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Thermodynamic Properties in HYSYS For The Peng
Thermodynamic Properties in HYSYS For The Peng
Package
Physical properties are predicted by HYSYS using the following thermodynamic based
equations
P dV
V
1 P
P
1
ln Z ln o
dV
R T V V
P
H H ID
1
Z 1
RT
RT
S S oID
RT
Where the Ideal Gas Enthalpy basis ( H ID ) used by HYSYS is equal to the ideal gas
Enthalpy of Formation at 25C and 1 atm. The Ideal Gas Enthalpy basis ( H ID ) used by
HYSYS changes with temperature according to the coefficients on the Tdep tab for each
individual component.
An example of the prediction of the enthalpy of a single component is given below where
the values of a f T and b are from the Peng-Robinson equation of state.
H H ID
1
da V 2 0.5 1 b
Z 1 1.5
a T ln
RT
dt V 2 0.5 1 b
2 bRT
where
a xi x j ai a j
N
i 1 j 1
bi 0.077796
0.5
1 k
ij
RTci
Pci
ai aci i
aci
RTci
0.457235
Pci
1 mi 1 Tri0.5
mi 0.37646 1.54226 i 0.2699 i2
Section A.3 Enthalpy and Entropy, in the Simulation Basis Manual give the details of the
Property packages used by HYSYS.
To see these properties go to the Simulation Basis Manager and View the Peng-Robinson
Property package.
Select View and then select the components tab.
Select a component and look at the properties. These are snapshots from the TDep tab or
Temperature Dependent properties.