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NAMA :....................................................................................................

KELAS :...................................................................................................

PEPERIKSAAN PERCUBAAN
SIJIL PELAJARAN MALAYSIA 2015

https://cikguadura.wordpress.com/

4541/1

CHEMISTRY
Kertas 1
September
1 jam

1 jam 15 minit

DO NOT OPEN THIS PAPER UNTIL YOU ARE TOLD TO DO SO


JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

INFORMATION FOR CANDIDATES


MAKLUMAT UNTUK CALON
1.
2.
3.

4.
5.

This question paper consists of 50 questions


Kertas soalan ini mengandungi 50 soalan
Answer all questions.
Jawab semua soalan.
Each question is followed by four alternative answers, A, B, C or D. For each question,
choose one answer only. Blacken your answer on the objective answer sheet provided.
Tiap-tiap soalan diikuti oleh empat pilihan jawapan, iaitu A, B, C dan D. Bagi setiap
soalan, pilih satu jawapan sahaja. Hitamkan jawapan anda pada kertas jawapan objektif
yang disediakan.
The diagrams in the questions provided are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukis mengikut skala kecuali dinyatakan.
You may use a non-programmable scientific calculator.
Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogram.

------------------------------------------------------------------------------------------------------------------------------Kertas soalan ini mengandungi 26 halaman bercetak

Lihat sebelah

1.

What is the first step in a scientific investigation?


Apakah langkah pertama dalam penyisatan saintifik?
A
B
C
D

2.

Identifying the problem


Mengenalpasti masalah
Making an observation
Membuat pemerhatian
Making a hypothesis
Membuat hipotesis
Planning an experiment
Merancang eksperimen

Which of the following statements is true about atomic model proposed


by Neils Bohr?
Antara berikut, pernyataan manakah yang benar tentang model atom yang
dicadangkan oleh Neils Bohr?
A
B
C

3.

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The nucleus of the atom contains proton.


Nukleus atom mengandungi proton
The nucleus of the atom contains proton and neutrons.
Nukleus bagi atom mengandungi proton dan neutron
The atom was described as a sphere of positive charge embedded with
electron
Atom merujuk kepada sebuah sfera bercas positif dengan elektron
bertaburan di atasnya.
The electrons in an atom move in shells around the nucleus
Elektron suatu atom bergerak di petalanya mengelilingi nukleus.

Which of the following statements is true about the isotopes

79
35

Br and 3581 Br ?
79

81

Antara berikut, pernyataan manakah adalah benar mengenai isotop 35 Br and 35 Br ?


I
They have the same chemical properties.
Isotop tersebut mempunyai sifat kimia yang sama
II
They have same physical properties.
Isotop tersebut mempunyai sifat fizikal yang sama.
III
They have the same number of valence electrons.
Isotop tersebut mempunyai bilangan electron valens yang sama
IV
They have different numbers of neutrons.
Isotop tersebut mempunyai bilangan neutron yang berbeza.

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3
A
B
C
D

4.

I , II and III only


I , II dan III sahaja
I, III and IV only
I, III dan IV sahaja
II, III and IV only
II, III dan IV sahaja
I, II ,III and IV
I, II ,III dan IV

Table 1 shows the melting point and boiling point of substances P,Q, R and S.
Jadual 1 menunjukkan takat lebur dan takat didih untuk bahan P, Q, R, dan S.
Substance
Bahan
P
Q
R
S

Melting point C
Boiling point C
Takat lebur C
Takat didih C
- 157
-9
- 13
55
80
196
256
300
Table 1
Jadual 1
Which substance is a liquid at room temperature?
Bahan manakah wujud sebagai cecair pada suhu bilik?
A
B
C
D
5.

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P
Q
R
S

1 mol of oxygen gas, O2 and 1 mol of carbon dioxide gas, CO2 have
1 mol gas oksigen, O2 dan 1 mol gas karbon dioksida, CO2 mempunyai
A
B
C
D

same mass
jisim yang sama
same number of atoms
bilangan atom yang sama
same number of molecules
bilangan molekul yang sama
same number of electrons
bilangan elektron yang sama

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4
6.

The formula for a nitrate ion is NO3- and for a sulphate is SO42-. If the formula of the
nitrate salts of M is MNO 3 2, what is the formula of the sulphate salt of M?
Formula untuk ion nitrat ialah NO3- manakala ion sulfat ialah SO42-. Sekiranya formula
garam nirat M ialah MNO 3 2, apakah formula untuk garam sulfat M?
A
B
C
D

7.

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MSO4
M2SO4
M SO4 2
M SO3 3

Diagram 1 shows three balloons with hydrogen, nitrogen and oxygen gas
respectively.
Rajah 1 menunjukkan tiga biji belon mengandungi gas hidrogen, nitrogen, dan
oksigen setiap satu.
2.5 g of
hydrogen
gas
2.5 g gas
hidrogen

7.0 g of
nitrogen
gas
7.0 g gas
nitrogen

2.5 g of
oxygen
gas
2.5 g gas
oksigen

Diagram 1
Rajah 1
Arrange the gases in descending order of volume.
[Relative atomic mass: H=1, N=14, O=16 and 1 mol of gas occupies 24 dm 3 at room
temperature and pressure]
Susun gas-gas tersebut mengikut susunan menurun isipadu.
[Jisim atom relatif: H=1, N=14, O=16; Isipadu molar gas = 24 dm3mol-1 pada keadaan
bilik)
A
B
C
D

Hydrogen, nitrogen, oxygen


Hidrogen, nitrogen, oksigen
Hydrogen, oxygen, nitrogen
Hidrogen, oksigen, nitrogen
Nitrogen, oxygen, hydrogen
Nitrogen, oksigen, hidrogen
Oxygen, nitrogen, hydrogen
Oksigen, nitrogen, hidrogen

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8.

Diagram 2
Rajah 2
Diagram 2 shows melamine plates. Melamine plates usually used at home because
of the good appearance, hardy and unbreakable. Melamine plates consist of mixture
including melamine with molecular formula C3H6N6. Find the relative molecular mass
of melamine.
[Relative atomic mass: H=1, N=14, C=12]
Rajah 2 menunjukkan pinggan melamin. Pinggan melamin biasanya digunakan di
rumah kerana selain rupanya yang cantik, ia juga tahan lasak dan tidak mudah
pecah. Pinggan melamin terdiri daripada bahan campuran termasuk melamin yang
mempunyai formula molekul C3H6N6. Hitungkan jisim molekul relatif melamin. [Jisim
atom relatif: H=1, N=14, C=12]
A
B
C
D
9.

121
126
130
132

Which statement is correct about noble gases?


Penyataan manakah yang benar tentang gas adi?
A
B
C
D

Do not form chemical bonds


Tidak membentuk ikatan kimia
Exist as diatomic molecules
Wujud sebagai molekul dwiatom
Form ions with different oxidation number
Membentuk ion dengan nombor pengoksidaan berbeza
Combine with transition metals to form coloured compounds
Bergabung dengan logam peralihan membentuk sebatian berwarna

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10.

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Table 2 shows the boiling points of three elements in Group 17.


Jadual 2 menunjukkan takat didih bagi tiga unsur dalam Kumpulan 17.
Halogen
Halogen
Fluorine
Fluorin
Chlorine
Klorin
Bromine
Bromin

Boiling point C
Takat didih C
-188
-35
59

Table 2
Jadual 2
Which of the following best explain why the boiling point increases down the
group?
Antara berikut, yang manakah menjelaskan dengan tepat mengapa takat didih
meningkat apabila menuruni kumpulan?
A
B
C
D

11.

Increase in proton number.


Bilangan proton bertambah
Intermolecular forces of attraction become stronger
Daya tarikan antara molekul semakin kuat
Increase in number of occupied shells of the atom
Bilangan petala yang berisi elektron bertambah
Increase in strength of the covalent bond between the atoms
Kekuatan ikatan kovalen antara atom bertambah

During the formation of ionic bonds, the atoms of elements


Semasa pembentukan ikatan ion, atom untuk setiap unsur
A
B
C
D

share electrons
berkongsi elektron
accept electrons
menerima elektron
donate electrons
menderma elektron
transfer electrons
memindahkan elektron

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12.

Among the following compounds, which one contains particles bonded by strong
electrostatic forces?
Antara sebatian-sebatian berikut, yang manakah mengandungi zarah yang terikat
dengan daya elektrostatik yang kuat?
A
B
C
D

13.

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Ammonia
Ammonia
Naphthalene
Naftalena
Potassium oxide
Kalium oksida
Carbon dioxide
Karbon dioksida

The number of valence electrons of atoms X and Y are 2 and 7 respectively. Which
of the following chemical formulae and types of bonding are true for the compound
formed between X and Y?
Bilangan elektron valens atom X dan Y ialah 2 dan 7 untuk setiap satu. Yang
manakah antara berikut menunjukkan formula kimia dan jenis ikatan yang terbentuk
antara X dan Y?
Chemical Formula
Sifat kimia
A
B
C
D

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XY2
XY2
X2Y
X2Y

Type of Bonding
Jenis Ikatan
Ionic
Ion
Covalent
Kovalen
Ionic
Ion
Covalent
Kovalen

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14.

