Ho

CH3OH
CO
H2

Vi
H
-90135.000
Vi
1
-1
-2

To
T

Cp/R
(CP)H
H

298.15
K
1073.15
K
3.5993627369
-2.0844676874
-17.330264353 J
-103565.95487

Tc/K

180.2
0.1679168802

CO + 2H2 -> CH3OH

CH3OH
CO
1
1
-200660
-110525

A
2.211
3.376
3.249
-7.663
-7.663
A

B
12.216
0.557
0.422
10.815
0.010815
B
500
533.15

H2
2

C
-3.45
0
0
-3.45
-0.00000345
C
F

D
0
-0.031
0.083
-0.135
-13500
D

Vi
H
-92220

Ho

NH3
N2
H2

To
T

Cp/R
(CP)H
H
Cp/R dT
H
R.Cp/RdT

H2
3
0

NH3
2
-46110

A
3.578
3.28
3.249
-5.871
-5.871
A

B
3.02
0.593
0.422
4.181
0.004181
B

C
0
0
0
0
0
C

Vi
2
-1
-3

298.15
K
873.15
K
2.9286
-3.6763
-30.5648
-109794.77 J
-2113.88
-109794.77
-17574.77

N2
1
0

D
-0.186
0.04
0.083
-0.661
-66100
D

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)
= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

2++1)+D/(To)2

Vi
H
-905468

Ho

NH3
O2
NO
H2O

To
T

Cp/R
(CP)H
H
Cp/R dT
H
R.Cp/RdT

O2
5
-241818

NO
4
90250

H2O
6
-241818

A
3.578
3.639
3.387
3.47
1.861
1.861
A

B
3.02
0.506
0.629
1.45
-3.394
-0.003394
B

C
0
0
0
0
0
0
C

D
-0.186
-0.227
0.014
0.121
2.661
266100
D

Vi
-4
-5
4
6

298.15
K
773.15
K
2.5932
1.1974
9.9550
-900739.38 J
568.75
-900739.38
4728.62

NH3
4
-46110

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)
= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

1)+D/(To)2

Ho

Vi
H
-71660

NO2
3
33180
J

H2O
1
-285830

HNO3
2
-174100

NO
1
90250

Ho

Vi
H
-61980 J

CaC2
1
-59800

H2O
1
-285830

C2H2
1
227480

CaO
1
-635090

Ho

Vi
H
-367582

Na
2
0
J

H2O
2
241818

NaOH
2
-425609

H2
1
0

Vi
H
-2732016

Ho

N2
H2O
NO2
NH3

To
T

Cp/R
(CP)H
H
Cp/R dT
H
R.Cp/RdT

1880.54
-2716381.19
15634.81

NH3
8
-46110

N2
7
0

A
3.28
3.47
4.982
3.578
6.084
6.084
A

B
0.593
1.45
1.195
3.02
-9.779
-0.009779
B

C
0
0
0
0
0
0
C

Vi
7
12
-6
-8

298.15
923.15
3.0963
3.0089
25.0157
-2716381.19

NO2
6
33180

K
K

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)
= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

H2O
12
-241818

D
0.04
0.121
-0.792
-0.186
7.972
797200
D

CTo2(2++1)+D/(To)2
)

dT

Ho

Vi
H
-105140 J

C2H4
1
52510

O2
0.5
0

((CH2)2)O
1
-52630

Ho

Vi
H
-38292 J

C2H4
1
227480

H2O
((CH2)2)O
1
1
-241818
-52630

Vi
H
164647

Ho

CO2
H2
CH4
H2O

To
T

Cp/R
(CP)H
H
Cp/R dT
H
R.Cp/RdT

3051.87
190020.26
25373.26

H2O
2
-241818

CO2
1
-393509

A
5.457
3.249
1.702
3.47
9.811
9.811
A

B
1.045
0.422
9.081
1.45
-9.248
-0.009248
B

C
0
0
-2.164
0
2.164
0.000002164
C

Vi
1
4
-1
-2

298.15
973.15
3.2640
4.5213
37.5900
190020.26

CH4
1
-74520

K
K

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)
= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

H2
4
0

D
-1.157
0.083
0
0.121
-1.067
-106700
D

CTo2(2++1)+D/(To)2
)

dT

Vi
H
-48969

Ho

CH3OH
H2o
Co2
H2

To
T

Cp/R
(CP)H
H
Cp/R dT
H
R.Cp/RdT

-1316.94
-59918.01
-10949.01

H2
3
0

CH3OH
1
-200660

A
2.211
3.47
5.457
3.249
-9.523
-9.523
A

B
12.216
1.45
1.045
0.422
11.355
0.011355
B

C
-3.45
0
0
0
-3.45
-0.00000345
C

Vi
1
1
-1
-3

298.15
583.15
1.9559
-4.6208
-38.4176
-59918.01

Co2
1
-393509

K
K

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)
= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

