AFI

Type Material [Al11.8P9.4Si3.8O48] : rR: wH2O

Batch Composition 0.15 cHA : 0.25 [(CH3)2CHO]3Al : 0.25 H3PO4: 13 H2O 0.5 SiO2
Sumber

aluminum isopropoxide (Aldrich, 98+%)

phosphoric acid (Aldrich A.C.S. grade, 85% H 3PO4)
cyclohexylamine (cHA)(Aldrich, 99+%)
silica sol (Dupont Ludox AS-40, 40% SiO2)

Sumber
komposisi
Al
alumunium isopropoxide (C9H21O3Al)
H2O

98%
2%

SiO2
H2O

40%
60%

H3PO4
H2O

85%
15%

CHA

CHA
H2O

99%
1%

H2O

H2O
ready
needed

Si

C9H21O3Al

SiO2

mol

2O 0.5 SiO2
0.25

molar weight
MW

mol

gram

1/35 prosedur

204.25
0.25 51.0625
18.0152 0.057845 1.042092
Total
52.10459

1.4589285714
0.0297740525
1.4887026239

60.0843
18.0152

0.5 30.04215
2.5014 45.06323
Total
75.10538

0.8583471429
1.2875207143
2.1458678571

97.994
0.25 24.4985
18.0152 0.239979 4.323265
Total
28.82176

0.6999571429
0.1235218487
0.8234789916

99.17
0.15 14.8755
18.0152 0.008341 0.150258
Total
15.02576

0.4250142857
0.0042930736
0.4293073593

18.0152

13 234.1976
2.807565
10.19244 183.6188

6.69136
5.2462503109

0.5

H3PO4

H2O

0.25

CHA

13

0.15

Batch Preparation (for 1 g product) b

(1) [4 g water + 1.44 g aluminum isopropoxide]; make slurry
(2) [1.2 g water + 0.81 g phosphoric acid]; mix

(3) [(1) + (2)]; add diluted phosphoric acid dropwise to the aluminum isopropoxide slurry. Stir and age the
(4) [(3) + 0.42 g cHA]; add cHA dropwise. A viscous gel results. Stir and age for 90 minutes

(5) [(4) + 2.13 g silica sol]; check to see that gel (4) is homogeneous, then add silica sol and stir for 10 m

sopropoxide slurry. Stir and age the gel for one hour to ensure homogeneity

nd age for 90 minutes

then add silica sol and stir for 10 minutes