Diagram 3
Rajah 3
Diagram 3 shows a picture of cooking gas cylinder which is always used at home.
Butane in cooking gas burns to release gas X. Both butane and gas X are
Rajah 3 menunjukkan gambar silinder gas memasak yang sering digunakan di
rumah. Butana dalam gas memasak terbakar membebaskan gas X. Kedua-dua
butana dan gas X adalah
A
B
C
D

15.

ionic compounds
sebatian ion
organic compounds
sebatian organik
covalent compounds
sebatian kovalen
hydrocarbon compounds
sebatian hidrokarbon

Which is the example of electrolyte?


Yang manakah antara berikut adalah contoh elektrolit?
A
B
C
D

Sugar solution
Larutan gula
Molten naphthalene
Leburan naftalena
Solid sodium chloride
Pepejal natrium klorida
Molten lead II bromide
Leburan plumbum II bromida

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9
16.

Anion that exist is molten zinc chloride include


Anion yang terdapat dalam zink klorida lebur termasuklah
A
B
C
D

17.

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ClCl- , OHCl- , Zn2+


Zn2+, H+, OH-, Cl-

Diagram 4 shows a chemical cell using magnesium and copper as the electrodes.
Rajah 4 menunjukkan satu sel kimia menggunakan magnesium dan kuprum sebagai
elektrod

Magnesium
Magnesium

Copper
Kuprum

Copper (II) sulphate solution


Larutan kuprum (II) sulfat

Diagram 4
Rajah 4
Which of the following half equations represents the reaction at the copper
electrode?
Antara berikut, yang manakah merupakan persamaan setengah yang menunjukkan
tindak balas pada elektrod kuprum?
A
B
C
D

Cu2+ + 2e Cu
2 H+ + 2e H2
Cu Cu2+ + 2e
2 Cl- Cl2 + 2e

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18.

Diagram 5
Rajah 5
A student has an iron ring as shown in Diagram 5. He wants to make the ring more
beautiful and durable to give to his friend as a present. What is the best way to do it?
Seorang pelajar mempunyai sebentuk cincin besi seperti yang ditunjukkan dalam
Rajah 5. Pelajar tersebut ingin menjadikan cincin tersebut lebih cantik dan tahan
lama untuk dihadiahkan kepada rakannya. Bagaimanakah cara terbaik untuk
mencantikkan cincin tersebut?
A
B
C
D

19.

Dip the ring in acid


Rendam cincin tersebut di dalam asid
Wash the ring with detergent
Basuh cincin dengan serbuk pencuci
Plate the ring with silver
Sadur cincin tersebut dengan perak
Brush the ring with glossy material
Berus cincin tersebut dengan bahan pengilat

Which of the following is true about an alkali?


Manakah antara berikut adalah benar tentang alkali?
A
B
C
D

an alkali is not corrosive


alkali adalah tidak menghakis
an alkali is a base that is soluble in water
alkali ialah bes yang larut dalam air
a weak alkali has a high pH value
alkali lemah mempunyai nilai pH yang tinggi
a strong alkali has a low degree of ionization
alkali kuat mempunyai darjah pengionan yang rendah

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20.

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Table 3 shows information about three chemical cells.


Jadual 3 menunjukkan maklumat tentang tiga sel kimia.
Pair of metals
Pasangan logam
R,S
T, S
S, U

Potential difference V
Beza keupayaan V
0.3
0.8
1.9
Table 3
Jadual 3

Positive terminal
Terminal positif
R
T
S

The arrangement of the metals in the electrochemical series in ascending order of


electropositivity is
Susunan logam dalam siri elektrokimia mengikut susunan menaik keelektropositifan
ialah
A
R, U, S, T
B
T, R, S, U
C
T, R, U, S
D
U, S, R, T
21.

Which of the following solutions has the lowest pH value?


Yang manakah antara larutan berikut mempunyai nilai pH paling rendah?
A
0.01 mol dm-3 nitric acid
0.01 mol dm-3 asid nitrik
B
0.10 mol dm-3 nitric acid
0.10 mol dm-3 asid nitrik
C
0.01 mol dm-3 sodium hydroxide
0.01 mol dm-3 natrium hidroksida
D
0.10 mol dm-3 sodium hydroxide
0.10 mol dm-3 natrium hidroksida

22.

Acid rain causes the land to become acidic. Farmers neutralize acidity in the soil
by adding
Hujan asid menyebabkan tanah menjadi berasid. Petani boleh meneutralkan
keasidan tanah dengan menambah
A
B
C
D

Sulphur
Sulfur
Zinc nitrate
Zink nitrat
Soda lime
Kapur tohor
Ammonium sulphate
Ammonium sulfat

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23.

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Diagram 6 show two aqueous solutions.


Rajah 6 menunjukkan dua jenis larutan akueus.

HCl
0.1 mole dm

CH3COOH
-3

0.1 mole dm

-3

Rajah 6
Diagram 6
Which of the following statements is true?
Yang manakah antara pernyataan berikut adalah benar?
A
B
C
D

24.

Both solutions are strong acid


Kedua-dua larutan merupakan asid kuat
The pH of both solutions are equal
pH untuk kedua-dua larutan adalah sama
Both solutions has low degree of ionization
Kedua-dua larutan mempunyai darjah pengionan yang rendah
Both solution can react with sodium hydroxide solution
Kedua-dua larutan boleh bertindak balas dengan larutan natrium hidroksida

Which of the following is an insoluble salt?


Yang manakah antara berikut adalah garam tidak larut?
A
B
C
D

Silver nitrate
Argentum nitrat
Ammonium klorida
Ammonium chloride
Zinc sulphate
Zink sulfat
Magnesium carbonate
Magnesium karbonat

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25.

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A metal carbonate, XCO3, is green in colour. When it is heated strongly, the


remaining solid is black. Which of the following metals could be X?
Sejenis logam karbonat, XCO3 adalah berwarna hijau. Apabila dipanaskan dengan
kuat, pepejal yang tertinggal berwarna hitam. Yang manakah kemungkinan adalah
logam X?
A
B
C
D

Zinc
Zink
Lead
Plumbum
Copper
Kuprum
Aluminium
Aluminium

26.

Diagram 7
Rajah 7
Diagram 7 shows a bottle of salt which has been used for cooking at home. This salt
can react with silver nitrate salt to produce an insoluble salt. Name the insoluble salt.
Rajah 7 menunjukkan sebotol garam yang digunakan untuk memasak di rumah.
Garam ini boleh bertindak balas dengan garam argentum nitrat menghasilkan sejenis
garam tak larut. Namakan garam tak larut yang terhasil
A
B
C
D

Sodium nitrate
Natrium nitrat
Sodium chloride
Natrium klorida
Silver chloride
Argentum klorida
Siver sulphate
Argentum sulfat

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14
27.

Which of the following equation represents the most suitable reaction to prepare an
insoluble salt?
Manakah antara persamaan kimia berikut menunjukkan tindak balas yang paling
sesuai untuk menyediakan garam tak terlarutkan.
A
B
C
D

28.

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PbNO 3 2
Ba NO 3 2
Pb
PbOH 2

+
+
+
+

2KCl
2KCl
H2SO4
2HCl

PbCl2 +
BaCl2 +
PbSO4 +
PbCl2 +

2KNO3
2KNO3
H2
2H2O

Table 4 shows the result of a series of tests carried out on a solution of salt J.
Jadual 4 menunjukkan keputusan beberapa siri ujian yang dijalankan terhadap satu
larutan garam J.
Test
Observation
Ujian
Pemerhatian
Add dilute sulphuric acid
No changes
Tambahkan asid sulfurik cair
Tiada perubahan
Add leadII nitrate solution , then
White precipitate dissolves when
heat it
heated.
Tambahkan plumbum II nitrat,
Mendakan putih larut apabila
kemudian panaskan
dipanaskan
Add sodium hydroxide solution until White precipitate is formed.
in excess
It is insoluble in excess sodium
Tambahkan larutan natrium
hydroxide solution
hidroksida sehingga berlebihan
Mendakan putih terbentuk.
Mendakan tidak larut dalam natrium
hidroksida berlebihan
Add ammonia solution until in
White precipitate is formed.
excess
It is insoluble in excess ammonia
Tambahkan larutan ammonia
solution
berlebihan
Mendakan putih terbentuk
Mendakan tidak larut dalam larutan
ammonia berlebihan
Table 4 / Jadual 4
Based on the results of the experiment, what is salt J?
Berdasarkan keputusan eksperimen, apakah garam J?
A
Magnesium chloride
Magnesium klorida
B
Zinc sulphate
Zink sulfat
C
Zinc chloride
Zink klorida
D
Magnesium sulphate
Magnesium sulfat

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29.

