?
(a)
(b)
(c)
(d)

Cl(g)
Cl(g)
Cl2(g)
Cl2(g)

_______ 21. What ions and how many of each are formed for every one formula unit of Al(NO3)3 that
dissociates in water?
(a)
(b)
(c)
(d)

One Al3+ ions and one NO3 ion

One Al3+ ion and three NO3 ions
One Al3+ ion, one N3 ions, and three O2 ions
One Al3+ ion, three N3 ions, and nine O2 ions

_______ 22. How many milliliters of a 0.400 M HCl solution is needed to neutralize 25.0 mL of a 0.200 M
Ba(OH)2 solution according to the following balanced chemical equation?
Ba(OH)2 (aq) + 2 HCl (aq) BaCl2 (aq) + 2 H2O (l)
(a)
(b)
(c)
(d)

4.00 mL
12.5 mL
25.0 mL
50.0 mL

_______ 23. What is the number of ions in one formula unit of Mg3(PO4)2?
(a)
(b)
(c)
(d)

2
5
8
13

CHM 11100 Final Exam -- Test #B1 12/18/15

_______ 24. How many moles of sodium ions and sulfate ions are formed when 284.1 grams of Na2SO4
dissolves in water? (Na2SO4 = 142.05 g/mol)

(a)
(b)
(c)
(d)

Moles sodium ions

142
4
2
1

Moles sulfate ions

71
2
1
1

_______ 25. Order the following atoms or ions by increasing ionic radius. (Smallest radius to largest radius.)
F, O2, Al3+, Mg2+
(a) Al3+ < Mg2+ < F < O2
(b) Al3+ < Mg2+ < O2 < F
(c) F < O2 < Al3+ < Mg2+
(d) Mg2+ < Al3+ < F < O2
(e) O2 < F < Mg2+ < Al3+
_______ 26. Arrange P, Si, and O in order of increasing atomic radius. (Smallest to largest.)
(a) Si < O < P
(b) P < Si < O
(c) O < Si < P
(d) O < P < Si
_______ 27. A limiting reactant is defined as:
(a)
(b)
(c)
(d)

The reactant that is completely used up and determines the amount of product formed.
The reactant that has the smallest molar mass and determines the amount of product formed.
The reactant that is in excess and determines the amount of product formed.
The reactant that is completely used up and determines which product is a precipitate.

CHM 11100 Final Exam -- Test #B1 12/18/15

_______ 28. Consider the reaction of H2 (white spheres) and Cl2 (black spheres) to form HCl, according to the
balanced equation:
H2(g) + Cl2(g) 2 HCl(g)
Identify the excess reactant and the limiting reactant based upon the images.

(a)
(b)
(c)
(d)

Limiting Reactant
H2
Cl2
H2
Cl2

Excess Reactant
Cl2
H2
HCl
HCl

_______ 29. Select the correct Lewis structure for SO2.

_______ 30. What is the parent and molecular geometry of nitrite ion, NO2?
(a)
(b)
(c)
(d)
(e)

Parent
trigonal pyramidal
trigonal pyramidal
linear
trigonal planar
trigonal planar

Molecular
trigonal pryamidal
bent
linear
trigonal planar
bent

CHM 11100 Final Exam -- Test #B1 12/18/15

_______ 31. When ammonium nitrate dissolves in water the temperature of the solution decreases. Which of
the following is true for this reaction?
(a) H < 0, process is exothermic.
(b) H > 0, process is exothermic.
(c) H < 0, process is endothermic
(d) H > 0, process is endothermic
_______ 32. Ethanol (C2H5OH) burns according to the following balanced equation
C2H5OH(l) + 3O2(g) 2CO2(g) + 3H2O(l)

H = -1367 kJ

How much heat is released when 35.0 g of ethanol is burned?

(Molar mass of C2H5OH = 46.07 g/mol)
(a)
(b)
(c)
(d)
(e)

9.61 104 kJ
1039 kJ
1367 kJ
1797 kJ
4.78 104 kJ

_______ 33. Which of the following molecules is polar?

10

CHM 11100 Final Exam -- Test #B1 12/18/15

_______ 34. If 20.0 g NH3 and 20.0 g CO2 undergo a reaction according to the following balanced chemical
equation how many grams of urea (CH4N2O) are produced? (NH3 = 17.03 g/mole;
CO2 = 44.01 g/mole; CH4N2O = 60.06 g/mole)
2 NH3 + CO2

CH4N2O + H2O

(a) 27.3 g
(b) 35.3 g
(c) 62.6 g
(d) 70.5 g
_______ 35. Which of these compounds is a not a strong electrolyte when dissolved in water?
(a)
(b)
(c)
(d)

