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Dental Materials Lecture - Mechanical Properties
Dental Materials Lecture - Mechanical Properties
Graham.Cross@tcd.ie
16.11.2007
Topics
Oct. 26: Basic metallurgy and alloys
Nov. 2: Properties of materials, thermals
Nov. 16: Mechanics of solids and fluids
Textbooks Further Reading
Applied Dental Materials 8 th Edition 1998, John F. McCabe, Angus W. G. Walls,
Blackwell, Oxford, UK.
Restorative Dental Materials 10th Edition 1997 Editor Robert G. Craig, Mosby Year
Book, Inc, St. Louis, USA
Notes on Dental Materials 6th Edition 1992 Editor E.C. Combe, Churchill Livingstone,
Edinburgh, UK
Phillips Science of Dental Materials 10th Edition 1996, Editor Kenneth J. Arusavice,
W.B. Saunders Company Philadelphia, USA
Dental Materials, Properties and Manipulation 6th Edition 1996 Editors Robert G. Craig,
William J. OBrien, John M. Power, Mosby Year Book, Inc, St. Louis, USA
16.11.2007
Stress
Stress is the force per unit area applied to an object:
Force
=
Area
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Tensile
Shear
Adhesion
Adhesion may be defined simply as a force interaction
between two materials at an interface where they are in
contact.
Failure occurs at a critical stress level
Interface must support a solely tensile load:
Mechanical
16.11.2007
Chemical
Dental Materials - Graham Cross
Chemical Adhesion
Rough surfaces mean small contact area, so a small force makes a large stress
at local points on surface, causing failure
Polishing a surface to make it smooth increases area and reduces stress
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Strain
Strain is a measure of the change in dimension of an
object that occurs by the application of stress.
It is defined as a relative displacement:
dl
=
l
Different kinds of
strain
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Stress
Strain
This is an intrinsic signature of a material
Why would a force vs. displacement curve
not be?
See: Applied Dental Materials 8th Edition 1998, John F. McCabe, Angus W. G. Walls, Chapter 2.
16.11.2007
Elasticity
Reversible stretching,
compression, or deforming of a
body
Stress
= E
limit
Strain
10
Elastic Modulus
Before
After
Polystyrene:
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Bulk
B=10 GPa
Youngs
E=3 GPa
Shear
G=1 GPa
11
Shear strain
Shear strain is a skew: it changes shape, not volume.
Very important when we consider flow.
dy
h
Shear strain rate:
h
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d dy h dy dt
=
=
dt
dt
h
d vy
=
dt
h
12
x
h
y
Force
Area
vy
dt
velocity
in y direction
13
Bonding energy
Repulsive
Distance of separation
Difficult!
Attractive
Compressive/tensile stress:
- Changing the distance of separation
of atoms is difficult (volume change)
Shear stress:
- Changing neighbours between atoms
is much easier (shape change)
Easy!
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14
solid
Position
(Low Temperature)
Atoms deep
in energy well
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vacancy
15
solid
Position
(Low Temperature)
Atoms deep
in energy well
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vacancy
16
solid
Position
(Low Temperature)
Atoms deep
in energy well
vacancy
Energy
liquid
Position
(High Temperature)
17
Viscosity
Viscosity describes the
way momentum is transferred
by a fluid during flow
For simple fluids it is a
constant of proportionality
between shear stress and
shear rate (Newton):
dt
d
=
dt
16.11.2007
Units: Pa s
(Poise)
Force
Fluid
Viscosity
Pa s
Air
0.00018
Water
0.0089
Mercury
0.015
Honey
100
Glass
1040 (?)
18
Rheology
Study of the flow of all materials, including
solids and complex liquids such as polymer
melts, colloids, suspensions, slurries, pastes,
etc.
Consider a complex fluid, a polymer melt:
What happens when you shear this material?
Molecules both flow and they change their
shape they relax
Gives rise to both shear rate (d/dt) and time
dependent behaviour.
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19
20
Time t
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Time t
Time t
Good rheological properties
- long working time
- reasonable setting time
21
d
dt
Shear
Stress
Shear
Stress
Shear rate
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d
dt
Dental Materials - Graham Cross
Shear rate
d
dt
22
Shear Stress
yield
Strain
Ductility
Like a liquid, plastic flow of solids involves shape change, not volume change
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23
solid
Position
sheared solid
Energy
Position
24
Viscoelasticity
Response of materials with both
elastic and viscous character:
time dependent
Eg. Elastomers
Two important forms:
Creep
Stress relaxation
Visualized by combining mechanical components of
Springs (elastic): instant response to stress
Dash-pots (viscous): slow response
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25
Creep
Time dependent dimensional change of materials under constant
stress.
Stress
Strain
Time
26
Stress relaxation
When a viscoelastic material is under
constant strain a gradual reduction
in stress can occur
Stress
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Time t
27