Diagram 8
Rajah 8
Diagram 8 shows ceramic vase which are made from clay. Name the main
component of clay.
Rajah 8 menunjukkan pasu seramik yang diperbuat daripada tanah liat. Namakan
komponen utama tanah liat.
A
B
C
D

30.

Kaolin
Kaolin
Perspex
Perspeks
Silicon dioxide
Silikon dioksida
Aluminium oxide
Aluminium oksida

Which of the following reactions occurs at the highest rate?


Antara tindak balas berikut, yang manakah berlaku pada kadar yang paling tinggi?
A
B
C
D

Photosynthesis
Fotosintesis
Rusting of iron
Pengaratan besi
Fermentation
Penapaian
Precipitation reaction
Tindak balas pemendakan

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31.

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The chemical equation shows a reaction between sodium thiosulphate solution with
hydrochloric acid solution.
Persamaan kimia di bawah menunjukkan tindak balas antara larutan natrium tiosulfat
dan larutan asid hidroklorik
Na2S2O3 + 2HCl

2NaCl +

SO2 + S + H2O

Which of the following changes cannot be used to determine the rate of reaction?
Antara berikut, perubahan manakah yang tidak boleh digunakan untuk
menentukan kadar tindak balas?
A

B
C
D

32.

Change in the pH of the mixture


Perubahan pH campuran
Time taken for X mark disappear from sight
Masa untuk pangkah X hilang daripada pandangan
Increase in mass of sulphur
Peningkatan jisim sulfur
Change in volume of sulphur dioxide gas released
Perubahan isipadu gas sulfur dioksida yang terbebas

Table 5 shows the total volume of gas collected at regular intervals in a reaction.
Jadual 5 menunjukkan jumlah isipadu gas yang dikumpul pada sela masa yang
sekata bagi satu tindak balas.
Time / min

0.0

0.5

Volume of gas / cm3

0.00

8.00

1.0

2.0

2.5

3.0

3.5

14.50 20.50 24.00 26.50 26.50 26.50


Table 5
Jadual 5

What is the average rate of reaction?


Berapakah kadar tindak balas purata?
A
0.10 cm3 min-1
B
7.60 cm3 min-1
C
10.60 cm3 min-1
D
37.40 cm3 min-1

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33.

Diagram 9
Rajah 9
A slice of meat which has been cut into smaller pieces takes a shorter time to
cook if compared to a slice of meat which did not cut to smaller pieces
Sekeping daging yang dipotong kepada kepingan-kepingan kecil akan
mengambil masa yang lebih cepat untuk dimasak berbanding sekeping daging
yang tidak dipotong.
Based on the above statement, choose the
. best explanation.
Berdasarkan pernyataan di atas, pilih penjelasan yang paling sesuai.
A
B

The smaller the size of reactant, the higher the kinetic energy of the particles
Lebih kecil saiz bahan tindak balas, lebih tinggi tenaga kinetik zarah-zarah.
The smaller the size of reactant, more particles in reactant will exist
Lebih kecil saiz bahan tindak balas, semakin banyak jumlah zarah yang
wujud.
The smaller the size of reactant, the lower activation energy needs for a
reaction to occur.
Lebih kecil saiz bahan tindak balas, lebih rendah tenaga pengaktifan yang
diperlukan untuk tindak balas.
The smaller the size of reactant, the bigger the total surface area.
Lebih kecil saiz bahan tindak balas, lebih besar luas jumlah permukaan
bahan tindak balas tersebut

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Situation A
Situasi A

Situation B
Situasi B
Diagram 10
Rajah 10

34.

Diagram 10 shows Puan Siti dry the cloth at two different places, which are situation
A: outside home, while situation B: inside home. Which situation can dry the cloth
faster and why?
Rajah 10 menunjukkan Puan Siti menjemur pakaian pada dua tempat yang berbeza,
iaitu situasi A: di luar rumah, manakala situasi B: di dalam rumah. Situasi manakah
yang dapat mengeringkan baju dengan lebih cepat dan mengapa?
Situation
Reason
Situasi
Sebab
A
A
There are more air particles outside home
compared to inside the home.
Lebih banyak zarah udara terdapat di luar rumah
berbanding di dalam rumah.
B
A
Temperature outside home is higher than inside
home.
Suhu di luar rumah lebih tinggi berbanding di dalam
rumah
C
B
The smaller space inside home can provide more
heat compared to outside home.
Ruang yang sempit di dalam rumah boleh
menghasilkan lebih banyak haba berbanding di luar
rumah.
D
B
There are air movement inside the home compared
to outside the home.
Terdapat pergerakan udara di dalam rumah
berbanding di luar rumah.

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35.

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Table 6 shows the experiments carried out to study the rate of reaction between zinc
carbonate and nitric acid.
Jadual 6 menunjukkan eksperimen yang dijalankan untuk mengkaji kadar tindak
balas antara zink karbonat dan asid nitrik
Experiment
Eksperimen

I
II

Zinc carbonate, ZnCO3


Zink karbonat, ZnCO3
Mass g
State
Jisim g
Keadaan
5
Granule
Butiran
5
Powder
Serbuk

Nitric acid, HNO3


Asid nitrik, HNO3
3
Volume cm
Concentration mol dm -3
Isipadu cm 3
Kepekatan mol dm -3
50
0.1
25

0.2

Table 6
Jadual 6
Which of the following graph represents the two experiments?
Antara berikut, graf manakah menunjukkan graf untuk kedua-dua eksperimen?
A

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36.

Which of the following is correct about the conversion of unsaturated fats to saturated
fats?
Antara berikut, yang manakah betul tentang penukaran lemak tak tepu kepada lemak
tepu?
A
Intermolecular forces of attraction become weaker
Daya tarikan antara molekul menjadi lemah
B
The boiling point of the fats increases
Takat didih lemak meningkat
C
Physical state changes from solid to liquid
Keadaan fizikal berubah daripada pepejal ke cecair
D
Relative molecular mass of the oil molecule decreases
Jisim relatif molekul minyak berkurang

37.

The structural formulae of two isomers are as follows.


Formula struktur untuk dua isomer ditunjukkan seperti berikut.
H H H H
| |
| |
HCCCCH
|
|
| |
H H Br H

H H H Br
| | |
|
HCCCCH
|
|
| |
H H H H

Which of the following name can be used for both isomers?


Nama yang manakah antara berikut boleh digunakan untuk kedua-dua isomer?
A
Bromoethane
Bromoetana
B
Bromopropane
Bromopropana
C
Bromobutane
Bromobutana
D
Bromopentane
Bromopentana

4541/1 PAHANG

21
38.

4541/1

When propane is burned in excess oxygen, carbon dioxide and water are formed and
is represented by the equation
Apabila propana terbakar dalam oksigen berlebihan, karbon dioksida dan air
dihasilkan dan persamaan yang terhasil adalah
a C3H8 +

b O2

c CO2 +

d H2O

What are the values of a, b, c and d?


Apakah nilai a, b, c dan d?
a
1
2
2
1

A
B
C
D
39.

b
5
5
5
5

c
1
1
3
3

d
3
5
8
4

Fuel is needed for machine to operate and vehicles to move. Both butane and butene
can be used as fuel because the reaction of combustion in air is an exothermic. What
are the others similar characteristics that butane and butene have?
Bahan api diperlukan untuk sesebuah mesin beroperasi dan kenderaan untuk
bergerak. Kedua-dua butana dan butena boleh digunakan sebagai bahan api kerana
tindak balas pembakaran keduanya adalah eksotermik, Apakah ciri-ciri sepunya lain
yang dipunyai oleh butana dan butena?
I
Exist as gas at room temperature.
Wujud sebagai gas pada suhu bilik
II
Decolourise the purple colour of acidified potassium manganateVII.
Menyahwarna ungu kalium manganat VII berasid
III
Cannot dissolve in water.
Tidak larut dalam air
IV
Terbakar di udara berlebihan menghasilkan gas yang mengeruhkan air kapur
Burn in excess air to produce a gas that turns limewater cloudy.
A
B
C
D

I and III only


I dan III sahaja
II and IV only
II dan IV sahaja
I, III and IV only
I, III dan IV sahaja
I, II, III dan IV
I, II, III dan IV

4541/1 PAHANG

22

4541/1

40.

The lorry tyres are made from vulcanized rubber. What property of vulcanized rubber
makes it suitable to be used for making these lorry tyres?
Tayar lori diperbuat daripada getah tervulkan. Apakah ciri getah tervulkan yang
paling sesuai menyebabkan ia digunakan sebagai tayar lori?
A
Resist to heat
Tahan haba
B
Harder and stronger
Keras dan kuat
C
Resist to oxidation
Tahan pengoksidaan
D
Can maintain their elasticity
Boleh mengekalkan sifat elastik

41.

