XC NH COD

II Ha cht
Hn hp acid H2SO4 c v Ag2SO4: cho 500ml acid H2SO4 v 2,75g Ag2SO4.
Dung dch K2Cr2O7 0,25N: cn 12,259g K2Cr2O7 cho vo 1l nc.
Dung dch mui FAS 0,025N: cn 9,8g FAS cho vo 1l H2O thm 2ml acid H2SO4 c
trong chai bc bng giy nhm.
III Cch tin hnh
Chun b mu trng: Ly 3ml dung dch acid H2SO4 c v Ag2SO4 + 1ml K2Cr2O7 0,25N
+ 2ml nc ct, un 150oC trong 2h v ngui.
Chun b nc mu: Ly 3ml dung dch acid H2SO4 c v Ag2SO4 + 1ml K2Cr2O7 0,25N
+ 2ml nc thi (ly nc thi ln lt theo tng cc c nh s theo quy trnh lm th
nghim), un 150oC trong 2h, ngui.
Xc nh COD:
Cho mu nc ngui vo bnh nn, thm 2-3 git feroin ri chun bng dung dch
mui FAS cho n khi dung dch chuyn t mu xanh qua nu th dng li. Ghi th tch
mui FAS tiu tn.
Gi tr COD c xc nh theo cng thc sau:

COD

trang

Vmau .1000.8.N FAS

2(ml )

Trong :
Vtrang l th tch FAS tiu tn i vi mu trng
Vmau l th tch FAS tiu tn i vi mu nc thi.
Mui FAS khng bn nn cn chun xc nh li nng mui FAS trc khi tin
hnh th nghim: Cho 1ml K2Cr2O7 0,25N + 3ml H2SO4 tinh khit + 2-3 git feroin cho vo
bnh nn. Dng dung dch FAS chun ti khi mu nu xut hin th dng li. Nng
FAS chun li tnh theo cng thc:

N FAS

0, 25
VFAS