C6H12O6
NaNO3
HCl
KOH

_______ 36. What are the coefficients of the following chemical equation when it is balanced?
___Al2(SO4)3 (aq) + ___NaOH (aq) _____Na2SO4 (aq) + ____Al(OH)3 (s)
(a)
(b)
(c)
(d)

1, 1, 1, 1
1, 2, 1, 2
1, 6, 3, 2
1, 3, 3, 2

11

CHM 11100 Final Exam -- Test #B1 12/18/15

_______ 37. Copper metal reacts with concentrated nitric acid according to the following balanced chemical
equation.
2 Cu (s) + 4 HNO3 (aq) Cu(NO3)2 (aq) + 2 NO2 (g) + 2 H2O (l)
What mole-to-mole ratio would you use in the following equation to determine the number of
moles of HNO3 required to react with a known amount of Cu?

(a)

(b)

63.020

mol Cu

?
?

= mol HNO3

63.546

4 3
2

(c)

1 3

(d)

4 3

_______ 38. Think back to the chemical interactions lab. Imagine you were given four unknowns with
numbers 45, 66, 77, and 80. Unknown 45 is green and clear, and the other three unknowns are
colorless and clear. The possible chemical formulas for the unknowns are Pb(NO3)2, K2CO3,
NaCl, and Ni(NO3)2. The student recorded the following interactions.
45
NR
NR
NR

45
66
77
80

green
precipitate

66
XXX
NR
white
precipitate
white
precipitate

77
XXX
XXX
NR

80
XXX
XXX
XXX

NR

NR

What is the identity of each unknown? (The solubility rules and colors of common insoluble
salts are given in the useful information document at the end of this test.)
(a)
(b)
(c)
(d)

45
NaCl
K2CO3
Ni(NO3)2
Ni(NO3)2

66
Pb(NO3)2
Pb(NO3)2
NaCl
Pb(NO3)2

77
Ni(NO3)2
NaCl
Pb(NO3)2
NaCl

80
K2CO3
Ni(NO3)2
K2CO3
K2CO3

CHM 11100 Final Exam -- Test #B1 12/18/15

12

_______ 39. In lab you carried out a serial dilution and calculated the concentration of each solution. Starting
with a 0.750 M HCl stock solution, three standard solutions are prepared by sequentially diluting
10.00 mL of each solution to 100.0 mL. What is the concentration of the final solution (the
third volumetric flask)?

(a)
(b)
(c)
(d)
(e)

0.225 M
0.0750 M
0.0075 M
7.50 104 M
9.38 105 M

_______ 40. In the third lab of the semester you learned how to pipet using a 10 mL pipet and performed a
pipetting badge activity. You subsequently used in a pipet in four more experiments. Which of
the following is correct about the use of a pipet and pipet bulb?
(a) The pipet should be inserted all the way up into the round part of the pipet bulb.
(b) The liquid should be drawn up into the pipet until the top of the meniscus is just below the
calibration mark.
(c) The liquid should be dispensed into the flask by squeezing the pipet bulb to force out all the
liquid.
(d) After dispensing the liquid from the pipet, there should be a small amount of liquid left in the
tip of the pipet.
_______ 41. Aluminum reacts with an aqueous solution containing excess copper(II) sulfate according to the
balanced chemical equation below. If 1.85 g Al reacts and the percent yield of Cu is 56.6%, what
mass of Cu is actually produced?
2 Al (s) +3 CuSO4 (aq) 3 Cu (s) + Al2(SO4)3 (aq)
(a)
(b)
(c)
(d)

2.47 g
3.70 g
4.36 g
6.54 g

13

CHM 11100 Final Exam -- Test #B1 12/18/15

_______ 42. A student is ready to begin a titration using the buret set up shown below. What will be the buret
reading after she dispenses 14.50 mL of solution from the buret?
(a)
(b)
(c)
(d)
(e)

7.85 mL
14.50 mL
21.00 mL
21.15 mL
21.85 mL

_______ 43. In the Chemical reaction and heat changes lab a team of students recorded the following data
by dissolving a known mass of NH4NO3 in 50 mL of water. They went on to calculate the heat
change for the dissolution of each sample. Complete the table and determine which of the
following statements, I through IV, is correct. (NH4NO3 = 80.06 g/mole)
Data and calculations
Sample
Mass NH4NO3
NH4NO3
(g)
Sample #1
2.058
Sample #2
3.990
I.
II.

Heat change for

the dissolution (J)
571
1120

Heat change per mole NH4NO3

(kJ/mole)
?
?

The dissolution is exothermic and the amount of heat released increases with the amount
of NH4NO3 dissolved in the water.
The dissolution is endothermic and the amount of heat absorbed increases with the
amount of NH4NO3 dissolved in the water.

III.

The heat change per mole is relatively the same for both samples.