Which of the following is an oxidation process?


Manakah antara berikut menunjukkan proses pengoksidaan?
A
B
C
D

42.

Which of the following chemical equation, is not a redox reaction?


Manakah antara berikut bukan tindak balas redoks?
A
B
C
D

43.

Zinc atom forms zinc ion


Atom zink membentuk ion zink
Butene changes into butane
Butena ditukarkan kepada butana
Lead II oxide loses its oxygen
Plumbum II oksida kehilangan oksigen
Bromine molecule gains electrons
Molekul bromin menerima electron

CuO
Mg
Cl2
Ag+

+
+
+
+

Zn
2 AgNO3
S2Cl-

ZnO +
MgNO 3 2 +
2Cl+
AgCl

Cu
2 Ag
S

What is the oxidation number of sulphur in Na2S2O3?


Apakah nombor pengoksidaan sulphur dalam Na2S2O3?
A
B
C
D

+2
+3
+4
+6

4541/1 PAHANG

23
44.

4541/1

The manufacture of sulphuric acid in the Contact Process involves the following
steps.
Pembuatan asid sulfurik dalam Proses Sentuh melibatkan langkah berikut.
S

SO2

SO3

H2SO4

Based on the equation above, which of the following is the correct oxidation number
of sulphur?
Berdasarkan persamaan di atas, yang manakah antara berikut merupakan nombor
pengoksidaan yang betul untuk sulfur?
S
SO2
SO3
H2SO4
A
0
+2
+3
+4
B
0
+2
+6
+6
C
0
+4
+6
+6
D
0
+4
+6
+8
45.

The following thermochemical equation shows the reaction between sodium


hydrogen carbonate and hydrochloric acid.
Persamaan termokimia berikut menunjukkan tindak balas antara natrium hidrogen
karbonat dan asid hidroklorik.
NaHCO3 +

HCl

NaCl

+ H2O + CO2

H = +11.8 kJmol-1

Which of the following is true about the reaction?


Antara berikut yang manakah benar tentang tindak balas itu?

A
B
C
D

4541/1 PAHANG

Heat change
Perubahan haba
Heat absorbed
Haba diserap
Hear absorbed
Haba diserap
Heat released
Haba dibebas
Heat released
Haba dibebas

Type of reaction
Jenis tindak balas
Exothermic
Eksotermik
Endothermic
Endotermik
Endothermic
Endothermic
Exothermic
Eksotermik

24
46.

4541/1

The thermochemical equation for a neutralisation reaction is given below.


Persamaan termokimia untuk tindak balas peneutralan diberi di bawah.
KOH

HCl

KCl

H2O

H = -57 kJ mol-1

Which neutralization reaction has the same value of the heat of neutralisation?
Manakah tindak balas peneutralan yang mempunyai nilai haba peneutralan yang
sama?
A
B
C
D

47.

HCl
+
CH3COOH
NaOH +
CH3COOH

NH3
+
HNO3
+

NH4Cl
KOH
CH3COOK
+
H2O

NaNO3
+
H2O
NH4OH

CH3COONH4 +

H2O

In an experiment, excess zinc powder is added to 50 cm3 0.1 mol dm-3 copper II
sulphate solution. The thermochemical equation is as shown:
Dalam satu eksperimen, serbuk zink ditambah secara berlebihan kepada 50 cm3
0.1 mol dm-3 larutan kuprum II sulfat. Persamaan termokimia untuk tindak balas itu
adalah seperti berikut:
Mg

Zn2+

Zn

Mg2+

H = -210 kJ mol-1

Calculate the temperature rise in this experiment.


[Specific heat capacity of solution: 4.2 Jg-1 0C-1, density of solution : 1gcm-3]
Hitungkan kenaikan suhu dalam eksperimen ini.
[Muatan haba tentu larutan: 4.2 Jg-1 0C-1, ketumpatan larutan: 1gcm-3]
0

50

x
50

0.1
x

x
4.2

210000

50
50

x
x

4.2
0.1

x
x

210000
1000

50

x
50

4.2
x

x
0.1

210.00

50

x
50

0.1
x

x
4.2

210.00

4541/1 PAHANG

25
48.

4541/1

Diagram 11 shows the energy level diagram for the reaction between silver ions and
chloride ions.
Rajah 11 menunjukkan rajah aras tenaga untuk tindak balas antara ion argentum
dan ion klorida.
Energy
Ag+aq + Cl

aq
H = - 65.5 kJmol-1
AgCls)
Diagram 11
Rajah 11

Which of the following statements is true about this reaction?


Antara berikut, pernyataan manakah adalah benar mengenai tindak balas ini?
A
B
C
D

49.

Endothermic reaction occurs


Tindak balas endotermik berlaku
The energy content of the product is higher than the reactants
Kandungan tenaga hasil tindak balas tinggi daripada bahan tindak balas
65 kJ of heat is absorbed when 1 mol of silver chloride is formed
65 kJ haba diserap apabila 1 mol argentums klorida terbentuk
The final temperature at the end of the reaction is higher than the initial
temperature.
Suhu akhir pada akhir tindak balas lebih tinggi daripada suhu awal.

Hilmi has the following symptoms: fever, headache, muscle and joint pains. The
medicine that can be taken to relieve the symptoms is
Hilmi mempunyai gejala-gejala seperti berikut: demam, pening kepala, sakit otot, dan
sakit sendi. Ubat yang boleh diambil untuk menangani gejala-gejala itu adalah
A
B
C
D

Codeine
Kodeina
Penicilin
Penisilin
Paracetamol
Parasetamol
Amphetamine
Amfetamin

4541/1 PAHANG

26
50.

4541/1

Why detergents are more effective than soaps?


Mengapa detergen lebih efektif berbanding sabun?
A
B
C

Detergents are soluble in grease


Detergen larut dalam gris
Detergents do not form scum in hard water
Detergen tidak membentuk kekat dalam air liat
Detergent has hydrocarbon chain which makes detergent dissociate less in
hard water
Detergen mengandungi ikatan hidrokarbon yang membuatkan detergen
kurang terpisah dalam air liat
The presence of magnesium ions in detergent forms scum
Kehadiran ion magnesium dalam detergen menghasilkan kekat.

END OF QUESTION PAPER


KERTAS SOALAN TAMAT
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4541/1 PAHANG

SULIT
NAMA :....................................................................................................
KELAS :...................................................................................................

PEPERIKSAAN PERCUBAAN
SIJIL PELAJARAN MALAYSIA 2015

4541/2

https://cikguadura.wordpress.com/

CHEMISTRY
Kertas 2
September
2 jam

2 jam 30 minit

DO NOT OPEN THIS PAPER UNTIL YOU ARE TOLD TO DO SO


JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU
1.

2.

3.

4.

5.

Tulis nama dan tingkatan anda


pada ruangan yang disediakan di
atas.
Kertas soalan ini adalah dalam
dwibahasa.

Untuk Kegunaan Pemeriksa


Bahagian

Soalan dalam Bahasa Inggeris


mendahului soalan yang sepadan
dalam Bahasa Melayu.
Calon dibenarkan menjawab
keseluruhan atau sebahagian soalan
sama ada dalam Bahasa Inggeris
atau Bahasa Melayu.
Calon dikehendaki membaca
maklumat di halaman belakang
kertas soalan ini

Soalan

Markah
Penuh

10

10

11

11

20

20

20

10

20

Markah
diperoleh

C
JUMLAH
------------------------------------------------------------------------------------------------------------------------------Kertas soalan ini mengandungi 33 halaman bercetak

4541/2

Section A
Bahagian A
[60 marks]
[60 markah]
Answer all the questions in this section.
Jawab semua soalan dalam bahagian ini.
https://cikguadura.wordpress.com/

1.

Diagram 1.1 shows the observation of an experiment when solid iodine is put into a gas
jar to prove the kinetic theory of matter.
Rajah 1.1 menunjukkan pemerhatian satu eksperimen apabila pepejal iodin diletakkan di
dalam satu balang gas bagi membuktikan teori kinetik jirim.

Gas jar
Balang gas

Purple coloured gas


Gas berwarna ungu

After several hours


Solid iodine
Pepejal iodin

Selepas beberapa jam

Diagram 1.1
Rajah 1.1
(a) (i) Name the process in this experiment.
Namakan proses dalam eksperimen itu.
......................................................................................................................
[1 mark]
[1 markah]

4541/2 PAHANG

[Lihat sebelah]

4541/2

(a) (ii) Draw the arrangement of the iodine particles in the solid and gaseous state.
Lukiskan susunan zarah-zarah iodin dalam keadaan pepejal dan gas.

