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Intercompany Memorandum: Cal Chem Corporation To: Date: Winter Quarter File: CHE 333 From
Intercompany Memorandum: Cal Chem Corporation To: Date: Winter Quarter File: CHE 333 From
Intercompany Memorandum: Cal Chem Corporation To: Date: Winter Quarter File: CHE 333 From
CHE Juniors
From:
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Laboratory Managers
Subject:
http://www.medal.com/en/membranes/nitrogen/index.asp
y, p
N2
1 -y
N
O 2
N 2
t
x, P
1 -x
Figure 2. Schematic of a membrane with thickness t used to separate O2 from N2.
The flux NO2 of oxygen across the membrane shown in Figure 2 is given as
NO2 =
PO2
(xP yp)
t
(1)
where PO2 is the permeance of the membrane to oxygen, x is the mole fraction of oxygen on the
upstream, or high pressure P, side of the membrane, and y is the mole fraction of oxygen on the
downstream, or low pressure p, side of the membrane. The ratio of permeance to membrane thickness is
called the permeability PO 2 of the membrane to oxygen. The permeability can be viewed as a mass
transfer coefficient that connects the flux with the driving force for transport, which is the partial
pressure difference between the upstream and downstream sides of the membrane.
We now need to consider the fact that as the feed gas travels through the hollow fibers, its composition
changes as selective permeation depletes the more permeable components from the feed gas mixture.
Figure 3 illustrates the ideal countercurrent flow pattern for the binary mixture of oxygen and nitrogen
moving through the fiber module.
P e rm e a te
y P, n P= n
p
d (y n )
xn
Feed
x F, n F
dA
P
yi
x n + d (x n )
R e te n ta te
x R, n R
Figure 3. Ideal countercurrent flow pattern through the separator.
The total mole and O2 species balances around the separator are2
nF = nR + nP
(2)
(3)
where nF, nR, and nP are the molar flow rates of the feed, retentate, and permeate streams,
respectively, and xF, xR, and xP are the feed, retentate, and permeate O2 mole fraction,
respectively. The molar flux of oxygen through a differential area dA in the membrane is given
by equation (1) or by
NO2 =
Therefore
P
d ( xn )
= O2 (xP yp) = QO2(xP yp)
dA
t
(4)
The above equation is just the O 2 species balance around the differential volume element in the
membrane. The reduction in the O2 molar flow rate d(xn) of the retentate stream provides the
same O2 molar flow rate d(yn) through the membrane. P and p are the average retentate and
permeate side pressures, respectively. Similar species balance for nitrogen around the differential
volume element in the membrane yields
(5)
The ratio
(6)
d ( xn )
is just the molar flow rate of oxygen over that of nitrogen in the
d [(1 x )n ]
permeate stream, therefore it is equal to the ratio of the mole fraction of oxygen over that of
Q 'O 2
y
nitrogen 1 y as shown schematically in Figure 4. Let * =
, equation (6) becomes
Q' N 2
xP yp
y
= *
1 y
(1 x ) P (1 y ) p
d (y n )
p
P e rm e a te
y P, n P= n
(7)
yi
xn
Feed
x F, n F
x n + d (x n )
P
R e te n ta te
x R, n R
(7)
When the change in feed mole fraction of oxygen is less than 50%, the driving force for diffusion
across the membrane, = xP yp, is assumed to be a linear function of the change in the molar
flow on the feed side of the membrane
d(xn) =
( xn ) R ( xn ) F
d
R F
From the species balance around the separator xFnF = xRnR + yPnP
(8)
(9)
Combine equations. (8) and (9) with equation (4) d(xn) = QO2(xP yp)dA, we obtain
d
yPnP = QO2dA
R
F
Separate the variables and integrate
R
yPnP
yPnP
A
d
= QO2 (R F) 0 dA
R
F
ln
= QO2 (R F)Am
yPnP = QO2lm Am
(10)
( xP yp ) R ( xP yp ) F
R F
( xP yp ) R
lm = ln R = (xP yp)lm =
ln
F
( xP yp ) F
(11)
Equation (10) expresses the molar flow rate yPnP of oxygen as a function of the permeance QO2
or mass transfer coefficient, area of membrane Am for mass transfer, and an average driving force
lm across the membrane. Similarly, the molar flow rate of nitrogen in the permeate stream can
be found
(1yP)nP = QN2 [(1x)P (1y)p)]lmAm
(12)
The oxygen species balance, xFnF = xR( nF nP) + yPnP, can be written in dimensionless form
using the definition of the cut = nP/nF,
xF = xR( 1 ) + yP
(13)
yPnP
nR
nR
1
1
=
Q A
nF Q' N 2
n F Q ' N 2 O2 lm m
(14)
yP
nP
nR
n
= 1 P
Q ' N 2 Am p n F
nF
Q 'O 2
(xr y)lm
Q' N 2
Experimental Procedure
Compressed air at about 110 psig is supplied to the membrane module through an air regulator.
The supplied air pressure can be controlled by turning the knob on top of the regulator. The
oxygen concentration is measured by a portable oxygen analyzer model GPR-30. You can
calibrate the oxygen analyzer by turn it on while in the ambient air and set the oxygen
concentration to 21.0 %.
Adjust the inlet pressure of the membrane module to 30 psig. Read the flow rate on the permeate
side of the membrane and set the same flow rate for the retentate. Record the oxygen
concentrations on both sides of the membrane when the system reaches steady state. The
permeate pressure p is assumed to be the ambient pressure and the retentate pressure P is the
average of the feed and retentate pressures as measured by the pressure gages.
Measure the oxygen concentrations and the retentate pressures again at the retentate flow rates of
twice and four times the permeate flow rate. Repeat the procedure at 40, 50, 60, 70, and 80 psig.
Analysis
1. Plot the experimental separation factor * as a function of r (= P/p) and discuss the results.
2. Compare calculated cut with experimental (= nP/nF) and plot the experimental and
calculated cut (= nP/nF) as a function of r and discuss the results.
3. If you are using the Newtons method, present one iteration at 30 psig and = 0.5 using the
guessed values yi = 0.2, = 0.5, * = 6, and KR = 2. Clearly indicate how you evaluate the
Jacobian matrix.
4. Explain the difference in the diffusion rates of gases through the membrane.
References
1. Coker, D. T., Prabhakar, R., Freeman, Tools for Teaching Gas Separation Using Polymers,
Chemical Engineering Education, 36, Winter 2002, 60
2. Davis, R. A., Sandall, O. C., A Simple Analysis for Gas Separation Membrane Experiments,
Chemical Engineering Education, 36, Winter 2002, 74
3. Welty, J. R., Wicks, C. E., Wilson, N. E., and Rorrer, G. L., Fundamentals of Momentum,
Heat and Mass Transfer, John Wiley and Son, (2001)