IV.

The heat change per mole changes doubles as the mass of the samples doubles.

(a)
(b)
(c)
(d)

I, III
I, IV
II, III
II, IV

14

CHM 11100 Final Exam -- Test #B1 12/18/15

_______ 44. Consider the following reaction.

Cr2O3(s) + 3CCl4(l) 2CrCl3(s) + 3COCl2(g)
green
colorless
purple colorless
solid
liquid
solid
gas
When the green solid is mixed with the colorless liquid in a flask, the mixture starts to bubble
and produce gas. When all bubbling has stopped, only a dry purple solid containing solid green
specks remains in the flask (there is no liquid). Which substance is the limiting reactant?
(a)
(b)
(c)
(d)
(e)

Cr2O3
CCl4
CrCl3
COCl2
there is no limiting reactant

_______ 45. The figure shows a molecular-level diagram of reactant molecules for the reaction:
2 H2(g) + O2(g) 2 H2O(l).

List the number and formulas of the molecules that will be present after the reaction takes place.
(a)
(b)
(c)
(d)
(e)

Molecules H2O
2
3
4
6
6

Molecules H2 Molecules O2
6
2
5
1
4
1
2
1
2
0

_______ 46. Which of the following compounds has ionic bonds?

(a)
(b)
(c)
(d)

NaCl
O2
CH4
SiO2

CHM 11100 Final Exam -- Test #B1 12/18/15

15

_______ 47. When solutions of barium chloride and silver nitrate are mixed silver chloride forms according to
the balanced chemical equation below. If 25.00 mL of 0.500 M barium chloride solution is
mixed with 25.00 mL of 0.500 M silver nitrate solution how many moles of silver chloride can
be formed?
BaCl2(aq) + 2AgNO3(aq) 2AgCl(s) + Ba(NO3)2(aq)
(a)
(b)
(c)
(d)

0.00625 mol
0.0125 mol
0.0250 mol
1.79 mol

CHM 11100 Final Exam -- Test #B1 12/18/15

Useful Information and Formulas

% Recovery =
% Yield =

The mole

mass of material recovered

100%
mass of material started with

Actual
100
Theoretical

Avogadros number: 1 mole = 6.022 x 1023 formula units

Solutions
MiVi = MfVf
1 ppm = 1 g/ 1 x 106 g = 1 mg/L = 1 mg/kg
Parts per million (ppm) = Grams of solute x 106
Grams of solution
1 ppb = 1g/L = 1 g/kg
Heat and energy
4.184 J = 1 cal
Fats: 9 kcal/g

Light

1000 cal = 1kcal = 1 Cal

Carbohydrates: 4 kcal/g Proteins: 4 kcal/g

=
=

c = 3 x 108 m/s

= =

h = 6.626 x 10-34 J s

CHM 11100 Final Exam -- Test #B1 12/18/15

Solubility rules: Rules used to predict the solubility of ionic compounds.

Ions
+

Rule
+

Na , K , NH4 (and
all other alkali metal
ions)

Most compounds of alkali metal and ammonium ions are soluble.

NO3-, CH3CO2-

All nitrates and acetates are soluble.

SO42-

Most sulfates are soluble. Exceptions are BaSO4, SrSO4, PbSO4, CaSO4,
Hg2SO4, and Ag2SO4.

Cl-, Br-. I-

Most chlorides, bromides, and iodides are soluble. Exceptions are AgX,
Hg2X2, PbX2, and HgI2 (X = Cl, Br, or I).

OH-

Hydroxides are insoluble. Exceptions are alkali metal hydroxides, Ba(OH)2,

Sr(OH)2, and Ca(OH)2 (somewhat soluble)

S2-

Sulfides are insoluble. Exceptions are compounds of Na+, K+, NH4+, Mg2+,
Ca2+, Al3+, and Ni2+

CO32-, PO43-

Most carbonates and phosphates are insoluble. Exceptions are compounds of

Na+, K+, and NH4+

Colors of ions in solutions: Solutions containing Cu2+ ion are blue, those containing Ni2+ are green. All other
anions and cations listed on this sheet are colorless in water.
Colors of Some Common Insoluble Salts
Chlorides, ClAgCl
Iodides, IAgI
Sulfides, S2Ag2S
NiS

white

PbCl2

white

yellow

PbI2

yellow

=
=

black
black

CuS
PbS

=
=

black
black

white

PbSO4

white

=
=
=

tan
white
green

CuCO3
CaCO3
PbCO3

=
=
=

pale blue
white
white

2-

Sulfates, SO4
BaSO4

Carbonates, CO3
Ag2CO3
BaCO3
NiCO3

2-

CHM 11100 Final Exam -- Test #B1 12/18/15

Final Exam, Fall 2015, Answers

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