Solid / Pepejal

Gas/Gas
[2 marks]
[2 markah]

(a) (iii) State the type of particles in gaseous iodine


Nyatakan jenis zarah dalam gas iodin.
..................................................................................................................
[1 mark]
[1 markah]
(b)

Diagram 1.2 shows the setup of the apparatus used in an experiment to


determine the empirical formula of an oxide of copper.
Rajah 1.2 menunjukkan radas yang digunakan dalam eksperimen untuk
menentukan formula empirik kuprum oksida.

Diagram 1.2
Rajah 1.2

4541/2 PAHANG

[Lihat sebelah]

4
(i)

4541/2

What is meant by empirical formula?


Apakah yang dimaksudkan dengan formula empirik?
.................................................................................................................................
................................................................................................................................
[1 mark]
[1 markah]

(ii)

State the name of two reactants to prepare hydrogen gas in the laboratory.
Nyatakan nama bagi dua bahan tindak balas untuk menyediakan gas hidrogen di
dalam makmal.

[2 marks]
[2 markah]

(iv)

State how to determine that the reaction between copper(II) oxide with hydrogen
gas has been completed.
Nyatakan bagaimana untuk menentukan bahawa tindak balas yang berlaku
antara kuprum(II) oksida dengan gas hidrogen telah lengkap.
................................................................................................................................
[1 mark]
[1 markah]

(iii)

State another metal oxide whose empirical formula can be determined using the
same method.
Nyatakan satu oksida logam lain yang formula empiriknya boleh ditentukan
dengan menggunakan kaedah yang sama.
.................................................................................................................................
[1 mark]
[1 markah]

4541/2 PAHANG

[Lihat sebelah]

4541/2
Carbon dioxide gas
Gas karbon dioksida

Syringe
Picagari
Calcium carbonate powder
Serbuk kalsium karbonat
Hydrochloric acid
Asid hidroklorik
Diagram 2.1
Rajah 2.1
2

Diagram 2.1 shows the set up apparatus of an experiment to investigate the reaction
between calcium carbonate and hydrochloric acid. A student collect the gas released by
using a syringe. 30 cm3 of carbon dioxide gas was collected at room condition.
Rajah 2.1 menunjukkan susunan radas satu eksperimen bagi mengkaji tindak balas di
antara kalsium karbonat dan asid hidroklorik. Seorang pelajar mengumpul gas yang
terbebas dengan menggunakan picagari. 30 cm3 gas karbon dioksida telah dikumpulkan
pada keadaan bilik.
(a) (i)

Write the chemical equation for the reaction.


Tuliskan persamaan kimia bagi tindak balas tersebut.

[2 marks]
[2 markah]
(ii)

Calculate the number of moles of carbon dioxide gas in the syringe.


Hitungkan bilangan mol gas karbon dioksida yang terdapat dalam picagari
tersebut.
[Molar volume=24 dm3 mol-1 at room condition]
[Isipadu molar = 24 dm3 mol-1 pada keadaan bilik]

[1 mark]
[1 markah]

4541/2 PAHANG

[Lihat sebelah]

6
(iii)

4541/2

Calculate the number of molecule of carbon dioxide gas in the syringe


Hitungkan bilangan molekul gas karbon dioksida dalam picagari.
[Avogadro Constant: 6.02 x 1023 mol-1 ]
[Pemalar Avogadro : 6.02 x 1023 mol-1 ]

[1 mark]
[1 markah]
(iv) Calculate the maximum mass of calcium carbonate needed to produce carbon
dioxide gas in the syringe.
Hitungkan jisim maksimum kalsium karbonat yang diperlukan untuk
menghasilkan gas karbon dioksida di dalam picagari tersebut.
[Relative atomic mass: Ca=40, C=12, O=16]
[Jisim atom relatif: Ca=40, C=12, O=16]

[2 marks]
[2 markah]

4541/2 PAHANG

[Lihat sebelah]

4541/2

Diagram 2.2
Rajah 2.2
(b)

Diagram 2.2 shows the structural formula of monosodium glutamate


(MSG). Monosodium glutamate is food additives usually added into the
food to make it more delicious.
Rajah 2.2 menunjukkan formula struktur bagi mononatrium glutamat
(MSG). Mononatrium glutamat adalah bahan tambah makanan yang
biasanya ditambahkan ke dalam makanan untuk menyedapkan rasanya.

(i)

Write the molecular formula of MSG.


Tuliskan formula molekul bagi MSG.

(ii)

..
[1 mark]
[1 markah]
State the types of compound for MSG.
Nyatakan jenis sebatian bagi MSG.

..
[1 mark]
[1 markah]
(iii)

Calculate the relative formula mass of monosodium glutamate.


Hitungkan jisim formula relatif bagi mononatrium glutamat.
[Relative atomic mass of C=12, O=16, N=14, Na=23, H=1]
[Jisim atom relatif C=12, O=16, N=14, Na=23, H=1]

[1 mark]
[1 markah]
4541/2 PAHANG

[Lihat sebelah]

1
1

4541/2

13

14

15

16

17

18

2
3

U
W

4
5
6

Diagram 3.1
Rajah 3.1
3

Diagram 3.1 shows the Periodic Table of elements. The letters P, Q, U and W do not
represent the actual symbols of the elements.
Rajah 3.1 menunjukkan suatu Jadual Berkala Unsur. Huruf P, Q, U dan W tidak
mewakili simbol sebenar unsur berkenaan.
(a)

Table 3 shows one characteristic for each of elements R, S and T.


Jadual 3 menunjukkan satu ciri bagi setiap unsur R, S dan T.
Element
Unsur
R
S
T

(i)

4541/2 PAHANG

Characteristic
Ciri
Located in Period 2 and has 6 valence electrons
Terletak di kala 2 dan mempunyai 6 elektron valens
Has electron arrangement of 2.8.8.1
Mempunyai susunan elektron 2.8.8.1
Has a stable duplet electron arrangement
Mempunyai susunan elektron duplet yang stabil
Table 3
Jadual 3
Referring to Table 3, indicate the positions of R, S and T by writing the
letters in the correct boxes of the above Periodic Table
Merujuk kepada ciri dalam Jadual 3, tuliskan abjad R, S dan T pada
kedudukan yang betul dalam Jadual Berkala Unsur di atas.
[3 marks]
[3 markah]

[Lihat sebelah]

(b)

4541/2

Which element among P, Q, R, S, T, U and W exists as a monoatomic gas?


Antara unsur P, Q, R, S, T, U dan W yang manakah wujud sebagai gas
monoatom?
.. ........................................................................
[1 mark]
[1 markah]

(c)

(d)

Element P and R can react to form a liquid. Write the chemical formula of the
compound formed.
Unsur P dan unsur R boleh bertindak balas menghasilkan suatu cecair. Tuliskan
formula kimia bagi sebatian yang terbentuk.
.................................................................................................................................
[1 mark]
[1 markah]
Both elements of Q and S can react with water.
Kedua-dua unsur Q dan S boleh bertindak balas dengan air.
(i)

(ii)

Which element reacts more vigorously ?


Unsur manakah menunjukkan tindak balas yang lebih cergas ?
.........................................................
[1 mark]
[1 markah]
Explain your answer in (d)(i).
Terangkan jawapan anda dalam (d) (i).
.....................................................................................................................
.....................................................................................................................
.....................................................................................................................
.....................................................................................................................
[3 marks]
[3 markah]

4541/2 PAHANG

[Lihat sebelah]

10

Palm oil
Minyak kelapa sawit
sawit

Margarine
Marjerin

180oC
2 atm
Element W
Unsur W

+ flavouring, salt,
vitamin & colouring
+ perisa, garam,
vitamin & pewarna

4541/2

Saturated fat (solid or semi solid)


Lemak tepu (pepejal atau separa pepejal)

+ Milk
+ Susu
White fat emulsion and milk
Emulsi putih lemak dan susu

Diagram 3.2
Rajah 3.2
(e)

Diagram 3.2 shows the hydrogenation process of palm oil in manufacturing of


margarine. Element W is used in the process. State one of the special
characteristic of element W in the hydrogenation process.
Rajah 3.2 menunjukkan proses penghidrogenan minyak kelapa sawit untuk
menghasilkan marjerin. Unsur W digunakan di dalam proses tersebut. Nyatakan
satu ciri istimewa unsur W di dalam proses tersebut.
..................................................................................................................................
[1 mark]
[1 markah]

4541/2 PAHANG

[Lihat sebelah]

11
4

4541/2

Diagram 4 shows two types of cell.


Rajah 4 menunjukkan dua jenis sel.

Copper plate
Kepingan
kuprum

Zinc plate
Kepingan
zink

Cell R
Sel R

Copper(II)
sulphate
solution
Larutan
kuprum(II)
sulfat

Copper plate
Kepingan kuprum

Cell S
Sel S

Diagram 4
Rajah 4
(a)

What is the meaning of cation?


