Basis

1000 kg
in

Komponen

BM

F
Massa
Mol
850 7.083333
150
0
0
0
0
0
0
0
0
1000 7.083333

Xf
FeS2
inert
O2
N2
Fe2O3
SO2

120

0.85
0.15
0
0
0
0
1

32
28
160
64
TOTAL

U
Massa

Xf

0
0
0
0
0.21
1870
0.79 6155.417
0
0
0
0
1 8025.417

Reaksi
4 FeS2
+ 11 O2----> 2 Fe2O3 + 8 SO2
7.083333 19.4791667
Neraca energi menggunakan reference
Senyawa
TC
H=?

H H

298

25

H
Ref

H1=

Unsur pd 25C
Href = 0

Hf298

Perhitungan

H arus m assa

Senyawa
pada 25C

Hf298
in

Komponen
FeS2
inert
O2
N2
Fe2O3
SO2
Total

F
Mol
7.083333
0
0
0
0

Cp d

Hf (kJ/mol)

Hf (kJ)

-177.9
0
0
0
0

-1260.125

Mol

Hf (kJ/mol)

Hf (kJ)

0 58.4375
0 219.8363
0
0
0
0
-1260.125

0
0
0
0

0
0
0
0
0

Perhitungan H sensible
TABEL Cp
Komponen a
b
c
d
FeS2
78
0
0
0
O2
29.1
0.01158 -6.08E-006 1.31E-009
N2
29
0.002199 5.723E-006 -2.9E-009
Fe2O3
103.4
0.06711 -1772000
0
SO2
38.91
0.03904 -3.10E-005 8.61E-009

Pers
1
1
1
2
1

n i. H

in
Komponen
FeS2
inert
O2
N2
Fe2O3
SO2
Total

Hf total
Hstotal
H total

F
Mol
7.083333
150
0
0
0
0

Cp dT

Hs(J)

0
0
0
0
0
0

F
U
-1260.125
0
-1260.125

Q=H = Hout - Hin =

U
Mol
0
0
0
0
0 58.4375
0 219.8363
0
0
0
0
0
C

P
0 -2855.361 -4062.352
0 6.22830067 128.3086
0 -2849.1327 -3934.044

-5523.0513 kJ

Cp dT

Hs(J)

0
0
0
0
0
0

0
0
0
0
0
0
0

U
Mol

H H

298

Mol
Xf
Mol
Xf
-4 -6.84128
0
0
0 0.03998956
0
0
0
0
0 0.20651236
-11 -18.81352 0.152784 1267.9673 39.62398
0
0
0
0.7417 6155.4167 219.8363
0
2 3.42064
0
0
0 0.75349808
8 13.68256 0.105516 875.68387 13.68256
0
1 8299.0679 273.1428
1

trial konversi
Eror

P
Massa

Koefisien

0
0
58.4375
219.8363
0
0
278.2738

Out

Reaksi

0.241457
1.04E-005

Cp dT
25

u s m a s s a n i. H f

298

H Pembentukan

n i. C p d T
25

H sensible

Out
C
Mol
0.242053
0
0
0
3.42064
0

TREF
T2

H (kJ/mol)

H (kJ)

-177.9 -43.06124
0
0
-822.156
0

Mol

Hf (kJ/mol)

0
0
0
0
-2812.3
0
0 13.68256
-2855.361

25 C
298 K
40 C
313 K

Hf (kJ)

0
0
0
0
0
0
-296.9 -4062.352
-4062.352

Out
C

Cp dT
Hs(J)
Cp dT
Hs(J)
Mol
Mol
0.242053
1170 283.2021
0
0
0
150
3.75
562.5
0
0
0
0 481.6185562
0 39.62398 481.61856 19083.64
0 451.8618362
0 219.8363 451.86184 99335.64
3.42064 1573.564703 5382.599
0
0
0
0
0
0 13.68256 722.77039 9889.35
6228.301
128308.6

C
Massa
Mol
29.04637 0.2420531
150
0
0
0
0
547.30242 3.4206401
0
0
726.34879 558.49999

