Batch Adsorption Process

ADSORPTION STUDY USING 1 G ADSORBE
For Calculation of Concentration

Beer-Lambert's Law
=
Where:
A=
=
b=
C=
Using Blank Sample

Concentration (mg/L)
Absorbance
b (cm)
(L/mg-cm)
100
1.4509
10
0.0014509
Trial 1
Contact Time (min)
Trial 2
Contact Time (min)
Absorbance
0
20
40
60
80
100
120
Trial 1
Contact Time (min)
absorbance
molar absorption
path length
concentration
1.4509
0.40533
0.18624
0.127207
0.113998
0.114
0.114
0
20
40
60
80
100
120
Trial 2
Contact Time (min)
0
100
0
20
27.94
20
40
12.84
40
60
8.77
60
80
7.86
80
100
7.86
100
120
7.86
120
Adsorption Capacity and Percent Removal

W (g)
V (L)
Trial 1
Contact Time (min)
1
0.1
Ci (mg/L)
0
20
40
Ct (mg/L)
100
100
100
100
27.94
12.84
60
80
100
120
100
100
100
100
9.21
qe (mg/g)
Trial 2
Contact Time (min)
Ci (mg/L)
Ct (mg/L)
0
20
40
60
80
100
120
100
100
100
100
100
100
100
9.21
qe (mg/g)
Trial 3
Contact Time (min)
8.77
7.86
7.86
7.86
Ci (mg/L)
100
27.93
12.85
8.39
7.86
7.86
7.86
Ct (mg/L)
0
20
40
60
80
100
120
100
100
100
100
100
100
100
9.21
qe(mg/g)
100
27.77
12.61
8.75
7.89
7.89
7.89
Adsorption Capacity vs Contact Time

10
8
6
qt (mg/g)
Trial 1
Trial 2
Trial 3
2
0
20
40
60
80
Contact Time (min)
100
120
140
qt (mg/g)
Trial 1
Trial 2
Trial 3
2
0
20
40
60
80
Contact Time (min)
100
120
140
TION STUDY USING 1 G ADSORBENT DOSAGE
Trial 3
Contact Time (min)
Absorbance
1.4509
0.40524
0.1864
0.12173
0.114
0.11402
0.11402
Absorbance
0
20
40
60
80
100
120
1.4509
0.40285
0.18294
0.1269
0.11454
0.11454
0.11454
Trial 3
Contact Time (min) Concentration (mg/L)
100.00
0
100.00
27.93
20
27.77
12.85
40
12.61
8.39
60
8.75
7.86
80
7.89
7.86
100
7.89
7.86
120
7.89
Adsorption Capacity vs Con
q(t) (mg/g)
R (%)
0
7.21
8.72
0
72.06
87.16
qt (mg/g)
20
40
60
80
Contact Time (min)
qt (mg/g)
9.12
9.21
9.21
9.21
91.23
92.14
92.14
92.14
20
40
60
80
Contact Time (min)

q(t) (mg/g)
R(%)
0
7.21
8.72
9.16
9.21
9.21
9.21
10
0
72.07
87.15
91.61
92.14
92.14
92.14
8
6
qt (mg/g)
4
2
0
20
40
60
80
Contact Time (min)
AdsorptionCapacity vs Con
q(t) (mg/g)
10
R(%)
0
7.22
8.74
9.13
9.21
9.21
9.21
0
72.23
87.39
91.25
92.11
92.11
92.11
8
6
qt (mg/g(
4
2
0
20
40
60
80
Contact Time (min)
me
Percentage Removal vs Contact Time