Apakah maksud kation?
.................................................................................................................................
[1 mark]
[1 markah]

(b)

State all the cations present in copper(II) sulphate solution.


Nyatakan semua kation dalam larutan kuprum(II) sulfat.
.................................................................................................................................
[1 mark]
[1 markah]

(c)

Name the product formed at cathode in Cell R. Explain your answer.


Namakan produk yang terhasil pada katod dalam Sel R. Terangkan jawapan
anda.
.................................................................................................................................
.................................................................................................................................
[2 marks]
[2 markah]

4541/2 PAHANG

[Lihat sebelah]

12
(d)

4541/2

Copper(II) sulphate solution in Cell R is replaced with dilute sulphuric acid. A


colourless gas produced at the cathode is collected.
Larutan kuprum(II) sulfat dalam Sel R digantikan dengan larutan asid sulfurik
cair. Gas tidak berwarna yang terhasil di katod dikumpulkan.
(i)

Name the gas produced.


Namakan gas yang terhasil.

.....................................................................................................................
[1 mark]
[1 markah]
(ii)

Describe one chemical test to confirm the gas in (d)(i).


Terangkan satu ujian kimia untuk mengesahkan gas di (d)(i).
.....................................................................................................................
.....................................................................................................................
[2 marks]
[2 markah]

(e)

State the metal used as negative terminal for Cell S.


Nyatakan logam yang digunakan sebagai terminal negatif di Sel S.
.................................................................................................................................
[1 mark]
[1 markah]

(f)

Zinc electrode in Cell S is replaced with magnesium.


Elektrod zink di Sel S digantikan dengan magnesium.
(i)

Compare the voltage reading of the cell.


Bandingkan bacaan voltan sel tersebut.
.....................................................................................................................
[1 mark]
[1 markah]

(ii)

Explain your answer in (f)(i).


Terangkan jawapan anda di (f)(i).

.....................................................................................................................
[1 mark]
[1 markah]

4541/2 PAHANG

[Lihat sebelah]

13
5

(a)

4541/2

A student conducted an experiment to study the reaction between sulphuric acid


and 0.1 mol dm-3 of sodium hydroxide solution by using phenolphthalein as an
indicator.
Seorang pelajar menjalankan satu eksperimen untuk mengkaji tindakbalas
antara asid sulfurik dan larutan natrium hidroksida 0.1 mol dm-3 dengan
menggunakan fenolftalein sebagai penunjuk.
(i)

Write a chemical equation to represent the reaction.


Tuliskan persamaan kimia bagi tindak balas yang berlaku.
....................................................................................................................
[2 marks]
[2 markah]

(ii)

25 cm3 of 0.1 mol dm-3 sodium hydroxide solution is required to react


completely with 12.50 cm3 of dilute sulphuric acid. Calculate the molarity
of the dilute sulphuric acid used.
25 cm3 larutan natrium hidroksida 0.1 mol dm-3 diperlukan untuk
bertindak balas lengkap dengan 12.50 cm3 asid sulfurik cair. Hitungkan
kemolaran asid sulfurik cair yang digunakan.

[3 marks]
[3 markah]

4541/2 PAHANG

[Lihat sebelah]

14
(iii)

4541/2

Draw a suitable diagram of the set-up of apparatus for the reaction


between sulphuric acid and sodium hydroxide solution in the laboratory.
Lukiskan gambarajah susunan radas yang sesuai bagi tindakbalas antara
asid sulfurik dengan larutan natrium hidroksida di dalam makmal.

[2 marks]
[2 markah]
(v)

If sulphuric acid is replaced by hydrochloric acid with the same


concentration, predict the volume of acid used. Explain your answer.
Jika asid sulfurik digantikan dengan asid hidroklorik dengan kepekatan
yang sama, ramalkan isipadu asid yang digunakan. Terangkan jawapan
anda.
.....................................................................................................................
.....................................................................................................................
[2 marks]
[2 markah]

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home remedy
rawatan di rumah

A child is stung by a bee


Seorang kanak-kanak
terkena sengatan lebah

remove the bee sting as soon


as possible
buangkan sengat lebah
secepat mungkin

Rub the toothpaste on the


bee sting site
Sapukan ubat gigi di atas
kawasan sengatan lebah

Take a toothpaste
Ambil ubat gigi
Diagram 5.1
Rajah 5.1

(b)

Diagram 5.1 shows home remedy to treat a bee sting. In your opinion, give a
rational reason why the toothpaste is apply on the bee sting site?
Rajah 5.1 menunjukkan rawatan di rumah untuk merawat sengatan lebah. Pada
pandangan anda, mengapakah ubat gigi disapukan ke atas kawasan sengatan
lebah tersebut?

.
..................................................................................................................................
..................................................................................................................................
[2 marks]
[2 markah]
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6.

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Diagram 6.1 shows changes of a carbon compound involving a series of reactions.


Rajah 6.1 menunjukkan perubahan sebatian karbon yang melibatkan beberapa siri
tindak balas.
Propane
Propana

Propene
Propena

Reaction I
Tindak balas I

porcelain chips
serpihan porselin
heat
dipanaskan

Propanol
Propanol
Diagram 6.1
Rajah 6.1
(a) State the functional group of propanol.
Nyatakan kumpulan berfungsi bagi propanol.
...................................................................................................................................
[ 1 mark ]
[ 1 markah]
(b) Draw the structural formulae for two isomers of propanol.
Lukiskan formula struktur bagi dua isomer propanol.

[ 2 marks]
[ 2 markah]
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(c) Propanol undergoes Reaction I to form propene.


Propanol mengalami tindak balas I membentuk propena.
(i)

Name reaction I.
Namakan tindak balas I
...................................................................................................................................
[ 1 mark ]
[ 1 markah]

(ii)

Write the balanced chemical equation for the conversion of propanol to propene
in reaction I.
Tuliskan persamaan kimia yang seimbang bagi penukaran propanol kepada
propena dalam tindak balas I.
................................................................................................................................
[ 1 mark]
[ 1 markah]

(d)

Propane and propene are hydrocarbons. Compare the observation when acidified
potassium manganate(VII) solution is added into propane and propene.
Propana dan propena adalah hidrokarbon. Bandingkan pemerhatian apabila larutan
kalium manganat(VII) berasid ditambahkan ke dalam propana dan propena.
....................................................................................................................................
.....................................................................................................................................
....................................................................................................................................
.....................................................................................................................................
[ 3 marks]
[ 3 markah]

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(e)

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Diagram 6.2
Rajah 6.2
Diagram 6.2 shows the liquid car perfume that is usually placed inside the car to
give a fragrance smell like apples. The liquid fragrance smell like apples contains
ethyl pentanoate, with the molecular formula of C4H9COOC2H5.
Rajah 6.2 menunjukkan cecair minyak wangi kereta yang biasanya diletakkan di
dalam kereta untuk memberikan bau wangi seperti epal. Cecair wangi yang berbau
epal ini mengandungi etil pentanoate, dengan formula molekul C4H9COOC2H5.
(i)

Name the homologous series of the liquid car perfume.


Namakan siri homolog bagi cecair pewangi tersebut.
..........................................................................................................................
[ 1 mark ]
[ 1 markah]

(ii)

Describe briefly how the liquid fragrance smell like apples can be prepared in
the laboratory.
Huraikan secara ringkas bagaimana cecair wangi yang berbau seperti epal
boleh disediakan di dalam makmal.

..........................................................................................................................
..........................................................................................................................
..........................................................................................................................
[ 2 marks]
[2 markah]

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Bahagian B
Section B
[20 markah]
Jawab mana-mana satu soalan dalam bahagian ini.
Answer any one question from this section.
https://cikguadura.wordpress.com/

7. Diagram 7.1 shows the flow map for the industrial manufactured of sulphuric acid.
Rajah 7.1 menunjukkan peta alir bagi pembuatan asid sullfurik dalam industri.

Sulphur
Sulfur

+ H2SO4
Step Y
Langkah Y

+ O2
Heat
Panaskan

Oleum
Oleum

Sulphur dioxide
Sulfur dioksida

+ H2O

+ O2
Step X
Langkah X

Sulphur trioxide
Sulfur trioksida

Sulphuric acid
Asid sulfurik
Diagram 7.1
Rajah 7.1

(a) (i)

Name the process of manufacturing sulphuric acid in industry and write a


balanced chemical equation for Step X and Step Y.
Namakan proses pembuatan asid sulfurik dalam industri dan tuliskan persamaan
kimia yang seimbang bagi langkah X dan langkah Y.
[5 marks]
[5 markah]

(iii)

Excess gas that produced during the manufacture of sulphuric acid can cause
environmental pollution. Explain how.
Gas berlebihan yang dibebaskan semasa pembuatan asid sulfurik boleh
menyebabkan pencemaran alam sekitar. Terangkan bagaimana.
[2 marks]
[2 markah]

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(b)

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Diagram 7.2 shows the steps to produce fertilizers X from the reaction between
sulphuric acid and the product of Haber Process.
Rajah 7.2 menunjukkan langkah-langkah untuk menghasilkan baja X daripada
tindak balas di antara asid sulfurik dan produk proses Haber.
Sulphuric Acid
Asid sulfurik
react
bertindak balas
Product of
Haber Process
Produk Proses
Haber

(i)

Fertilizers X
Baja X

Diagram 7.2
Rajah 7.2

State the chemical formula of fertilizers X.


