= q msT m = 25mL density of water = 25mL 0.998 g // mL = 24.95g s water = 4.184 J / g oC T = (T f Ti )= 5 oC qwater= 24.95 g 4.184 ( J / g oC ) 5 oC = 521.954 J Since 0.5 g NaOH released 208.78 J heat. Therefore 1 gm NaOH will release (521.954/0.50)=1043.908 J/g H1 =q Mol. wt. NaOH = 1043.908 ( J / g ) 40 g/= mol 41.756 kJ/ mol Part B: Heat of neutralization amount of water in 25 mL of 1M HCl solution M 1V1 = M 2V2 11.94 M V1 = 1M 25mL V1 = 2.1mL volume of water=(25-2.1)mL=22.89 mL weight of 22.89 mL water=22.89mLx0.998 g/mL=22.84 g = q msT s water = 4.184 J / g oC T = (T f Ti )= 6 oC qwater= 22.84 g 4.184 ( J / g oC ) 6 oC = 573.375 J
amount of NaOH in 25 mL 1M NaOH solution=1.0 gm
H 2 =q Mol. wt. NaOH = 573.375 ( J / g ) 40 g/ mol = 22.935 kJ/ mol
Part C: Heat of Reaction
amount of water in 25 mL of 0.5M HCl solution M 1V1 = M 2V2 11.94 M V= 0.5M 25mL 1 V1 = 1.04mL volume of water=(25-1.04)mL=23.95 mL weight of 23.95 mL water=23.95mLx0.998 g/mL=23.90 g = q msT s water = 4.184 J / g oC T = (T f Ti )= 8 oC qwater= 23.90 g 4.184 ( J / g oC ) 8 oC = 799.98 J
Since 0.5 g NaOH released 799.98 J heat.
Therefore 1 gm NaOH will release (799.98/0.50)=1599.96 J/g H 3 =q Mol. wt. NaOH = 1599.96 ( J / g ) 40 g/ mol = 63.998 kJ/ mol