S lc lch s pht trin

Cao su Butyl c sn sut ln u tin bi hai nh ha hc ngi M l William Sparks

v Robert Thomas cng ty Standard Oil bang New Jersey ( by gi l tp on Exxon ) vo
nm 1937. Lc by gi vic sn sut cao su tng hp ch yu da trn vic Polyme ha nhm
diene nh Isoprene v Butadiene. Sparks v Thomas khng i tgheo li mn m tin hnh
copolyme ha Isobutylene vi mt lng nh ( thp hn 2% ) Isoprene. L mt diene, Isoprene
cung cp thm ni i cho copolyme tin hnh ni mng khng gian khin chui polyme tr
nn bn ha hn. Tuy nhin c mt s kh khn trong qu trnh th nghim khin cao su Butyl
b gi l Futile Butyl, c ngha l Butyl v dng. Nhng qua mt s ci tin, n dc chp
nhn rng ri b kh nng chng thm kh tt v kh nng khng Oxy v Ozone tuyt vi nhit
thng. Trong th chin th 2, polyme ny c gi l GRI, vit tt ca Government
Rubber Isobutylene, ngha l cao su Isobutyl ca chnh ph

Cng thc cu to v tnh cht

n v lp ca polyme c dng

Bi v mch polyme chnh, polyisobutylene, c cu to i xng v mch kt tinh nhanh

chng khi b ko dn cho nn IIR d ch cha mt lng nh Ispoprene cng khe nh cao su
thin nhin. Thm vo , v copolyme ch cha mt lng nh nhm khng no, tnh bo ha
tnh theo phn t lng l 1/5000 ( so vi cao su isoprene l 1/68), nn t b oxy ha lm gim
cp khi tip xc vi khng kh. Mch phn t Cao su Butyl cng th hin tnh t linh ng khc
thng trn nhit ha thy tinh nn c kh nng chng thm kh v khng Ozone cao.Tm
li cao su Butyl thng c s dng vi cc tnh cht sau:
Tnh khng nhit lo ha
Tnh khng Ozone v khng thi tit
Tnh khng ha cht v tnh khng m
Copolyme c thu hi t dung dch di dng ht vng, c th pha trn vi cc cht
n v ph gia sau em i lu ha to thnh sn phm cao su c gi tr thc tin. Hn hp
cao su thng c t l l 20% than en v 30% cht n.

ng dng
IIR l cao su c s dng ph bin th ba sau SBR v BR. Nh tnh chng thm kh
cao, cao su Butyl c s dng lm ng trong bnh xe v ng vai tr quan trng trong cng
ngh sn xut li trong ca bnh xe khng ng.IIR cng c dng nhiu trong cc b phn t
nh joint ca knh xe nh tnh chng xi ha. Kh nng chu nhit ca IIR khin n tr thnh
mt phn khng th thiu trong cng ngh sn xut lp xe khi c s dng gi hi nc hay
nc nng trong lu ha lp. Ngoi ra cao su Butyl cn c s dng lm tm lp bc cch
in, thm lt phng tm, nm hi, nm gim xc,
Dn sut BIIR v CIIR
Brom v Clo c th c cho vo phn Isoprene ca IIR to thnh BIIR v CIIR. Tnh cht
ca hai dn sut ny kh ging vi IIR nhng chng d gia cng, iu chnh hn vi lng ph
gia t hn, loi ph gia dng iu chnh cng khc vi IIR. Nh vy BIIR v CIIR c th d dng
kt hp vi cc Polyme khc to thnh sn phm cao su