100
80
Trial 1
Trial 2
Trial 3
60
Removal (%)
40
20
140
20
40
60
80
100
120
140
Trial 1
Trial 2
Trial 3
60
Removal (%)
40
20
140
20
40
60
80
Contact Time (min)
100
120
140
Percentage Removal vs C
rption Capacity vs Contact Time
100
80
60
Trial 1
Removal (%)
40
20
0
40
60
80
Contact Time (min)
100
120
140
20
40
60
80
Contact Time (min
Trial 1
Removal (%)
40
20
0
40
60
80
100
120
140
20
40
60
80
Contact Time (min
Contact Time (min)
orption Capacity vs Contact Time
100
80
60
Trial 2
Removal (%)
40
20
0
40
60
80
100
120
140
20
40
60
80
Contavt Time (m
Contact Time (min)
Percentage Removal vs
orptionCapacity vs Contact Time
100
80
60
Trial 3
Removal (%)
40
20
40
60
80
100
120
Trial 1
Trial 2
Trial 3
100
120
140
140
20
40
60
Contact Time (
Contact Time (min)
s Contact Time
80
80
(min)
Trial 1
Trial 2
Trial 3
100
120
140
tage Removal vs Contact Time
Trial 1
40
60
80
Contact Time (min)
100
120
140
Trial 1
40
60
80
100
120
140
Contact Time (min)
ntage Removal vs Contact Time
Trial 2
20
40
60
80
100
120
140
Contavt Time (min)
entage Removal vs Contact Time
Trial 3
20
40
60
80
Contact Time (min)
100
120
140
ADSORPTION STUDY USING 1 G ADSORBENT

Beer-Lambert's Law
=
Where:
A=
=
b=
C=
absorbance
molar absorption
path length
concentration
Using Blank Sample

100
Absorbance
1.4509
b (cm)
10
(L/mg-cm)
0.0014509
Run 1
Trial 1
Trial 2
Contact Time (min)
Absorbance
Contact Time (min)
0
1.4509
0
20
0.41533
20
40
0.19624
40
60
0.137207
60
80
0.123998
80
100
0.104
100
120
0.104
120
W (g)
1
Trial 1
V (L)
0.1
Contact Time (min)
Ct (mg/L)
Ci (mg/L)
0
100
100
20
28.63
100
40
13.53
100
60
9.46
100
80
8.55
100
100
7.17
100
120
7.17
100
Trial 2
Contact Time (min)
Ci (mg/L)
0
100.00
20
29.31
40
14.23
60
9.08
80
8.55
100
8.55
120
8.55
100
100
100
100
100
100
100
Trial 3
Contact Time (min)
0
20
40
60
80
100
120
Run 2
Trial 1
Contact Time (min)
Ci (mg/L)
100.00
31.21
17.43
12.88
11.34
9.96
9.96
1.4509
0.40533
0.18624
0.127207
0.113998
0.114
0.114
W (g)
V (L)
Ct (mg/L)
Trial 1
Contact Time (min)
0
20
40
60
80
100
120
Trial 2
Contact Time (min)
0
20
40
60
80
100
120
1
0.1
Ci (mg/L)
100
27.94
12.84
8.77
7.86
7.86
7.86
100
100
100
100
100
100
100
Ci (mg/L)
100.00
31.18
16.29
10.46
9.24
9.24
9.24
100
100
100
100
100
100
100
Ci (mg/L)
0
100.00
100
0
20
40
60
80
100
120
Trial 3
Contact Time (min)
Trial 2
Contact Time (min)
Absorbance
0
20
40
60
80
100
120
100
100
100
100
100
100
100
20
40
60
80
100
120
Run 3
Trial 1
Contact Time (min)
29.83
17.43
13.57
11.34
10.62
10.62
Trial 2
Contact Time (min)
Absorbance
0
20
40
60
80
100
120
1.4509
0.41533
0.18624
0.12607
0.11998
0.116
0.116
W (g)
V (L)
Ct (mg/L)
Trial 1
Contact Time (min)
0
20
40
60
80
100
120
100
100
100
100
100
100
0
20
40
60
80
100
120
1
0.1
Ci (mg/L)
100
28.63
12.84
8.69
8.27
8.00
8.00
