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IPCC Waste Model
IPCC Waste Model
IPCC Waste Model
IPCC 2006
Introduction
This spreadsheet has been developed by the IPCC to enable countries to estimate emissions of methane from solid waste disposal
sites (SWDS) using the first order decay method. It also allows an estimation of the carbon stored in the SWDS by in the Harvested
Wood Products (HWP) category as well as methane from HWP in SWDS. See Volume 4 Chapter 12 for details.
Worksheets
Name
Instructions
Parameters
MCF
Activity
Amnt_Deposited
Recovery_OX
Results
Stored_C
HWP
Theory
Defaults
Food
Garden
Paper
Wood
Textiles
Nappies
Sludge
MSW
Industry
Details
(This worksheet) Step by step guidance for using the model
Data entry for parameters such as DOC and decay half-life
Data entry for distribution of waste management types (used to estimate a time series for the weighted average
methane correction factor)
Data entry for population and gross domestic product to estimate MSW and industrial waste generation
Data entry for waste amounts disposed (or calculated from Activity sheet)
Data entry for methane recovery
Displays results (methane generated and emitted)
Displays carbon stored in the SWDS
Displays carbon stored in the SWDS and methane emitted from Harvested Wood Products
Background to the First Order Decay theory, and equations used in the model
IPCC default values for methane generation rate constants by material type and climate zone, DOC values by
waste type, and waste generation, composition, and disposal by region
Calculations for food waste
Calculations for garden (yard) and park waste
Calculations for paper waste
Calculations for wood waste
Calculations for textiles waste
Calculations for nappies (disposable diapers)
Calculations for sludge waste
Calculations for bulk MSW
Calculations for industrial waste
1. Enter the country in the Parameters worksheet and select the appropriate region from the drop down menu. The region
selection will adjust the IPCC defaults in other worksheets based on values in the 2006 Guidelines.
2. Set the starting year for the calculations on the Parameters worksheet. The default starting year is 1950, but this can be
changed by the user if required. It is good practice to use a starting year of 1950 or earlier. If the starting year is set later than
1950, the inventory compiler should demonstrate that there will be no significant underestimation of emissions from waste
disposed of between 1950 and the starting year. For example, in hot, wet climates with shallow disposal sites, degradation may
be fast enough to justify the use of a later starting year. If you change the start year after you have entered activity data, you will
need to manually move the activity data to the correct year in the MCF, Activity, Amnt_Deposited, and Recovery_OX sheets, as
applicable.
3. Fill in the values for the parameters DOC, DOCf, methane generation rate constant, fraction to methane and oxidation rate, on
the Parameters sheet. Where no national data are available, use IPCC default values shown in the grey cells.
a. The drop-down menu in the DOC input area allows for selection of DOC and methane generation rate constant defaults
for modelling by waste composition or by bulk MSW. When using the bulk waste model and IPCC waste type/material
composition default values it is good practice to check that the national definition for MSW corresponds to the IPCC
default definition. Larger amounts of inert material (e.g., inclusion of construction and demolition waste in MSW) may
lead to overestimation of the emissions, or in the opposite case to underestimation. Also, it is of importance to keep
good track of waste composition when using the bulk waste option, both for determining new DOC values as waste
composition changes, and for HWP calculations. Nations using the bulk waste option, with DOC for MSW varying over
time, enter the DOC data directly onto the lightly coloured yellow DOC column in the "MSW" sheet. Make a notice of
this in the "Parameters" sheet.
b. The drop-down menu in the methane generation rate constant input area allows selection of the appropriate IPCC
default values for the selected climate zone. Guidance on the choice of values for these parameters is given in section
3.2.3 of the Guidelines (Choice of Emission Factors and Parameters).
c. Nations with oxidation rate (OX) varying over time, enter the OX data directly onto the lightly coloured yellow OX
column in the "Recovery_OX" sheet. Make a notice of this in the "Parameters" sheet.
4. Time Delay. Enter the "Delay time" (in "Parameters" worksheet). The default assumption is that the reaction starts on the first of
January in the year after deposition, which is equivalent to an average delay time of six months before decay to methane
commences ("Delay time" = 6). It is good practice to assume an average delay of from two to six months. If a value greater than
six months is chosen, evidence to support this must be provided. To make the model work for delay times from 7 to 18 months,
the number 13 in exp2 in all the methane calculating sheets has to be changed to 25, and DDOCmd in columns F and G has to
be readdressed one cell down.
