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Novas Formulações Com Silicones
Novas Formulações Com Silicones
50
Polyglycerin-3
Diisostearate
40
Interfacial Tension (mN/m)
Sorbitan Oleate
30
Lauryl PEG/
PPG-18/18
Methicone
20
10
0
-5
-4
-3
-2
-1
sifier is outside current clear antiperspirant patents and therefore allows freedom to practice.
Formulation 1 illustrates the use of the
new silicone emulsifier in a clear antiperspirant gel made with a low shear process.
Formulation 2 demonstrates the use of
the silicone emulsifier in a water-insilicone foundation.
Formulation 1
Clear Antiperspirant Gel
Ingredient
Phase A
1. Cyclopentasiloxane (and) PEG-12
dimethicone crosspolymer
2. Dimethicone
3. Phenyl trimethicone
4. Cyclopentasiloxane
Phase B
5. Aluminum sesquichlorohydrate
6. Deionized water
7. Propylene glycol
8. Glycerin
9. Ethyl alcohol, 200 proof
Wt. %
Trade Name/Supplier
10.0
3.5
0.5
6.0
42.0
17.5
12.5
6.5
1.5
Procedure
Combine Phase A ingredients. In a separate container, combine Phase B ingredients. Match the refractive
index of Phase A to that of Phase B. If the refractive index of Phase A is higher than that of Phase B, add
water to the aqueous phase to match. If lower, add glycerin to match. With rapid mixing, add Phase B to
Phase A very slowly, using a separatory funnel. (Use a 1000 ml tall beaker and 1376 rpm.)
Formulation 2
Water-in-Silicone Foundation
Ingredient
Wt. %
Phase A
1. Dextrin palmitate
2.10
2. PEG-12 dimethicone
1.90
3. Tricaprylin
5.00
4. Cyclopentasiloxane (and) PEG-12
10.00
dimethicone crosspolymer
Phase B
5. Cyclopentasiloxane & Cyclohexasiloxane 20.00
Phase C
6. C.I. 77891, Dimethicone
2.75
7. C.I. 77492, Dimethicone
0.43
8. C.I. 77491, Dimethicone
0.32
9. C.I. 77499, Dimethicone
0.01
Phase D
10. Deionized water
to 100.00
11.Sodium chloride
1.00
Trade Name/Supplier
Rheopearl KL/Miyoshi Kasel
XIAMETER OFX-0193 Fluid
Trivent OC-G/Trivent
Dow Corning 9011 Silicone Elastomer Blend
XIAMETER PMX-0345 Cyclosiloxane Blend
SAT-T-47-051/US Cosmetics
SAT-Y-338073/US Cosmetics
SAT-R-33-128/US Cosmetics
SAT-B-33134/US Cosmetics
Sodium chloride/Merck
Procedure
Heat Phase A to 80C, ensuring that ingredient 1 is fully dissolved. Cool to 50C. Combine ingredients of Phase
C. Add Phase C to Phase B and mix. Add Phase B to Phase A with mixing. Combine ingredients of Phase D.
Add Phase D to Phase A with high shear mixing. (Formulation developed by S Black Ltd. UK)
30 min
1 hour
2 hours
3 hours
4 hours
5 hours
6 hours
T ime
Figure 2. Corneometer measurements of moisturization effect from a water-inoil formulation containing lauryl PEG/PPG-18/18 methicone emulsifier.
Figure 4 illustrates the wash-off resistance of a water-soluble sunscreen active in an oil-in-water formulation containing an organic emulsifier (cetyl
phosphate) and a water-in-oil system
formulated with lauryl PEG/PPG-18/18
methicone. The formulation containing
O/W
W/O
Wetness 99.9%
8.00
Slipperiness 99.9%
Spreadability 99.9%
7.00
6.00
5.00
4.00
3.00
2.00
1.00
0.00
Silkiness 99.9%
Absorbancy
Greasiness
Gloss
Film residue
60
53 %
50
40
30
20
<1%
10
0
O/W
W/O
Level (%)
(Dow
Corning 5225C*
Emulsifier
Oil phase
Water phase
and 9011)
Water-in-Oil Emulsions
(Dow Corning 5200*)
7 - 20
1-3
20 - 50
20 - 35
1-2
1-2
0.5
0.5
50 - 82
Electrolyte
(NaCl preferred)
Co-emulsifier
65 - 80
INCI Name
Cyclopentasiloxane
and PEG/PPG-18/18
Dimethicone
(Dow Corning 5225C)
Cyclopentasiloxane
and PEG-12
Dimethicone
Crosspolymer
(Dow Corning 9011)
Conclusions
New developments in silicone emulsifier
technology provide expanded options
for creating stable water-in-oil and waterin-silicone emulsions with a broad range
of sensory characteristics. In skin and
underarm products, these ingredients
give formulators flexibility for developing clear products with superior aesthetics
and novel forms such as anhydrous systems, multiple emulsions or water-inwax sticks. In addition, benefits of waterin-oil systems such as good sensory
profiles, improved wash-off resistance
and excellent moisturization have been
demonstrated. Silicone emulsifiers offer
versatility for low or high shear options
as well as cold processing, presenting
new opportunities for cost-effective and
highly innovative skin care and underarm
products.
References
Emulsion Type
Water-in-silicone,
multiple emulsions,
Water-in-silicone,
multiple emulsions
anhydrous emulsions
Water-in-oil,
Water-in-wax
% Actives
10%
12.5%
100%
Shear /
Processing
requirements
High shear
High shear
Use Levels
7-15%
6-14%
2-3%
Dow Corning
5225C
Dow Corning
9011
W/Si Systems
W/O Systems
X
X
Moisturizing, wash-off
resistant, long lasting creams
Multiple emulsions W/Si/W
Dow Corning
5200
X
X
X
X
Sci0212