100
100
100
100
100
100
100
Trial 2
Contact Time (min)
Ci (mg/L)
0
100.00
20
29.80
40
14.23
60
10.46
80
9.24
100
7.87
120
7.87
Trial 3
Contact Time (min)
Ci (mg/L)
0
100.00
20
29.98
40
13.99
60
11.65
100
100
100
100
100
100
100
100
100
100
100
80
100
120
9.33
7.86
7.86
100
100
100
PTION STUDY USING 1 G ADSORBENT DOSAGE
Trial 3
Contact Time (min)
Absorbance
1.4509
0.42524
0.2064
0.13173
0.124
0.12402
0.12402
0
20
40
60
80
100
120
Absorbance
1.4509
0.45285
0.25294
0.1869
0.16454
0.14454
0.14454
Adsorption
10
8
6
qt (mg/g)
q(t) (mg/g)
R (%)
0
7.1374319388
8.6474601971
9.0543317941
9.1453718382
9.2832035288
9.2832035288
0
71.374319388
86.4746019712
90.5433179406
91.4537183817
92.8320352884
92.8320352884
20
Percentage
q(t) (mg/g)
0
7.0691295058
8.5774346957
9.0920807774
9.1453580536
9.1452202081
9.1452202081
R (%)
100
0
70.6912950582
85.7743469571
90.9208077745
91.4535805362
91.4522020815
91.4522020815
80
60
Removal (%)
40
20
0
40
20
0
q(t) (mg/g)
R (%)
0
6.8788338273
8.2566682749
8.711834034
8.865962506
9.0037897167
9.0037893721
0
68.7883382728
82.5666827486
87.1183403405
88.6596250603
90.0378971673
90.0378937211
Trial 3
Contact Time (min)
Absorbance
1.4509
0.4524
0.2364
0.15173
0.134
0.13402
0.13402
Absorbance
0
20
40
60
80
100
120
1.4509
0.43285
0.25294
0.1969
0.16454
0.15402
0.15402
Adsropt
10
8
6
qt (mg/g)
q(t) (mg/g)
R (%)
0
7.2063546764
8.7163829347
9.1232545317
9.2142945758
9.2142807912
9.2142807912
0
72.0635467641
87.1638293473
91.2325453167
92.1429457578
92.1428079123
92.1428079123
Percenta
100
q(t) (mg/g)
R (%)
0
6.8819353505
8.3706664829
8.9542353022
9.076435316
9.0762974705
9.0762974705
q(t) (mg/g)
0
68.8193535047
83.7066648287
89.5423530223
90.7643531601
90.7629747054
90.7629747054
R (%)
0
80
60
R (%)
40
20
0
20
7.0166793025
8.2566682749
8.6429112964
8.865962506
8.9384864567
8.9384519953
70.166793025
82.5666827486
86.4291129644
88.6596250603
89.3848645668
89.3845199531
Trial 3
Contact Time (min)
Absorbance
1.4509
0.4324
0.2064
0.15173
0.134
0.1142
0.1142
0
20
40
60
80
100
120
Absorbance
1.4509
0.43500
0.20294
0.169
0.13538
0.11402
0.11400
Adsorption
10
8
6
qt (mg/g)
4
2
q(t) (mg/g)
R (%)
0
7.1374319388
8.7163829347
9.1310910469
9.1730649941
9.2004962437
9.2004962437
0
71.374319388
87.1638293473
91.3109104694
91.7306499414
92.0049624371
92.0049624371
20
Percentage
100
80
q(t) (mg/g)
R (%)
0
7.0197808257
8.5774346957
8.9542353022
9.076435316
9.2129023365
9.2129023365
q(t) (mg/g)
0
7.0018609139
8.6012819629
8.8352057344
0
70.1978082569
85.7743469571
89.5423530223
90.7643531601
92.1290233648
92.1290233648
R (%)
0
70.0186091392
86.0128196292
88.3520573437
60
R (%)
40
20
0
20
9.0669584396
9.2141774071
9.2142807912
90.6695843959
92.1417740713
92.1428079123
Adsorption Capacity vs Contact Time - Run 1