5. Enter data on the approximate distribution of waste between different types of sites in the appropriate columns on the MCF
worksheet to calculate the weighted average MCF (Methane correction factor). Either IPCC default MCFs (pre-entered) or
country-specific values may be entered in the yellow cells at the top of the sheet (Row 13). Guidance on selecting a methane
correction factor is given in Volume 5, Section 3.2.3 of the Guidelines. The average methane correction factor may vary with time
according to changes in waste management practices. The distribution of waste disposed by management type also needs to be
entered in the "MCF" worksheet. Row 16 can be used to enter a fixed distribution to be used for all years. If management
Page 2 of 103
Page 3 of 103
Parameters
Country
Europe: Western
Region
Please enter parameters in the yellow cells. If no national data are available, copy the IPCC default value.
Help on parameter selection can be found in the 2006 IPCC guidelines
1950
Waste by composition
Range
0.08-0.20
0.18-0.22
0.36-0.45
0.39-0.46
0.20-0.40
0.18-0.32
0.04-0.05
Default
0.15
0.2
0.4
0.43
0.24
0.24
0.05
0-0.54
0.15
0.15
0.2
0.4
0.43
0.24
0.24
0.05
0
0.15
0.5
0.5
Country-specific parameters
Value
Reference and remarks
1950
Wet temperate
Range
0.10.2
0.060.1
0.050.07
0.020.04
0.050.07
0.060.1
0.10.2
Default
0.185
0.1
0.06
0.03
0.06
0.1
0.185
0.080.1
0.09
0.185
0.1
0.06
0.03
0.06
0.1
0.185
0
0.09
0.5
0.5
1.33
1.33
0%
0%
0%
0%
This worksheet calculates a weighted average MCF from the estimated distribution of site types
Enter either IPCC default values or national values into the yellow MCF cells in row 12
Then enter the approximate distribution of waste disposals (by mass) between site types in the column
Totals on each row must add up to 100% (see "distribution check" values)
MSW
IPCC default
Country-specific
value
UnUnmanaged, managed,
shallow
deep
Managed
MCF
MCF
MCF
0.4
0.8
1
0.4
0.8
Managed,
semiaerobic
MCF
0.5
Uncategorised
MCF
0.6
0.5
0.6
Distribution
Check
25%
%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
30%
%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
25%
%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
5%
%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
15%
Total
%
(100%)
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
15%
100%
Unmanaged,
shallow
MCF
0.4
0.4
Distribution of W
20%
%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
2026
2027
2028
2029
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
15%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
2030
25%
30%
25%
5%
15%
100%
20%
Calculated valu
Industrial
Unmanaged,
deep
MCF
0.8
0.8
Managed,
semiManaged
aerobic
MCF
MCF
1
0.5
1
0.5
Uncategorised
MCF
0.6
Distribution
Check
0.6
25%
%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
5%
%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
20%
Total
%
(100%)
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
20%
100%
References / remarks
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
30%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
25%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
20%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
30%
25%
5%
20%
100%
MSW
Industrial
Weighted
Weighted
average MCF
average MCF
for Industrial
for MSW
Waste
wt. fraction
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
wt. fraction
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.71
0.72
Enter population, waste per capita and MSW waste composition into the yellow cells.
Help and default regional values are given in the 2006 IPCC Guidelines.
Industrial waste activity data must be entered separately starting in Column Q.
IPCC Regional defaults
560
47%
24%
0%
28%
11%
0%
Composition of waste going to solid waste disposal sites
Year
Population
millions
1950
1951
1952
1953
1954
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
Waste
per
capita
kg/cap/yr
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
Total
MSW
Gg
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
% to
SWDS
%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
Food
%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
Garden
%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
Paper
%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
Wood
%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
Textile
%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
2026
2027
2028
2029
2030
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
560
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
5600
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
47%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
24%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
28%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
11%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
37%
solid waste disposal sites
Plastics,
other
Nappies
inert
%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
100%
Total
%
(=100%)
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
37%
100%
Year
1950
1951
1952
1953
1954
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
GDP
$ millions
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Waste
Total
generation industrial
rate
waste
Gg/$m
GDP/yr
Gg
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
5
500
% to
SWDS
%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
0%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
37%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
2026
2027
2028
2029
2030
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
100%
Total to
SWDS
Gg
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
Country
Food
Gg
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
Garden
Gg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Paper
Gg
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
Wood
Gg
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
Textile
Gg
Nappies
Gg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Sludge
Gg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
2026
2027
2028
2029
2030
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
DS
Deposited
MSW
Gg
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
Inert
Industrial
Gg
Gg
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
982
500
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
982
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
References / remarks
Fraction
recovered
methane
Methane
oxidised
(OX)
0
Gg
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Fraction
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
2026
2027
2028
2029
2030
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.07
0.07
0.07
0.07
0.07
0.07
0.07
0.07
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
References/remarks
Results
Country
0
Enter starting year, industrial waste disposal data and methane recovery into the yellow cells.