Nyatakan formula kimia bagi baja X.
[ 1 mark ]
[1 markah]

Diagram 7.3
Rajah 7.3
(ii) A farmer found that the crops in his farm is infertile as shown in Diagram 7.3. His
friend suggested two fertilizers to improve the fertility of the soil, urea, CO(NH2)2 and
fertilizers X. Choose the best fertilizer for the growth of the plants. Explain your
answer.
[Relative atomic mass: C=12, O=16, N=14, S=32, H=1]
Seorang petani mendapati tanaman di kebunnya tidak subur seperti yang
ditunjukkan dalam rajah 7.3. Rakannya telah mencadangkan dua jenis baja yang
boleh menambah kesuburan tanah, urea, CO(NH2)2 dan baja X.
Pilih baja yang terbaik untuk penanaman tumbuhan. Terangkan jawapan anda.
[Jisim atom relatif: C=12, O=16, N=14, S=32, H=1]
[4 marks]
[4 markah]
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(c) Table 7.1 shows five different manufactured substances in industry, P, Q, R, S and T
and their uses.
Jadual 7.1 menunjukkan lima bahan buatan berbeza dalam industri, P, Q, R, S, T dan
kegunaannya
Manufactured substances in
industry
Bahan buatan dalam industri
P
Q
R
S
T

Uses
Kegunaan
To make boats and badminton racket
Membuat bot dan reket badminton
To make medals and statues
Membuat medal dan tugu
To make the body of aeroplanes
Membuat badan kapal terbang
To make kitchen ware and internal wall of furnace
Membuat peralatan dapur dan dinding relau
To make prism and lenses
Membuat prisma dan kanta
Table 7.1
Jadual 7.1

Based on Table 7.1, state the names of P,Q,R,S and T


Berdasarkan Jadual 7,1, nyatakan nama bagi P,Q, R, S dan T
[5 marks ]
[5 markah]

(d) Polyethene is one of the polymer widely use in daily life.


State two properties and one use of polyethene in daily life.
Polietena adalah salah satu polimer yang digunakan dengan meluas dalam kehidupan
harian.
Nyatakan dua sifat dan satu kegunaan polietena dalam kehidupan seharian.
[3 marks]
[3 markah]

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8.

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(a) A student has carried out an experiment to construct an ionic equation for the
formation of lead (II) iodide. Seven test tubes of the same size were labelled 1 to 7. A
fixed volume of 5.0 cm3 of 1.0 mol dm-3 potassium iodide solution was poured in each
test tube. The volume of 1.0 mol dm-3 lead (II) nitrate solution that added is shown in
Table 8. The height of precipitate formed in each test tube was measured. The results
are shown in Table 8.
Seorang pelajar telah menjalankan eksperimen untuk membina persamaan ion bagi
pembentukan plumbum (II) iodida. Tujuh tabung uji yang sama saiz dilabelkan dengan
nombor 1 hingga 7. Isipadu tetap larutan kalium iodida 1.0 mol dm-3 sebanyak 5 cm3
dituangkan ke dalam setiap tabung uji. Isipadu larutan plumbum (II) nitrat 1.0 mol dm-3
ditambahkan ke dalam tabung uji seperti yang ditunjukkan di dalam Jadual 8. Tinggi
mendakan yang terbentuk dalam setiap tabung uji diukur. Keputusan eksperimen
ditunjukkan di dalam Jadual 8.

Test tube
Tabung uji
Volume of 1.0 moldm-3
lead(II) nitrate solution / cm3
Isipadu 1.0 moldm-3
plumbum(II) nitrat / cm3
Height of precipitate /cm
Tinggi mendakan / cm

0.5

1.0

1.5

2.0

2.5

3.0

3.5

1.1

2.2

3.4

4.4

5.5

5.5

5.5

Table 8
Jadual 8
(i)

Based on Table 8, plot a graph of the height of precipitate against volume of


lead (II) nitrate solution.
Berdasarkan Jadual 8, plotkan graf tinggi mendakan melawan isipadu larutan
plumbum(II) nitrat.
[3 marks]
[3 markah]

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(ii) Determine the number of moles of lead (II) ions and iodide ions that are
required for the formation of lead (II) iodide. Your answer should consist of
the following:
Tentukan bilangan mol bagi ion plumbum (II) dan ion iodida yang diperlukan
bagi pembentukan plumbum (II) iodida. Jawapan anda hendaklah mengandungi
perkara berikut :

The volume of lead (II) nitrate solution that had reacted completely with 5.0
cm3 of 1.0 mol dm-3 potassium iodide
Isipadu larutan plumbum(II) nitrat yang bertindak balas lengkap dengan 5.0
cm3 1.0 moldm-3 larutan kalium iodida.

Calclate the number of moles of lead(II) ions and iodide ions


Kirakan bilangan mol plumbum(II) ion dan ion iodida

Calculate the number of moles of iodide ions that has reacted with 1 mol of
lead(II) ions.
Kirakan bilangan mol ion iodida yang bertindak balas dengan 1 mol ion
plumbum(II)

Write the ionic equation for the formation of lead(II) iodide.


Tuliskan persamaan ion bagi pembentukan plumbum(II) iodide
[7 marks]
[7 markah]

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(b) Diagram 8 shows the reaction between oxide metal T which is black in colour with
sulphuric acid to form blue salt solution of compound W.
Salt solution W reacts with barium nitrate solution to form salt solution X and insoluble
salt, Solid Y.
Rajah 8 menunjukkan tindak balas di antara oksida logam T yang berwarna hitam
dengan asid sulfurik untuk membentuk larutan garam W yang berwarna biru.
Larutan garam W bertindak balas dengan larutan barium nitrat menghasilkan larutan
garam X dan pepejal Y.

Oxide Metal T
Oksida Logam T

H2SO4

Salt Solution W
Larutan Garam W

Water
Air

+ Ba(NO3)2
Salt Solution X
Larutan Garam X

Solid Y
Pepejal Y

Diagram 8
Rajah 8
Based on Diagram 8 :
Berdasarkan Rajah 8 :
(i) Identify oxide metal T, salt W, salt X and solid Y.
Kenal pasti oksida logam T, garam W, garam X dan pepejal Y.
[4 marks]
[4 markah]
(ii) State one observation when salt solution W reacts with barium nitrate solution
and name the type of reaction occurred.
Nyatakan satu pemerhatian apabila larutan garam W bertindak balas dengan
larutan barium nitrat dan namakan jenis tindak balas yang berlaku.
[2 marks]
[2 markah]

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(iii) Salt solution W reacts with 50 cm3 of 1.0 mol dm-3 barium nitrate solution.
Write the chemical equation for the reaction and calculate the mass of solid Y
produced.
[Relative formula mass of solid Y: 233]
Larutan garam W bertindak balas dengan 50 cm3 1.0 mol dm-3 larutan barium
nitrat. Tuliskan persamaan kimia bagi tindak balas tersebut dan kirakan jisim
pepejal Y yang terhasil.
[Jisim formula relatif bagi pepejal Y : 233]
[4 marks]
[4 markah]

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SECTION C
Bahagian C
[20 markah]
Answer any one question from this section.
Jawab mana-mana satu soalan dalam bahagian ini.
https://cikguadura.wordpress.com/

9.

Table 9 shows the experiments which are carried out to investigate factors that affect the
rate of reaction of zinc powder with acid X and acid Y.
Jadual 9 menunjukkan ekperimen yang dijalankan untuk mengkaji faktor-faktor yang
mempengaruhi kadar tindak balas antara serbuk zink dengan asid X dan asid Y.

Experiment
Eksperimen

II

III

Reactants
Bahan Tindak balas
2 g zinc powder + 50.0 cm3 of 0.5 mol dm3
acid X
2 g serbuk zink + 50.0 cm3 of 0.5 mol dm3
asid X
2 g zinc powder + 50.0 cm3 of 0.5mol dm3
acid Y
2 g serbuk zink + 50.0 cm3 of 0.5 mol dm3
asid Y
2 g zinc powder + 50.0 cm3 of 0.5 mol dm3
acid Y + 5 drops copper(II) sulphate solution.
2 g serbuk zink + 50.0 cm3 of 0.5 mol dm3
asid Y + 5 titis larutan kuprum(II) sulfat

Products
Hasil Tindak balas
Zinc chloride and gas Z
Zink klorida dan gas Z

Zinc sulphate and gas Z


Zink sulfat dan gas Z

Zinc sulphate and gas Z


Zink sulfat dan gas Z

Table 9
Jadual 9
(a)

(i) Name acid X, acid Y and gas Z.