H2o
1
-241818

D
0
0.121
-1.157
0.083
1.029
102900
D

CTo2(2++1)+D/(To)2

Ho

Vi
H
-149728 J

CH3OH
1
-200660

O2
0.5
0

HCHO
1
-108570

H2O
1
-241818

Vi
H
-1036036

Ho

H2O
SO2
H2S
O2

To
T

Cp/R
(CP)H
H
Cp/R dT
H
R.Cp/RdT

O2
3
0

H2O
2
-241818

A
3.47
5.699
3.931
3.639
-0.441
-0.441
A

B
1.45
0.801
1.49
0.506
0.004
0.000004
B

C
0
0
0
0
0
0
C

Vi
2
2
-2
-3

298.15
K
683.15
K
2.2913
-0.7547
-6.2748
-1038451.80 J
-290.57
-1038451.80
-2415.80

H2S
2
-20630

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)
= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

SO2
2
-296830

D
0.121
-1.015
-0.232
-0.227
-0.643
-64300
D

CTo2(2++1)+D/(To)2
)

dT

Vi
H
207436

Ho

H2
SO2
H2S
H2O

To
T

Cp/R
(CP)H
H
Cp/R dT
H
R.Cp/RdT

1619.80
220903.04
13467.04

H2O
2
-241818

H2
3
0

SO2
1
-296830

A
3.249
5.699
3.931
3.47
4.575
4.575
A

B
0.422
0.801
1.49
1.45
-2.323
-0.002323
B

C
0
0
0
0
0
0
C

D
0.083
-1.015
-0.232
0.121
-0.776
-77600
D

Vi
3
1
-1
-2

298.15
850
2.8509
2.9352
24.4034
220903.04

H2S
1
-20630

K
K

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)
= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

+1)+D/(To)2

Ho

Vi
H
180500

NO
N2
O2

Vi
2
-1
-1

Versi T=1300K
To
T

Cp/R

NO
2
90250
J
A
3.387
3.28
3.639
-0.145
-0.145
A

B
0.629
0.593
0.506
0.159
0.000159
B

C
0
0
0
0
0
C

D
0.014
0.04
-0.227
0.215
21500
D

(CP)H
H

298.15
K
1300
K
4.3602
0.0375
0.3120
180812.54 J

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)

Cp/R dT
H
R.Cp/RdT

37.59
180812.54
312.54

= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

++1)+D/(To)2

Versi T=1350K
To
T

Cp/R
(CP)H
H
Cp/R dT
H
R.Cp/RdT

298.15
1350
4.5279
0.0394
0.3279
344.94
41.49
180844.94
344.94

K
K

Ho

CaCo3
CaO
CO2

To
T

Cp/R

Vi
H
178321

CaCo3
1
-1206920

CaO
1
-635090

CO2
1
-393509

A
12.572
6.104
5.457
-1.011
-1.011
A

B
2.637
0.443
1.045
-1.149
-0.001149
B

C
0
0
0
0
0
C

Vi
-1
1
1

D
-3.12
-1.047
-1.157
0.916
91600
D

(CP)H
H

298.15
K
1073.15
K
3.5994
-1.5125
-12.5751
168575.27 J

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)

Cp/R dT
H
R.Cp/RdT

-1172.21
168575.27
-9745.73

= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

Tc/K

180.2
0.1679168802

/(To)2

Ho

Vi
H
-132439 J

SO3
1
-395720

H2O
1
-285830

H2SO4
1
-813989

Ho

Vi
H
-44370 J

C2H4
1
52510

H2O
1
-285830

C2H5OH
1
-277690

Ho

C2H5OH
CH3CHO
H2

Vi
H
-68910 J

CH3CHO
1
-166190

H2
1
0

C2H5OH
1
-235100

A
3.518
1.693
3.249

B
20.001
17.978
0.422

C
-6.002
-6.158
0

Vi
1
-1
-1

-1.424
-1.424
A
To
T

Cp/R
(CP)H
H

298.15 K
723.15 K
2.4255
-0.6019
-5.0043
###
J

Cp/R dT -255.82
H
-71036.85 J
R.Cp/RdT-2126.85

1.601
0.156
0.001601 1.56E-007
B
C

D
0
0
0.083
-0.083
-8300
D

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)
= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

