nay SOLUTIONS EXAW 4 FALL 4. 10 mol of ideal gas are taken through the process illustrated on the pV diagram below. What is the maximum temperature along the diagonal line process? Use R=10J/Kmol. vRV py AR Pa) (poom’) (Lomol) (ie Tek Grek 10K c) 30K — d) 60K e) 12K 2. What is true about the number of degrees of freedom, f? it represents the ways a molecule can move. b) It is always 3 c) Itis always 5. d) It is 5 for a monatomic gas. e) It can never change for a diatomic gas.3. What is the work done by the gas per cycle for the process on the pV diagram illustrated below? p (Pa | Ss 2 4 6 ¥ 1D v(m?) (a))24J en W= AREA OF SHAPE c) 20J d) -20J5 e) 10J We- (>), + gw 4 L b, ha) W- -[4 (2n’)(4Pa) + (ag)(¥Pa) + Aue Jae) | We-247 Wye 7 W4. Find the heat Q3 for the diagonal line process illustrated on the pV diagram below. The gas is diatomic. (hint: find and use az, for one cycle) cycles AE =O = Qrwr Qrw + Qs W; Wy z P(Pa) Q = SON te = Z(-5.¢ (2r,) = -3S87 % a= = a a = S(ch,\(1e2}= (SoJ 3 @w- lee (su2)(2Ra)= 10° Nel) = 2 2 “= (aw +4oh ) 10 Ss v(m?) (a)-1005 Mah a = (s.3 2Pa + 3 (.2)(LP.)) = Py vo = e,Ny 6000 = S00 kk v; » PNG & isetherm isechord > ; =e \ yee Bills ooo 1Ookk t GO yf) hs (308 y. = Gezore\ (eon) b) 500 m3 600oPa c) 10 m3 d) 100 m3 ae 3 e) 150 m3 lv, Soy 7. A heat pump has temperature reservoirs at TC=100K and TH=400K. What is the coefficient of perfomance for cooling and heating, respectively, if both are 1/4 the Carnot values. W231 ko stk, = 4 Te, oe ool) | \ b) 1/3, 112 see eay Vt, Zook} \ 12, c) 4/3, 1/3 d) 3/4, 3/4 k Lk eit ail aan, . > S\ 14 e) 2/3, 7/8 wed 4 edt 4 (a mi 3 ., 4 eemsg = (1 g}eud) (Hoene) = oq ye “Le og 2m mM 20 & |x ol 8. 40 cm3 of liquid water is boiled to steam oO at 400K until the gas fills a container of volume 10,000 cm3. What is the pressure of the steam? Use pai g/cm3 and M=20 g/mol for liquid water. Use R=10 J/Kmol. @eo0,c0c0Pa PY = RT = ART ge Boe 5) 80,000 Pa Vv c) 400,000 Pa \ot Yaak d) 200,000 Pa P= (2melK0gFaak)(HBS) COCO e) 18,000 Pa 0,600 LIT wa? 2 9. What is a violation of the first law of thermodynamics for a heat engine? Q \ 2 Wi = = caune ¥ be @) aH=104, Ws= Bs s* Wye ge b) QC=10J, Ws=10J XC negati c) QH=12J, Wg=10J Violatis d) QC=12J, Wg=10J ON e) QHF5U, Ws=4Jd \ 0 u ua 10. What is false about an isochoric process? a) weo b) apeo W<-0 Ser °) areo qd) oz0 ) av=o0 iso choric 11. A heat engine has an efficiency of = 2/3 . What is the ratio Qo/QH for this engine? b) 2/3, l Qy = c) 4/3 d) 7/5 e) 5/9 Qa _ 1\ Q 312. 1 mol of ideal gas at T=100K is taken through the isothermal process illustrated on the pV diagram below. What is the work done on the gas and the heat, respectively. Use R=10 J/Kmol. P (Pa) °) % ? V(m W =1000In(2/7)J _ N @e —1000In(2/7)J W= WRT In ce W =10001n(7/2)J a b) 9 =-10001n(7/2)7 We (1mo1)( ate)" 00's W =10001n(7/2)7 ©) Q=10001n(7/2)7 W =1001n(7/2)F d) Q=1001n(7/2)7 W =nC,AT e) 9-0= 28 jx ep? exit ° R-R Re v= Sar? y= 5% (28) 13. A sealed spherical balloon expands at constant pressure, ME 4 BAR doubling its radius. By what factor does the temperature increase? e 2 4 That is, find 7#7j, (hint: use the volume of a sphere, ”=37%" .) (@s isclaric Mi Es oe Te . Me b)2 i ve \ Ve c)4 4 (s 3 d) 172 Te SWRA K _ fe e)3 a 8 a . SS i a 14. What is az, for process #2 on the pV diagram illustrated below? The gas is diatomic. (hint: the temperature change for both processes is the same.) Nena + = WT P (Pa yy - 20 |------ 70 e) -100J15. Label the process names on the pV diagram below. & pV constant Vv a). isotherm 2. adiabat 3. isobar 4. isochord b) 1. adiabat 2. isotherm 3. isobar 4. isochord c) 1, adiabat 2. isotherm 3. isochord 4. isobar d) 1. isochord 2. isotherm 3. adiabat 4. isobar e) 1. isochord 2. isobar 3. adiabat 4. isotherm