Basis

1000 kg
in

Komponen

BM
Xf

FeS2
inert
O2
N2
Fe2O3
SO2

120

0.85
0.15
0
0
0
0
1

32
28
160
64
TOTAL

F
Massa
Mol
850 7.083333
150
0
0
0
0
0
0
0
0
1000 7.083333

U
Massa

Xf

0
0
0
0
0.21
1870
0.79 6155.417
0
0
0
0
1 8025.417

Reaksi
4 FeS2
+
11 O2----> 2 Fe2O3 + 8 SO2
7.083333333 19.4791667
Neraca energi tanpa menggunakan reference
H

Massa keluar (produk)

T2C, Hout

Massa masuk
T1C, Hin
H 1

H 3 n 0 .

25

ni .

Cp i dT

T1

H2 = Hrxn,

298

Massa masuk
25C

T2

Cp

dT

25

Massa keluar (produk)

25C

Hout - Hin = H = H1 + H2 + H3
H1

Perhitungan H2
Cara 1
H2 = Hrxn,

298

= H rxn298

vi H

fi

298

produk

vi H

fi

298

reaktan

Reaksi
4 FeS2
+ 11 O2 ---> 2 Fe2O3 + 8 SO2
6.84128025 18.8135207 3.42064 13.6825605

mol
Komponen
Reaktan

FeS2
O2

Mol

6.84128025
18.8135207
Total

Hf (kJ/mol)

Hf (kJ)

-177.9 -1217.064
0
0
-1217.064

Produk

F32O3
SO2

3.42064013
13.6825605
Total

H2 = Hrxn,

298

Cara 2
H2 = Hrxn,

298

=H

-822.156
-2812.3
-296.9 -4062.352
-6874.652

-5657.5883 kJ

rxn298 vi H

fi 298

keluar

vi H

masuk

In
Komponen

Mol

FeS2
inert
O2
N2
Fe2O3
SO2

Out

Hf (kJ/mol)

6.84128025

fi 298

Hf (kJ)

Mol

-177.9 -1217.0638 0.242053

Hf (kJ/mol)

Hf (kJ)

-177.9 -43.06124

58.4375
0
0 39.62398
0
0
219.8363095
0
0 219.8363
0
0
0
0
0 3.42064
-822.156
-2812.3
0
0
0 13.68256
-296.9 -4062.352
Total
-1217.0638
Total
-6874.652
H2 = Hrxn, 298 =
-5657.5883 kJ
Perhitungan
TABEL Cp
Komponen a
FeS2
O2
N2
Fe2O3
SO2

H3 ( H sensible )
b
78
29.1
29
103.4
38.91

0
0
0
0.01158 -6.08E-006 1.31E-009
0.002199 5.723E-006 -2.9E-009
0.06711 -1772000
0
0.03904 -3.10E-005 8.61E-009

Pers
1
1
1
2
1

Out
Komponen
FeS2
inert
O2
N2
Fe2O3
SO2
Total
H3 =

Cp dT
Hs(J)
Cp dT
Hs(J)
Mol
Mol
0.242053083
78 283.202107
0
0
0
150
3.75
562.5
0
0
0
0 481.618556
0 39.62398 481.618556 19083.64
0 451.861836
0 219.8363 451.861836 99335.64
3.420640125 1573.5647 5382.59856
0
0
0
0
0
0 13.68256 722.770389 9889.35
6228.30067
128308.6

134.5369324 kJ
Q=H = H1 + H2 + H3 = -5523.0513 kJ

Reaksi

U
Mol

Koefisien

0
0
58.4375
219.8363
0
0
278.2738
trial konversi
Eror

Out
P
Massa

Mol
Xf
Mol
Xf
-4 -6.84128
0
0
0 0.03998956
0
0
0
0
0 0.20651236
-11 -18.81352 0.152784 1267.9673 39.62398
0
0
0
0.7417 6155.4167 219.8363
0
2 3.42064
0
0
0 0.75349808
8 13.68256 0.105516 875.68387 13.68256
0
1 8299.0679 273.1428
1
0.241457
1.04E-005

T1
T2

25 C
298 K
40 C
313 K

C
Massa
Mol
29.04637 0.2420531
150
0
0
0
0
547.30242 3.4206401
0
0
726.34879 558.49999