MSW activity data is entered on MSW sheet
Methane generated
Year
1950
1951
1952
1953
1954
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
1975
1976
1977
1978
1979
1980
1981
1982
1983
Food
Garden
Paper
Wood
Textile
Nappies
Sludge
MSW
Gg
Gg
Gg
Gg
Gg
Gg
Gg
Gg
0
4
7
10
12
14
15
16
17
18
19
20
20
20
21
21
21
21
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4
8
11
15
18
21
23
26
28
31
33
35
37
39
40
42
44
45
46
48
49
50
51
52
53
54
55
55
56
57
57
58
59
0
1
2
3
3
4
5
6
6
7
8
8
9
9
10
11
11
12
12
13
13
14
14
15
15
15
16
16
17
17
17
18
18
18
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
2026
2027
2028
2029
2030
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
59
60
60
61
61
61
62
62
63
63
63
63
64
64
64
64
65
65
65
65
65
66
66
66
66
66
66
66
66
66
67
67
67
67
67
67
67
67
67
67
67
67
67
67
67
67
67
19
19
19
20
20
20
20
21
21
21
21
22
22
22
22
23
23
23
23
23
23
24
24
24
24
24
24
25
25
25
25
25
25
25
25
26
26
26
26
26
26
26
26
26
26
27
27
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Industrial
Total
Methane
recovery
Methane
emission
M = (K-L)*(1OX)
Gg
Gg
Gg
Gg
0
2
3
4
5
6
7
8
9
10
11
11
12
12
13
13
14
14
14
15
15
15
15
16
16
16
16
16
16
17
17
17
17
17
0
10
19
28
35
42
48
54
59
63
68
72
76
79
82
85
88
91
93
95
98
100
101
103
105
107
108
109
111
112
113
114
115
116
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
10
19
28
35
42
48
54
59
63
68
72
76
79
82
85
88
91
93
95
98
100
101
103
105
107
108
109
111
112
113
114
115
116
17
17
17
17
17
17
17
17
17
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
117
118
119
120
121
121
122
123
123
124
125
125
126
126
127
127
128
128
128
129
129
129
130
130
130
131
131
131
131
132
132
132
132
132
133
133
133
133
133
133
134
134
134
134
134
134
134
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
117
118
119
120
121
121
122
123
123
124
125
125
126
126
127
127
118
118
118
119
119
119
120
120
120
121
121
121
121
122
122
122
122
122
123
123
123
123
123
123
124
124
124
124
124
124
124
Year
1950
1951
1952
1953
1954
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
Long-term stored C
Long term stored C accumulated
Garden C Paper C Wood C Garden C Paper C
Wood C
Gg
Gg
Gg
Gg
Gg
Gg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
102
204
306
408
510
612
714
816
919
1,021
1,123
1,225
1,327
1,429
1,531
1,633
1,735
1,837
1,939
2,041
2,143
2,245
2,347
2,449
2,551
2,653
2,756
2,858
2,960
3,062
3,164
3,266
3,368
3,470
3,572
3,674
3,776
3,878
3,980
44
88
132
176
219
263
307
351
395
439
483
527
570
614
658
702
746
790
834
878
922
965
1,009
1,053
1,097
1,141
1,185
1,229
1,273
1,317
1,360
1,404
1,448
1,492
1,536
1,580
1,624
1,668
1,711
CH4 generated
Garden
Paper
Gg
Gg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4
8
11
15
18
21
23
26
28
31
33
35
37
39
40
42
44
45
46
48
49
50
51
52
53
54
55
55
56
57
57
58
59
59
60
60
61
61
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
2026
2027
2028
2029
2030
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4,082
4,184
4,286
4,388
4,490
4,593
4,695
4,797
4,899
5,001
5,103
5,205
5,307
5,409
5,511
5,613
5,715
5,817
5,919
6,021
6,123
6,225
6,327
6,430
6,532
6,634
6,736
6,838
6,940
7,042
7,144
7,246
7,348
7,450
7,552
7,654
7,756
7,858
7,960
8,062
8,164
8,267
1,755
1,799
1,843
1,887
1,931
1,975
2,019
2,063
2,106
2,150
2,194
2,238
2,282
2,326
2,370
2,414
2,458
2,501
2,545
2,589
2,633
2,677
2,721
2,765
2,809
2,852
2,896
2,940
2,984
3,028
3,072
3,116
3,160
3,204
3,247
3,291
3,335
3,379
3,423
3,467
3,511
3,555
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
61
62
62
63
63
63
63
64
64
64
64
65
65
65
65
65
66
66
66
66
66
66
66
66
66
67
67
67
67
67
67
67
67
67
67
67
67
67
67
67
67
67
H4 generated
Wood
Gg
0
1
2
3
3
4
5
6
6
7
8
8
9
9
10
11
11
12
12
13
13
14
14
15
15
15
16
16
17
17
17
18
18
18
19
19
19
20
20
Garden
Gg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CH4 emitted
Paper
Wood
Gg
Gg