10
8
6
qt (mg/g)
Trial 1
Trial 2
Trial 3
2
0
20
40
60
80
100
120
140
Contact Time (min)
Percentage Removal vs Contact Time - Run1

100
80
60
Removal (%)
Trial 1
Trial 2
40
Trial 3
20
0
20
40
60
80
Contact Time (min)
100
120
140
40
Trial 3
20
0
20
40
60
80
100
120
140
Contact Time (min)
Adsroption Capacity vs Contact Time - Run 2

10
8
6
qt (mg/g)
Trial 1
Trial 2
Trial 3
2
0
20
40
60
80
100
120
140
Contact Time (min)
Percentage Removal vs Contact Time - Run 2

100
80
60
R (%)
Trial 1
Trial 2
40
Trail 3
20
0
20
40
60
80
Contact Time (min)
100
120
140
Adsorption Capacity vs Contact Time - Run 3

10
8
6
qt (mg/g)
Trial 1
Trial 2
Trial 3
2
0
20
40
60
80
100
120
140
Contact Time (min)
Percentage Removal vs Contact Time - Run 3

100
80
60
R (%)
Trial 1
Trial 2
40
Trial 3
20
0
20
40
60
80
Contact Time (min)
100
120
140
ADSORPTION STUDY USING 1 G ADSORBE

Beer-Lambert's Law
=
Where:
A=
=
b=
C=
Using Blank Sample

Absorbance
b (cm)
(L/mg-cm)
100
0.41103
10
0.00041103
Trial 1
Contact Time (min)
Trial 2
Contact Time (min)
Absorbance
0
20
40
60
80
100
120
Trial 1
Contact Time (min)
absorbance
molar absorption
path length
concentration
0.41103
0.21054
0.104533
0.079502
0.068501
0.0595
0.059498
0
20
40
60
80
100
120
Trial 2
Contact Time (min)
0
100
0
20
51.22
20
40
25.43
40
60
19.34
60
80
16.67
80
100
14.48
100
120
14.48
120
Adsorption Capacity and Percent Removal

W (g)
V (L)
Trial 1
Contact Time (min)
1
0.1
Ci (mg/L)
0
20
40
Ct (mg/L)
100
100
100
100
51.22
25.43
60
80
100
120
100
100
100
100
8.55
qe(mg/g)
Ce (mg/L)
Trial 2
Contact Time (min)
Ci (mg/L)
Ct (mg/L)
0
20
40
60
80
100
120
100
100
100
100
100
100
100
8.55
qe(mg/g)
Trial 3
Contact Time (min)
19.34
16.67
14.48
14.48
Ci (mg/L)
100
51.22
25.38
19.31
16.91
14.47
14.47
Ct (mg/L)
0
20
40
60
80
100
120
100
100
100
100
100
100
100
8.55
qe(mg/g)
100
51.22
25.41
19.32
16.91
14.47
14.47
Adsorption Capacity vs Contact Time

9
8
7
6
qt (mg/g)
Trial 1
Trial 2
Trial 3
3
2
1
0
20
40
60
80
Contact Time (min)
100
120
140
qt (mg/g)
Trial 1
Trial 2
Trial 3
3
2
1
0
20
40
60
80
Contact Time (min)
100
120
140
Trial 3
Contact Time (min)
Absorbance
0.41103
0.210524
0.10432
0.0793865
0.0695
0.05946
0.05946
Absorbance
0
20
40
60
80
100
120
0.41103
0.21053
0.1044265
0.07942725
0.06950
0.05948
0.05948
Trial 3
Contact Time (min) Concentration (mg/L)
100.00
0
100.00
51.22
20
51.22
25.38
40
25.41
19.31
60
19.32
16.91
80
16.91
14.47
100
14.47
14.47
120
14.47
q(t) (mg/g)
R (%)
0
4.88
7.46
0
48.78
74.57
qt (mg/g)
20
40
60
80
Contact Time (min)
qt (mg/g)
8.07
8.33
8.55
8.55
80.66
83.33
85.52
85.52
20
40
60
80
Contact Time (min)

q(t) (mg/g)
R(%)
0
4.88
7.46
8.07
8.31
8.55
8.55
0
48.78
74.62
80.69
83.09
85.53
85.53
qt (mg/g)
9
8
7
6
5
4
3
2
1
0
20
40
60
80
Contact Time (min)
AdsorptionCapacity vs Cont
q(t) (mg/g)
R(%)
0
4.88
7.46
8.07
8.31
8.55
8.55
0
48.78
74.59
80.68
83.09
85.53
85.53
8
7
6
qt (mg/g(
5
4
3
2
1
0
20
40
60
80
Contact Time (min)
me
Percentage Removal vs Contact Time

90
80
70
60
Trial 1
Trial 2
Trial 3
Removal (%)
50
40
30
20
10
140
20
40
60
80
100
120
140
60
Trial 1
Trial 2
Trial 3
Removal (%)
50
40
30
20
10
140
20
40
60
80
Contact Time (min)
100
120
140
rption Capacity vs Contact Time

90
80
70
60
Trial 1
Removal (%)
50
40
30
20
10
0
40
60
80
Contact Time (min)
100
120
140
20
40
60
80
Contact Time (min
Trial 1
Removal (%)
40
30
20
10
0
40
60
80
100
120
140
40
60
80
Contact Time (min
Contact Time (min)
orption Capacity vs Contact Time

