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Mercury Analysis PDF
Mercury Analysis PDF
Gas samples are collecte d by a syringe or byTedlar gas sampli ng bag s, and th en d irect ly introd uced in t he DMA-80.
A schem atic representatio n of t he enti re process is shown bel ow.
Detector
HgTrap
Gas Module
Injection
Ab sorbtion Cells
DMA-80 Outlet
i
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ill
Vacuum Pump
Amalgamator
Hg Lamp
The gas kit consist s of an injection block and a vacuum pump, w hich allow th e flo wing of t he sample t hro ug h th e DMA
80 f urnaces, amalga mat or and spectrometer.
Benefits
Ease of use
Applications
Environmental
II
Petrochemical
Health and Safety
Hazmat mercury response
Workplace monitoring
Mercury spill screening
Mercury surveys
Invest igation of contaminated sites
Environmental monito ring
Hazardous waste inspect ion
Performance specifications
DMA-80 Dual-Cell
DMA-80 Tri-Cell
Data
Total Hg (ng)
Total Hg (ng)
(1st) 0.05-20
(2nd ) 20-1200
(1st) 0.05-20
(2nd ) 20-1200
(1 st) 0.015-10
(2nd ) 10-20
(3rd ) 20-1200
(1") 0.015-10
Worki ng range
Det ect ion li m it
0.005
(2nd ) 10-20
(3rd ) 20-1200
0.0015
Sorbent tra ps are available fo r the Milest one DMA-80 to measure t he mass concent rat ion of Mercury in gases, including
elemen tal Mercury (HgO) and oxidized for ms of Mercu ry (Hg+ 2) in mic ro-grams per dry st and ard cub ic m;ter (uq/dscm).
Gases are collecte d onto the sor bent tu bes by specific devices fi rst.
At the completi on of the sampling proc ess, the sorbent tubes are dire ct ly placed on the DMA-80 aut o-sampl er and
analyzed.
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Benefits
Best quality-price
Performance specifications
Sorbent trap
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mg Adso qu ic_k_ _
Reusable sorbent tr ap
Up t o ' 0 ti mes
Flow rate
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> 99 .1%
> 99.2%
> 98.5%
<2%
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BENEFITS
US EPA AND ASTM METHODS ALREADY
AVAILABLE
NO SAMPLE PREPARATION
The DMA-80 enables the operator to do direct
determination of total mercury without the need for acid
digestion or other wet chemistry sample treatment prior
the analysis; this means no hazardous chemicals to
purchase, handle and dispose.
HIGH PRODUCTIVITY
Typical analysistime is 5 minutes. A dual-trayautosampler
allows for unattended analysis of multiple samples.
EASY MAINTENANCE
EASE OF USE
MATRIX-INDEPENDENT RESULTS
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Sample boat
..
Time(minutes)
Drying/Decomposition fumace
Sample preparation
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Analysis
DMA80
CV-AAS
500
1.000
1.500
2.000
2.500
USO
labo ur
Reagents
Catalyst furnace
Amalgamator
Spectrophotometer
ACCURACY
PRECISION
MEMORY EFFECT
Sample
Certified (Ilg/kg)
DMA-80 (Ilg/kg)
Sample
BCR-680 Polyethylene
24,3-26,3 mg/kg
Run
NIST 27 11 Soil
6.250 190
6.240 70
6,2
237, 1
420
- 534-612
543-575
574 12
5,7
228,5
410
558 8
6,0
229 ,9
422
GSD-10
Sediment
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- Stream
.
280 40
270 15
6,0
236, 7
409
210- 250
22 1 3
5,7
24 1,1
4 17
PVC
lH'
Human Hair
Hg co ntent (Ilg/kg)
141_ 19
93,8 3,7
J c7 ~ 1 1" 1
5,8 0,5
142!? .
93,4 2,4
Average
5,9
234,7
416
.fJ,.2_:!, 0,2
sd
0,2
5,3
5,9
5,9 0,2
RSD
3,6%
2,2 %
1,4%
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20%
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5 0 0 - - - - - - - - - -- 400
6,0
80%
60%
Human Hair
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SAMPLE WEIGHT
SAMPLE MATRIX
DIFFICULT SAMPLES
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VIRGIN NAPHTHA
Replicate
Hg content ~glkg)
Average
sd
RSD
5,4
5, 1
5,2
5.2
0.15
2,9%
DMA-80 FEATURES
SYSTEM CONTROLLER
EASY MAINTENANCE
Terminal 1640.
M ILESTONE
MILESTON E Sri - Via Fatebenefratelli, 1/ 5 - 240 10 Sorisole (88) - Italy - Tel: +39035573857 - Fax: +39035575498
www.milestonesrl.com - email: analytical@milestonesrl.com l UNI EN ISO 9001: 2008CERTIFIED - Registration N 0513907
MILESTONE INC. - 25 Controls Drive - Shelton. CT 06484 - USA - Tel: (203) 925-4240 - Toll-free: (866) 995- 5100 - Fax:
MILESTONE GENERAL K.K. - KSP. 3-2-1 , Sakado - Takatsu-Ku. Kawasaki 213-0012 - Japan
Tel: +81 (0)44 85038 11 - Fax: +8 1 (0)44 8193036 www.milestone-general.com - email: info@milestone-general.com
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