0
4
8
11
15
18
21
23
26
28
31
33
35
37
39
40
42
44
45
46
48
49
50
51
52
53
54
55
55
56
57
57
58
59
59
60
60
61
61
0
1
2
3
3
4
5
6
6
7
8
8
9
9
10
11
11
12
12
13
13
14
14
15
15
15
16
16
17
17
17
18
18
18
19
19
19
20
20
20
20
21
21
21
21
22
22
22
22
23
23
23
23
23
23
24
24
24
24
24
24
25
25
25
25
25
25
25
25
26
26
26
26
26
26
26
26
26
26
27
27
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
61
62
62
63
63
63
63
64
64
64
64
60
60
60
60
60
60
61
61
61
61
61
61
61
61
62
62
62
62
62
62
62
62
62
62
62
62
62
62
62
62
62
20
20
21
21
21
21
22
22
22
22
23
21
21
21
21
22
22
22
22
22
22
23
23
23
23
23
23
23
23
24
24
24
24
24
24
24
24
24
24
24
25
25
Country
Year
1950
1951
1952
1953
1954
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
MSW
Gg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.4
0.43
Food waste
Garden
Textiles
0.15
0.2
0.24
Nappies
Sludge
Industry
Food
Gg
Garden
Gg
Paper
Gg
Wood
Gg
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
0.24
0.05
0.15
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1987
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
2026
2027
2028
2029
2030
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Paper,
Wood,
C,
industry industry
Industry subtotal subtotal
Gg
Gg
Gg
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Long-term
stored C
Gg
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
Long-term
stored C
accumulated
Gg
206
413
619
826
1,032
1,239
1,445
1,651
1,858
2,064
2,271
2,477
2,684
2,890
3,096
3,303
3,509
3,716
3,922
4,129
4,335
4,541
4,748
4,954
5,161
5,367
5,574
5,780
5,986
6,193
6,399
6,606
6,812
7,019
7,225
7,432
7,638
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
206
7,844
8,051
8,257
8,464
8,670
8,877
9,083
9,289
9,496
9,702
9,909
10,115
10,322
10,528
10,734
10,941
11,147
11,354
11,560
11,767
11,973
12,179
12,386
12,592
12,799
13,005
13,212
13,418
13,624
13,831
14,037
14,244
14,450
14,657
14,863
15,069
15,276
15,482
15,689
15,895
16,102
16,308
16,514
16,721
IPCC Spreadsheet for Estimating Methane emissions from Solid Waste Disposal Sites
where DDOCm(0) is the mass of decomposable degradable organic carbon (DOC) at the start of the
reaction, when t=0 and e^-kt=1, k is the reaction constant and t is the time in years. DDOCm is the mass of
DDOC at any time.
From equation (I) it is easy to see that at the end of year 1 (going from point 0 to point 1 on the time axis)
the mass of DDOC left not decomposed in the SWDS is:
(2)
and the mass of DDOC decomposed into CH4 and CO2 will be:
(3)
In a first order reaction, the amount of product (here decomposed DDOCm) is always proportional to the
amount of reactant (here DDOCm). This means that it does not matter when the DDOCm was deposited.
This also means that when the amount of DDOCm accumulated in the SWDS, plus last year's deposit, is
known, CH4 production can be calculated as if every year is year number one in the time series. Then all
calculations can be done by equations (2) and (3) in a simple spreadsheet.
The default assumption is that CH4 generation from all the waste deposited each year begins on the 1st of
January in the year after deposition. This is the same as an average six month delay until substantial CH 4
generation begins (the time it takes for anaerobic conditions to become well established). However, the
worksheet includes the possibility of an earlier start to the reaction, in the year of deposition of the waste.
This requires separate calculations for the deposition year. For longer delay times than 6 months, DDOCmd
in the columns F and G cells in the CH4 calculating sheets, have to be readdressed one cell down, and the
number 13 in exp2 has to be changed to 25 (7 to 18 months delay time).
The equations used in these spreadsheets are: (As the mathematics of every waste fraction/category is the
same, indexing for fraction/category is omitted for equations 4-9.)
