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13.2 IP Calculating Heat of Reactions

Hess Law use Hess Law to determine H for each reaction given
the step equations and their H values.
1. Reaction: 2CO2(g)+ H2O(g) C2H2(g) + 5/2 O2(g)
C2H2 (g) +2 H2 (g) C2H6 (g)
H2O (g) H2 (g) + O2 (g)
C2H6 (g) + 7/2 O2 (g) 2 CO2 (g) + 3 H2O (g)

H = -94.5
kJ
H = 71.2
kJ
H = -283
kJ

SUM =

2. Reaction: H2SO4 (l) SO3 (g) + H2O (g)

H2S (g) + 2 O2 (g) H2SO4 (l)

H =
-235.5 kJ

H2S (g) + 2 O2 (g) SO3 (g) + H2O (l)

H = -207
kJ

H2O (l) H2O (g)

H = 44 kJ

SUM =

3. Reaction: N2 (g) + 2 O2 (g) 2 NO2 (g)

N2 (g) + 3 H2 (g) 2 NH3 (g)

H = -115
kJ

2 NH3 (g) + 4 H2O (l) 2 NO2 (g) + 7 H2 (g)

H =
-142.5 kJ

H2O (l) H2 (g) + O2 (g)

H = -43.7
kJ

SUM =

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Standard EnthalpiesUse the standard enthaplies of formation to

calculate the H for each reaction.

4. NaOH(s) + HCl(g) ----> NaCl(s) + H2O(g)

5. 2 CO(g) + O2(g) ---> 2 CO2(g)

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6. 2 H2S(g) + 3 O2(g) ---> 2 H2O(l) + 2 SO2(g)

Bond Energies Use the bond energies to determine the H of each
reaction.

7.

8.

Use bond energies to calculate the

heat of reaction

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