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Glycerol (Data Page) - Wikipedia PDF
Glycerol (Data Page) - Wikipedia PDF
Glycerol(datapage)Wikipedia
Glycerol(datapage)
FromWikipedia,thefreeencyclopedia
Thispageprovidessupplementarychemicaldataonglycerol.
Contents
1
2
3
4
5
6
7
8
MaterialSafetyDataSheet
Structureandproperties
Thermodynamicproperties
Vaporpressureofliquid
Freezingpointofaqueoussolutions
Distillationdata
Spectraldata
References
MaterialSafetyDataSheet
Thehandlingofthischemicalmayincurnotablesafetyprecautions.ItishighlyrecommendedthatyouseektheMaterialSafetyDatasheet(MSDS)for
thischemicalfromareliablesourceandfollowitsdirections.
ScienceLab(http://www.sciencelab.com/msds.php?msdsId=9927350)
Structureandproperties
Structureandproperties
Indexofrefraction,nD 1.4729at20C
Abbenumber
Dielectricconstant,r
42.50at25C
Bondstrength
Bondlength
Bondangle
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Magneticsusceptibility ?
Surfacetension
63.4mN/mat20C
58.6mN/mat90C
51.9mN/mat150C
Viscosity[1]
4.220Pasat2.8C
1.069Pasat20C
Thermodynamicproperties
Phasebehavior
Triplepoint
291.8K(18.7C),~99500Pa
Criticalpoint
850K(577C),7500kPa
Stdenthalpychange
offusion,fusHo
18.28kJ/mol
Stdentropychange
offusion,fusSo
62.7J/(molK)
Stdenthalpychange
ofvaporization,vapHo
91.7kJ/mol
Stdentropychange
ofvaporization,vapSo
201J/(molK)
Solidproperties
Stdenthalpychange
offormation,fHosolid
?kJ/mol
Standardmolarentropy,
Sosolid
?J/(molK)
Heatcapacity,cp
150.J/(molK)6C11C
Liquidproperties
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Stdenthalpychange
offormation,fHoliquid
669.6kJ/mol
Standardmolarentropy,
Soliquid
?J/(molK)
Enthalpyofcombustion,cHo 1654.3kJ/mol
Heatcapacity,cp
221.9J/(molK)at25C
Gasproperties
Stdenthalpychange
offormation,fHogas
577.9kJ/mol
Standardmolarentropy,
Sogas
?J/(molK)
Heatcapacity,cp
?J/(molK)
Vaporpressureofliquid
PinmmHg 1
TinC
10
40
100
400
760
TabledataobtainedfromCRCHandbookofChemistryandPhysics,44thed.
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log10ofGlycerolvaporpressure.Usesformula:
obtainedfrom
CHERIC[2]
Freezingpointofaqueoussolutions
%glycerol
byvolume[probablyatypofor"byweight"see
10
20
30
40
50
60
70
80
90
100
Freezingpoint
C
1.6
4.8
9.5
15.5
22.0
33.6
37.8
19.2
1.6
17.0
Specificgravity
d15
1.02415 1.04935 1.07560 1.10255 1.12985 1.15770 1.18540 1.21290 1.23950 1.26557
Lange'scitedbelow.]
TabledataobtainedfromLange'sHandbookofChemistry,10thed.Specificgravityisat15C,referencedtowaterat15C.
Seedetailson:FreezingPointsofGlycerineWaterSolutions(http://www.dow.com/glycerine/resources/table8.htm)DowChemical[3]
Distillationdata
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VaporliquidEquilibriumofGlycerol/water[4]
P=760mmHg
BP
Temp.
C
%bymolewater
liquid
vapor
278.8
2.75
93.15
247.0
4.67
94.73
224.0
6.90
95.63
219.2
7.67
97.43
210.0
9.01
97.83
202.5
10.31
97.24
196.5
11.59
98.39
175.2
17.56
98.99
149.3
30.04
99.64
137.2
38.47
99.76
136.8
38.95
98.78
131.8
43.58
99.76
121.5
56.33
99.84
112.8
70.68
99.93
111.3
73.86
99.94
106.3
84.42
99.96
Spectraldata
UVVis
max
?nm
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Extinctioncoefficient, ?
IR
Majorabsorptionbands ?cm1
NMR
ProtonNMR
Carbon13NMR
OtherNMRdata
MS
Massesof
mainfragments
References
1.Lange'sHandbookofChemistry,10thed.pp16691674
2."PureComponentProperties"(Queriabledatabase).ChemicalEngineeringResearchInformationCenter.Retrieved13May2007.
3.FreezingPointsofGlycerineWaterSolutions(http://www.dow.com/glycerine/resources/table8.htm)DowChemical
4."BinaryVaporLiquidEquilibriumData"(Queriabledatabase).ChemicalEngineeringResearchInformationCenter.Retrieved7June2007.
Exceptwherenotedotherwise,datarelatetostandardambienttemperatureandpressure.
Disclaimerapplies.
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Categories: Chemicaldatapages
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