To calculate mass of decomposable DOC (DDOCm) from amount of waste material (W):
(4) DDOCmd(T), = W(T) DOC * DOCf
MCF
The amount of deposited DDOCm remaining not decomposed at the end of deposition year T:
(5) DDOCmrem(T) = DDOCmd(T) e^(-k ((13-M)/12)
The amount of deposited DDOCm decomposed during deposition year T:
(6) DDOCmdec(T) = DDOCmd(T) (1 e^(-k ((13-M)/12)))
The amount of DDOCm accumulated in the SWDS at the end of year T
(7) DDOCma(T) = DDOCmrem(T) + ( DDOCma(T-1) e^-k)
The total amount of DDOCm decomposed in year T
(8) DDOCmdecomp(T) = DDOCmdec(T) + (DDOCma(T-1) (1 - e^-k))
The amount of CH4 generated from DOC decomposed
(9) CH4 generated(T) = DDOCmdecomp(T) F 16/12
The amount of CH4 emitted
(10) CH4 emitted in year T = (xCH4 generated (x,T) R(T)) (1- OX(T))
Type of Waste
Dry
Default Value
Trop
Wet
Dry
0.04
0.030.05
Default
Value
0.06
0.02
0.010.03
0.03
0.020.04
0.025
0.05
0.040.06
0.1
0.060.1
0.065
0.06
0.050.08
0.185
0.10.2
0.085
0.05
0.040.06
0.09
0.080.1
0.065
Range
0.050.07
Default
Value
0.045
Range
1
2
3
4
Dry temperate
Wet temperate
Dry tropical
Moist and wet
tropical
MAT
0 - 20C
0 - 20C
> 20C
MAP
> 20C
>1000 mm
MAP/PET
<1
>1
Selected:
2
<1000 mm
35
Decay rate
constant (y-1)
0.05
0.020
Half life (years)
13.863
Tropical
Dry
Range
0.040.06
Default
Value
0.15
Food waste
0.020.04
0.035
0.030.05
Garden
0.2
0.050.08
0.17
0.150.2
Paper
0.4
0.070.1
0.4
0.170.7
0.43
0.050.08
0.17
0.150.2
Textiles
0.24
Disposable
nappies
Sewage sludge
Rubber
Bulk MSW waste
0.24
Industrial waste
0.15
0.05
0.39
0.18
Select2:
1
1
OC VALUES
Default DOC
Select3
0.4
13
0.24
Percen
Paper/ card
board
Range
Textiles
0.08-0.20
1 Asia: Eastern
18.8
3.5
0.18-0.22
2 Asia: South-central
11.3
2.5
0.36-0.45
3 Asia- Southeast
12.9
2.7
0.39-0.46
18.0
2.9
0.20-0.40
7.7
1.7
0.18-0.32
6 Africa: Middle
16.8
2.5
0.04-0.05
0.39
0.12-0.28
7 Africa: Northern
8 Africa: Southern
9 Africa: Western
16.5
25.0
9.8
2.5
Europe: Eastern
Europe: Northern
Europe: Southern
Europe: Western
21.8
30.6
17.0
27.5
4.7
2.0
30.0
0-0.54
Waste by composition
Bulk waste data only
10
11
12
13
1.0
6.0
23.2
13.7
17.1
17.0
3.9
2.6
2.6
5.1
17.9
17.7%
2.9
2.8%
0.15
Food
waste
0.43
0.2
0.24
0.05
Sewage
sludge
0.39
Rubber /
leather
MSW
Generation Fraction
Rate
MSW
All other, (tonnes/cap/ disposed
inerts
yr)
to SWDS
26.2
3.5
1.0
47.0
0.55
0.55
40.3
7.9
0.8
37.2
0.21
0.74
43.5
9.9
0.9
30.1
0.27
0.59
41.1
9.8
0.6
27.6
0.42
0.68
53.9
7.0
1.1
28.6
0.29
0.69
43.4
6.5
30.8
0.29
0.69
51.1
23.0
40.4
2.0
15.0
4.4
27.9
37.0
44.4
0.29
0.29
0.29
0.69
0.69
0.69
30.1
23.8
36.9
24.2
7.5
10.0
10.6
11.0
34.5
33.6
35.5
37.3
0.38
0.64
0.52
0.56
0.90
0.47
0.85
0.47
36.0
24.0
10.0
0.69
0.85
67.5
2.5
24.0
0.69
0.85
33.9
43.8
44.9
46.9
6.2
13.5
4.7
2.4
1.4
1.8
0.7
1.9
31.4
24.6
30.0
26.7
0.65
0.21
0.26
0.49
0.58
0.50
0.54
0.83
39.5
39.0%
8.3
8.2%
1.2
1.1%
31.5
31.1%
101.3
1.4
0.0%
0.0%
0.0%
Averages
0.42
0.68
Regional
Average
DOC (wt
fraction)
0.14
0.15
0.17
0.19
0.15
0.17
0.16
0.20
0.12
0.18
0.21
0.17
0.19
0.28
0.14
0.19
0.19
0.16
0.17
0.18
DOC
DOCf
Methane generation rate constant
Half-life time (t1/2, years):
DOC
DOCf
k
h = ln(2)/k
exp1
Process start in deposition year. Month M
exp2
Fraction to CH4
exp(-k)
M
exp(-k*((13-M)/12))
F
3.7
0.83
13.00
1.00
0.500
MCF
DDOCm
Decomposa DDOCm not decompose
DDOCm
ble DOC
reacted.