90
80
70
60
Trial 2
Removal (%)
50
40
30
20
10
0
40
60
80
100
120
140
20
40
60
80
Contavt Time (mi
Contact Time (min)
Percentage Removal vs
orptionCapacity vs Contact Time
90
80
70
60
Trial 3
Removal (%)
50
40
30
20
10
40
60
80
100
120
Trial 1
Trial 2
Trial 3
100
120
140
140
20
40
60
80
Contact Time (
Contact Time (min)
s Contact Time
20
min)
Trial 1
Trial 2
Trial 3
100
120
140
tage Removal vs Contact Time
Trial 1
40
60
80
Contact Time (min)
100
120
140
Trial 1
40
60
80
100
120
140
Contact Time (min)
ntage Removal vs Contact Time
Trial 2
40
60
80
100
120
140
Contavt Time (min)
entage Removal vs Contact Time
Trial 3
20
40
60
80
Contact Time (min)
100
120
140
ADSORPTION STUDY USING 1 G ADSORBENT

Beer-Lambert's Law
=
Where:
A=
=
b=
C=
Using Blank Sample

Absorbance
b (cm)
(L/mg-cm)
Run 1
Trial 1
Contact Time (min)
0
20
40
60
80
100
120
Trial 1
Contact Time (min)
100
0.41103
10
0.00041103
Trial 2
Contact Time (min)
Absorbance
0.41103
0.21054
0.104533
0.079502
0.068501
0.0595
0.059498
0
20
40
60
80
100
120
Trial 2
Contact Time (min)
absorbance
molar absorption
path length
concentration
100
51.22
25.43
19.34
16.67
14.48
14.48
0
100.00
20
51.22
40
25.38
60
19.31
80
16.91
100
14.47
120
14.47
0
20
40
60
80
100
120
Trial 3
Contact Time (min)
0
20
40
60
80
100
120
100.00
51.22
25.41
19.32
16.91
14.47
14.47
Trial 3
Contact Time (min)
Absorbance
0.41103
0.210524
0.10432
0.0793865
0.0695
0.05946
0.05946
0
20
40
60
80
100
120
Absorbance
0.41103
0.21053
0.1044265
0.07942725
0.06950
0.05948
0.05948

Batch Adsorption Process

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Batch Adsorption Process

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ADSORPTION STUDY USING 1 G ADSORBE

For Calculation of Concentration

Using Blank Sample

Adsorption Capacity and Percent Removal

Adsorption Capacity vs Contact Time

Contact Time (min)

Contact Time (min)

TION STUDY USING 1 G ADSORBENT DOSAGE

Adsorption Capacity vs Con

Contact Time (min)

Contact Time (min)

Adsorption Capacity vs Con

Contact Time (min)

Contact Time (min)

Percentage Removal vs Contact Time

Contact Time (min)

rption Capacity vs Contact Time

Contact Time (min)

Contact Time (min

Contact Time (min

Contact Time (min)

orption Capacity vs Contact Time

Contact Time (min)

orptionCapacity vs Contact Time

Contact Time (min)

tage Removal vs Contact Time

Contact Time (min)

Contact Time (min)

ntage Removal vs Contact Time

Contavt Time (min)

entage Removal vs Contact Time

Contact Time (min)

ADSORPTION STUDY USING 1 G ADSORBENT

Using Blank Sample

PTION STUDY USING 1 G ADSORBENT DOSAGE

Adsorption Capacity vs Contact Time - Run 1

Contact Time (min)

Percentage Removal vs Contact Time - Run1

Contact Time (min)

Contact Time (min)

Adsroption Capacity vs Contact Time - Run 2

Contact Time (min)

Percentage Removal vs Contact Time - Run 2

Contact Time (min)

Adsorption Capacity vs Contact Time - Run 3

Contact Time (min)

Percentage Removal vs Contact Time - Run 3

Contact Time (min)

ADSORPTION STUDY USING 1 G ADSORBE

Using Blank Sample

Adsorption Capacity and Percent Removal

Adsorption Capacity vs Contact Time

Contact Time (min)

Contact Time (min)

TION STUDY USING 1 G ADSORBENT DOSAGE

Adsorption Capacity vs Con

Contact Time (min)

Contact Time (min)

Adsorption Capacity vs Con

Contact Time (min)

Contact Time (min)

Percentage Removal vs Contact Time

Contact Time (min)