Ho

Vi
H
-492640 J

C2H5OH
1
-277690

O2
3
0

CH3COOH
H2O
1
1
-484500 -285830

Vi
H
109780

Ho

C4H8
C4H6
H2

To
T

Cp/R

C4H8
1
-540

(CP)H
H
Cp/R dT
H
R.Cp/RdT

893.01
117204.48
7424.48

H2
1
0

Vi
-1
1
1

298.15
733.15
2.4590
2.0529
17.0678
117204.48

C4H6
1
109240

A
1.967
2.734
3.249
4.016
4.016
A

B
C
31.63
-9.873
26.786
-8.882
0.422
0
-4.422
0.991
-0.004422 9.91E-007
B
C

D
0
0
0.083
0.083
8300
D

K
K

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)
= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

2++1)+D/(To)2

Ho

C4H6
H2
C4H10

To
T

Cp/R

Vi
H
235030

(CP)H
H
Cp/R dT
H
R.Cp/RdT

1671.29
248925.12
13895.12

C4H6
1
109240

H2
2
0

A
2.734
3.249
1.935

B
26.786
0.422
36.915

C
-8.882
0
-11.402

D
0
0.083
0

7.297
7.297
A

-9.285
-0.009285
B

2.52
0.00000252
C

0.166
16600
D

Vi
1
2
-1

298.15
900
3.0186
2.7769
23.0873
248925.12

C4H10
1
-125790

K
K

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)
= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

+1)+D/(To)2

Vi
H
-132038

Ho

C4H6
H2O
C4H8
O2

To
T

Cp/R
(CP)H
H
Cp/R dT
H
R.Cp/RdT

424.69
-128507.14
3530.86

O2
0.5
0

C4H6
1
109240

H2O
1
-241818

A
2.734
3.47
1.967
3.639
2.4175
2.4175
A

B
26.786
1.45
31.63
0.506
-3.647
-0.003647
B

C
-8.882
0
-9.873
0
0.991
0.000000991
C

D
0
0.121
0
-0.227
0.2345
23450
D

Vi
1
1
-1
-0.5

298.15
900
3.0186
0.7056
5.8667
-128507.14

C4H8
1
-540

K
K

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)
= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

+1)+D/(To)2

Vi
H
-1807968

Ho

H2O
N2
NH3
NO

To
T

Cp/R
(CP)H
H
Cp/R dT
H
R.Cp/RdT

NH3
4
-46110

NO
6
90250

H2O
6
-241818

N2
5
0

A
3.47
3.28
3.578
3.387
2.586
2.586
A

B
1.45
0.593
3.02
0.629
-4.189
-0.004189
B

C
0
0
0
0
0
0
C

D
0.121
0.04
-0.186
0.014
1.586
158600
D

Vi
6
5
-4
-6

298.15
K
673.15
K
2.2578
1.3418
11.1561
-1803784.45 J
503.19
-1803784.45 J
4183.55

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)
= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

++1)+D/(To)2

Vi
H
42720

Ho

HCN
N2
C2H2

To
T

Cp/R
(CP)H
H
Cp/R dT
H
R.Cp/RdT

15.06
42845.18
125.18

C2H2
1
227480

HCN
2
135100

A
4.736
3.28
6.132

B
1.359
0.593
1.952

C
0
0
0

D
-0.725
0.04
-1.299

0.06
0.06
A

0.173
0.000173
B

0
0
C

-0.191
-19100
D

Vi
2
-1
-1

298.15
648.15
2.1739
0.0430
0.3576
42845.18

N2
1
0

K
K

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)
= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

++1)+D/(To)2

Ho

C8H8
H2
C8H10

To
T

Cp/R

Vi
H
117440

C8H10
1
29920

C8H8
1
147360

H2
2
0

A
2.05
3.249
1.124

B
50.192
0.422
55.38

C
-16.662
0
-18.476

D
0
0.083
0

4.175
4.175
A

-4.766
-0.004766
B

1.814
0.000001814
C

0.083
8300
D

Vi
1
1
-1

(CP)H
H

298.15
K
1083.15 K
3.6329
1.8675
15.5263
129628.15 J

= A+BTo/2(-1)+CTo2(2++1)+D/(To)2
= Ho + (Cp)H (T-To)

Cp/R dT
H
R.Cp/RdT

1465.98
129628.15 J
12188.15

= (Cp/R) (T-To)
= Ho + R . Cp/R dT
= R . Cp/R dT

+1)+D/(To)2

Ho

Vi
H
175305 J

C
1
0

H2O
1
-285830

H2
1
0

CO
1
-110525