d.
accumulated in
(DDOCm) Deposition Deposition SWDS end of
deposited
year
year
year
MCF
D = W * DOC *
DOCf * MCF
B = D * exp2
C = D * (1exp2)
H = B + (Hlast year *
exp1)
E = C + Hlast year *
(1 - exp1)
Gg
fraction
Gg
Gg
Gg
Gg
Gg
Amount
Year deposited
1950
1951
1952
1953
1954
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
1975
1976
1977
1978
National
values
0.15
0.500
0.185
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
34
62
85
104
120
134
145
154
162
168
173
178
181
184
187
189
191
192
193
194
195
196
197
197
197
198
198
198
198
DDOCm
decomposed
0
6
10
14
18
20
23
24
26
27
28
29
30
31
31
32
32
32
32
33
33
33
33
33
33
33
33
33
33
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
2026
2027
2028
2029
2030
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
637
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
199
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
34
CH4
generated
Q = E * 16/12
*F
Gg
0
4
7
10
12
14
15
16
17
18
19
20
20
20
21
21
21
21
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
DOC
DOCf
Methane generation rate constant
Half-life time (t1/2, years):
DOC
DOCf
k
6.9
0.90
13.00
1.00
0.500
h = ln(2)/k
exp1
Process start in deposition year. Month M
exp2
Fraction to CH4
exp(-k)
M
exp(-k*((13-M)/12))
F
MCF
DDOCm
Decomposa DDOCm not decompose
DDOCm
ble DOC
reacted.
d.
accumulated in
(DDOCm) Deposition Deposition SWDS end of
deposited
year
year
year
MCF
D = W * DOC *
DOCf * MCF
B = D * exp2
C = D * (1exp2)
H = B + (Hlast year *
exp1)
E = C + Hlast year *
(1 - exp1)
Gg
fraction
Gg
Gg
Gg
Gg
Gg
Amount
Year deposited
1950
1951
1952
1953
1954
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
National
values
0.2
0.500
0.100
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
DDOCm
decomposed
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2026
2027
2028
2029
2030
0
0
0
0
0
0.71
0.71
0.71
0.71
0.71
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CH4
generated
Q = E * 16/12
*F
Gg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
DOC
DOCf
Methane generation rate constant
Half-life time (t1/2, years):
DOC
DOCf
k
h = ln(2)/k
exp1
Process start in deposition year. Month M
exp2
Fraction to CH4
exp(-k)
M
exp(-k*((13-M)/12))
F
11.6
0.94
13.00
1.00
0.500
MCF
DDOCm
Decomposa DDOCm not decompose
DDOCm
ble DOC
reacted.
d.
accumulated in
(DDOCm) Deposition Deposition SWDS end of
DDOCm
deposited
year
year
year
decomposed
MCF
D = W * DOC *
DOCf * MCF
B = D * exp2
C = D * (1exp2)
H = B + (Hlast year *
exp1)
E = C + Hlast year *
(1 - exp1)
Gg
fraction
Gg
Gg
Gg
Gg
Gg
Amount
Year deposited
1950
1951
1952
1953
1954
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
National
values
0.4
0.500
0.060
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
102
198
289
374
454
530
601
668
731
791
847
899
949
996
1,040
1,081
1,121
1,157
1,192
1,225
1,255
1,284
1,312
1,337
1,361
0
6
12
17
22
26
31
35
39
43
46
49
52
55
58
61
63
65
67
69
71
73
75
76
78
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
724
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
102
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,384
1,406
1,426
1,445
1,463
1,480
1,496
1,511
1,525
1,538
1,550
1,562
1,573
1,584
1,593
1,603
1,611
1,620
1,627
1,635
1,642
1,648
1,654
1,660
1,665
1,670
1,675
1,680
1,684
1,688
1,692
1,695
1,698
1,702
1,705
1,707
1,710
1,712
1,715
1,717
1,719
1,721
1,723
1,725
1,726
1,728
1,729
1,731
1,732
1,733
1,734
79
81
82
83
84
85
86
87
88
89
90
90
91
92
92
93
93
94
94
95
95
96
96
96
97
97
97
98
98
98
98
99
99
99
99
99
99
100
100
100
100
100
100
100
100
101
101
101
101
101
101
2026
2027
2028
2029
2030
724
724
724
724
724
0.71
0.71
0.71
0.71
0.71
102
102
102
102
102
102
102
102
102
102
0
0
0
0
0
1,735
1,736
1,737
1,738
1,739
101
101
101
101
101
CH4
generated
Q = E * 16/12
*F
Gg
0
4
8
11
15
18
21
23
26
28
31
33
35
37
39
40
42
44
45
46
48
49
50
51
52
53
54
55
55
56
57
57
58
59
59
60
60
61
61
61
62
62
63
63
63
63
64
64
64
64
65
65
65
65
65
66
66
66
66
66
66
66
66
66
67
67
67
67
67
67
67
67
67
67
67
67
67
67
67
67
67
DOC
DOCf
Methane generation rate constant
Half-life time (t1/2, years):
DOC
DOCf
k
h = ln(2)/k
exp1
Process start in deposition year. Month M
exp2
Fraction to CH4
exp(-k)
M
exp(-k*((13-M)/12))
F
23.1
0.97
13.00
1.00
0.500
MCF
DDOCm
Decomposa DDOCm not decompose
DDOCm
ble DOC
reacted.
d.
accumulated in
(DDOCm) Deposition Deposition SWDS end of
DDOCm
deposited
year
year
year
decomposed
MCF
D = W * DOC *
DOCf * MCF
B = D * exp2
C = D * (1exp2)
H = B + (Hlast year *
exp1)
E = C + Hlast year *
(1 - exp1)
Gg
fraction
Gg
Gg
Gg
Gg
Gg
Amount
Year deposited
1950
1951
1952
1953
1954
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
National
values
0.43
0.500
0.030
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
44
86
128
168
207
245
281
317
351
385
417
449
480
509
538
566
593
620
645
670
694
717
740
762
783
0
1
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
18
19
20
21
21
22
23
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
290
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
804
824
844
863
881
899
916
933
949
965
981
996
1,010
1,024
1,038
1,051
1,064
1,076
1,088
1,100
1,111
1,122
1,133
1,143
1,154
1,163
1,173
1,182
1,191
1,200
1,208
1,216
1,224
1,232
1,239
1,247
1,254
1,261
1,267
1,274
1,280
1,286
1,292
1,297
1,303
1,308
1,314
1,319
1,324
1,328
1,333
23
24
24
25
25
26
27
27
28
28
29
29
29
30
30
31
31
31
32
32
33
33
33
33
34
34
34
35
35
35
35
36
36
36
36
37
37
37
37
37
38
38
38
38
38
39
39
39
39
39
39
2026
2027
2028
2029
2030
290
290
290
290
290
0.71
0.71
0.71
0.71
0.71
44
44
44
44
44
44
44
44
44
44
0
0
0
0
0
1,337
1,342
1,346
1,350
1,354
39
40
40
40
40
CH4
generated
Q = E * 16/12
*F
Gg
0
1
2
3
3
4
5
6
6
7
8
8
9
9
10
11
11
12
12
13
13
14
14
15
15
15
16
16
17
17
17
18
18
18
19
19
19
20
20
20
20
21
21
21
21
22
22
22
22
23
23
23
23
23
23
24
24
24
24
24
24
25
25
25
25
25
25
25
25
26
26
26
26
26
26
26
26
26
26
27
27
DOC
DOCf
Methane generation rate constant
Half-life time (t1/2, years):
DOC
DOCf
k
11.6
0.94
13.00
1.00
0.500
h = ln(2)/k
exp1
Process start in deposition year. Month M
exp2
Fraction to CH4
exp(-k)
M
exp(-k*((13-M)/12))
F
MCF
DDOCm
Decomposa DDOCm not decompose
DDOCm
ble DOC
reacted.
d.
accumulated in
(DDOCm) Deposition Deposition SWDS end of
DDOCm
deposited
year
year
year
decomposed
MCF
D = W * DOC *
DOCf * MCF
B = D * exp2
C = D * (1exp2)
H = B + (Hlast year *
exp1)
E = C + Hlast year *
(1 - exp1)
Gg
fraction
Gg
Gg
Gg
Gg
Gg
Amount
Year deposited
1950
1951
1952
1953
1954
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
National
values
0.24
0.500
0.060
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2026
2027
2028
2029
2030
0
0
0
0
0
0.71
0.71
0.71
0.71
0.71
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CH4
generated
Q = E * 16/12
*F
Gg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
DOC
DOCf
Methane generation rate constant
Half-life time (t1/2, years):
DOC
DOCf
k
6.9
0.90
13.00
1.00
0.500
h = ln(2)/k
exp1
Process start in deposition year. Month M
exp2
Fraction to CH4
exp(-k)
M
exp(-k*((13-M)/12))
F
MCF
DDOCm
Decomposa DDOCm not decompose
DDOCm
ble DOC
reacted.
d.
accumulated in
(DDOCm) Deposition Deposition SWDS end of
DDOCm
deposited
year
year
year
decomposed
MCF
D = W * DOC *
DOCf * MCF
B = D * exp2
C = D * (1exp2)
H = B + (Hlast year *
exp1)
E = C + Hlast year *
(1 - exp1)
Gg
fraction
Gg
Gg
Gg
Gg
Gg
Amount
Year deposited
1950
1951
1952
1953
1954
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
National
values
0.24
0.500
0.100
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2026
2027
2028
2029
2030
0
0
0
0
0
0.71
0.71
0.71
0.71
0.71
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CH4
generated
Q = E * 16/12
*F
Gg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
DOC
DOCf
Methane generation rate constant
Half-life time (t1/2, years):
DOC
DOCf
k
3.7
0.83
13.00
1.00
0.500
h = ln(2)/k
exp1
Process start in deposition year. Month M
exp2
Fraction to CH4
exp(-k)
M
exp(-k*((13-M)/12))
F
MCF
DDOCm
Decomposa DDOCm not decompose
DDOCm
ble DOC
reacted.
d.
accumulated in
(DDOCm) Deposition Deposition SWDS end of
DDOCm
deposited
year
year
year
decomposed
MCF
D = W * DOC *
DOCf * MCF
B = D * exp2
C = D * (1exp2)
H = B + (Hlast year *
exp1)
E = C + Hlast year *
(1 - exp1)
Gg
fraction
Gg
Gg
Gg
Gg
Gg
Amount
Year deposited
1950
1951
1952
1953
1954
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
National
values
0.05
0.500
0.185
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2026
2027
2028
2029
2030
0
0
0
0
0
0.71
0.71
0.71
0.71
0.71
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CH4
generated
Q = E * 16/12
*F
Gg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
DOC
DOCf
Methane generation rate constant
Half-life time (t1/2, years):
DOC
DOCf
k
Gg
1950
1951
1952
1953
1954
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
7.7
0.91
13.00
1.00
0.500
h = ln(2)/k
exp1
Process start in deposition year. Month M
exp2
Fraction to CH4
Amount
Year deposited
National
values
0
0.500
0.090
exp(-k)
M
exp(-k*((13-M)/12))
F
MCF
DOC
MCF
DOC
D = W * DOC *
DOCf * MCF
B = D * exp2
C = D * (1- exp2)
H = B + (Hlast year *
exp1)
E = C + Hlast year *
(1 - exp1)
Gg
Gg
Gg
Gg
Gg
fraction fraction
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
DDOCm
accumulated
in SWDS end
DDOCm
of year
decomposed
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
2,632
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2026
2027
2028
2029
2030
2,632
2,632
2,632
2,632
2,632
0.71
0.71
0.71
0.71
0.71
0.00
0.00
0.00
0.00
0.00
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CH4
generated
Q = E * 16/12
*F
Gg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
DOC
exp1
Process start in deposition year. Month M
exp2
Fraction to CH4
exp(-k)
DOCf
k
h = ln(2)/k
M
exp(-k*((13-M)/12))
F
7.7
0.91
13.00
1.00
0.500
MCF
DDOCm
Decomposa DDOCm not decompose
DDOCm
ble DOC
reacted.
d.
accumulated in
(DDOCm) Deposition Deposition SWDS end of
deposited
year
year
year
MCF
D = W * DOC *
DOCf * MCF
B = D * exp2
C = D * (1exp2)
H = B + (Hlast year *
exp1)
E = C + Hlast year *
(1 - exp1)
Gg
fraction
Gg
Gg
Gg
Gg
Gg
Amount
Year deposited
1950
1951
1952
1953
1954
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
DOC
DOCf
Methane generation rate constant
Half-life time (t1/2, years):
National
values
0.150
0.500
0.090
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
27
51
74
94
113
130
146
160
173
185
196
206
215
223
231
238
244
250
255
260
264
269
272
276
279
DDOCm
decomposed
0
2
4
6
8
10
11
13
14
15
16
17
18
18
19
20
20
21
22
22
22
23
23
23
24
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
282
284
286
289
291
292
294
296
297
298
299
300
301
302
303
304
304
305
306
306
307
307
307
308
308
308
309
309
309
309
310
310
310
310
310
310
310
310
311
311
311
311
311
311
311
311
311
311
311
311
311
24
24
24
25
25
25
25
25
25
26
26
26
26
26
26
26
26
26
26
26
26
26
26
26
26
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
27
2026
2027
2028
2029
2030
500
500
500
500
500
0.72
0.72
0.72
0.72
0.72
27
27
27
27
27
27
27
27
27
27
0
0
0
0
0
311
311
311
311
311
27
27
27
27
27
CH4
generated
Q = E * 16/12
*F
Gg
0
2
3
4
5
6
7
8
9
10
11
11
12
12
13
13
14
14
14
15
15
15
15
16
16
16
16
16
16
17
17
17
17
17
17
17
17
17
17
17
17
17
17
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18