Describe a chemical test to identify gaz Z.
Namakan asid X, asid Y dan gas Z.
Huraikan ujian kimia untuk mengenal pasti gas Z.
[5 marks]
[5 markah]

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(ii)

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Calculate the maximum volume of gas Z produced at room condition in


experiment II.
[Relative atomic mass: Zn, 65. volume of 1 mol of gas at room condition
= 24 dm3]
Kirakan isipadu maksimum gas Z yang terhasil pada keadaan bilik dalam
eksperimen II.
[Jisim atom relatif: Zn, 65. Isipadu 1 mol gas pada keadaan bilik = 24 dm3]
[3 marks]
[3 markah]

(iii) Sketch a graph volume of gas Z against time for experiment I, II and III on the
same axes.
Lakarkan graf isipadu gas Z melawan masa bagi eksperimen I, II dan III pada
paksi yang sama.
[ 4 marks]
[4 markah]
(iv) Compare the rate of reaction in experiment II and III . Explain your answer based
on collision theory
Bandingkan kadar tindak balas dalam eksperimen II dan III. Terangkan jawapan
anda berdasarkan teori perlanggaran.
.
[ 5 marks]
[5 markah]

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Diagram 9
Rajah 9
(b) Diagram 9 shows a baker making his dough in order to make bread. The baker
discovers that the bread dough rises faster in a warm place than in a cool place.
From the situation above, identify the factor that affects the rate of rising of dough
and explain how the factor affects the rate of rising of the dough.
Rajah 9 menunjukkan seorang tukang masak membuat adunan roti. Tukang masak
tersebut mendapati bahawa adunan roti menaik dengan lebih cepat di tempat yang
panas berbanding tempat yang sejuk.
Dari situasi di atas, kenal pasti faktor yang mempengaruhi kadar kenaikan doh dan
terangkan bagaimana faktor tersebut mempengaruhi kadar kenaikan doh tersebut.
[ 3 marks ]
[3 markah]

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Respiration Process
Proses Respirasi

Photosynthesis Process
Proses Fotosintesis

Diagram 10.1
Rajah 10.1

Diagram 10.2
Rajah 10.2

Diagram 10.1 shows the respiration process. Cellular


respiration is the set of metabolic reactions and
processes that take place in the cells of organisms to
convert biochemical energy from nutrients into
adenosine triphosphate (ATP), and then release
waste products. The chemical equation may be
simplified as:

Diagram 10.2 shows the photosynthesis process. In


plants, photosynthesis occurs mainly within the leaves.
Photosynthesis requires carbon dioxide, water, and
sunlight. All of these substances must be obtained by or
transported to the leaves to produce glucose and
release oxygen gas. The chemical equation may be
simplified as:

C6H12O6 + 6O2 6H2O + 6CO2+ energy


H = - x kJmol-1

6CO2 + 6H2O + sunlight C6H12O6 + 6O2


H = + y kJmol-1

Rajah 10.1 menunjukkan proses respirasi sel.


Respirasi sel adalah satu set tindak balas metabolik
dan proses yang berlaku di dalam sel organisma
untuk menukarkan tenaga biokimia daripada nutrien
kepada adenosin trifosfat (ATP), dan kemudian
membebaskan hasil buangan.
Persamaan kimia boleh diringkaskan seperti berikut :
C6H12O6 + 6O2 6H2O + 6CO2+ tenaga
H = - x kJmol-

4541/2 PAHANG

Rajah 10.2 menunjukkan proses fotosintesis. Dalam


tumbuh-tumbuhan, fotosintesis berlaku dengan banyak
pada bahagian daun. Fotosintesis memerlukan karbon
dioksida, air dan cahaya matahari. Kesemua bahanbahan ini mesti diperoleh atau dipindahkan kepada
bahagian daun untuk menghasilkan glukosa dan
membebaskan oksigen. Persamaan kimia boleh
diringkaskan seperti berikut :
6CO2 + 6H2O + cahaya matahari C6H12O6 + 6O2
H = + y kJmol-

[Lihat sebelah]

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10

(a)

4541/2

Based on Diagram 10.1 and 10.2, compare and contrast both processes above.
Your explanation should include the following :
types of chemical reactions
energy content of reactants and products
draw the energy level diagrams
Berdasarkan Rajah 10.1 dan Rajah 10.2, banding bezakan kedua-dua proses di
atas. Penerangan anda perlu memasukkan perkara-perkara berikut :
jenis tindak balas kimia
kandungan tenaga bahan dan hasil tindak balas
lukis gambarajah aras tenaga
[ 8 marks ]
[8 markah]
Spatula
Spatula
Thermometer
Termometer

Metal X
Logam X
Polystyrene Cup
Cawan polistirena
Copper(II) sulphate solution
Larutan kuprum(II) sulfat
Diagram 10.3
Rajah 10.3

(b)

Excess metal X powder is added to 50 cm3 of 0.1 mol dm-3 copper (II) sulphate
solution produce 210 kJmol-1 heat energy. Based on diagram 10.3, suggest metal
X. Calculate the change in temperature of the solution.
[Given that Specific heat capacity of solution : 4.2 J g -1oC-1]
Serbuk logam X berlebihan ditambahkan kepada 50 cm3 0.1 mol dm-3 larutan
kuprum (II) sulfat menghasilkan 210 kJmol-1 tenaga haba. Berdasarkan rajah
10.3, cadangkan logam X. Hitungkan perubahan suhu larutan.
[Muatan haba tentu larutan : 4.2 J g -1oC-1]
[ 4 marks ]
[4 markah]

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W2+ (aq) + SO42-(aq) WSO4 (s)


W2+(ak) + SO42- (ak) WSO4 (p)

(c)

Based on ionic equation above, describe a laboratory experiment to determine


the heat of precipitation of solid WSO4. In your description, include the following
aspects :
Berdasarkan persamaan ion di atas, huraikan satu eksperimen makmal untuk
menentukan haba pemendakan bagi pepejal WSO4. Dalam huraian anda,
sertakan aspek-aspek berikut:

Materials needed
Bahan-bahan yang diperlukan

Procedure of experiment
Prosedur eksperimen

A table to collect data


Jadual untuk mengumpul data
[ 8 marks ]
[8 markah]

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END OF QUESTION PAPER


KERTAS SOALAN TAMAT

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INFORMATION FOR CANDIDATES


MAKLUMAT UNTUK CALON
1.

This question paper consists of three sections: Section A, Section B and Section C.
Kertas soalan ini mengandungi tiga bahagian: Bahagian A, Bahagian B danBahagian C.

2.

Answer all questions in Section A. Write your answers for Section A in the spaces provided in the
question paper.
Jawabsemua soalan dalam Bahagian A. Tuliskan jawapan bagi Bahagian A dalam ruang yang
disediakan dalam kertas soalan

3.

Answer one question from Section B and one question from Section C.
Write your answers for Section B and Section C on the `answer sheet provided by the invigilators.
Answer questions in Section B and Section C in detail.
You may use equations, diagrams, tables, graphs and other suitable methods to explain your answer.
Jawab satu soalan daripada Bahagian B dan satu soalan daripada Bahagian C. Tuliskan jawapan
bagi Bahagian B dan Bahagian C pada kertas tulis yang dibekalkan oleh pengawas peperiksaan.
Jawab Bahagian B dan Bahagian C dengan terperinci. Anda boleh menggunakan persamaan,
gambar rajah, jadual, graf dan cara lain yang sesuai untuk menjelaskan jawapan anda.

4.

The diagrams in the questions are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan

5.

Marks allocated for each question or sub-part of the question is shown in brackets.
Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan dalam kurungan.

6.

Show your working. It may help you to get marks.


Tunjukkan kerja mengira.Ini membantu anda mendapatkan markah.

7.

If you wish to change your answer, neatly cross out the answer that you have done. Then write down
the new answer.
Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan itu.

8.

You may use a non-programmable scientific calculator.


Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan.

9.

You are advised to spend 90 minutes to answer questions in Section A, 30 minutes for Section B and
30 minutes for Section C.
Anda dicadangkan mengambil masa 90 minit untuk menjawab soalan dalam Bahagian A, 30 minit
untuk Bahagian B dan 30 minit untuk BahagianC.

10. Tie together your answer sheets at the end of the examination.
Ikat semua kertas jawapan anda di akhir peperiksaan.

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SULIT

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NAMA :....................................................................................................

KELAS :...................................................................................................

PEPERIKSAAN PERCUBAAN
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SIJIL PELAJARAN MALAYSIA 2015

4541/3

CHEMISTRY
Kertas 3
September
1 jam

1 jam 30 minit

DO NOT OPEN THIS PAPER UNTIL YOU ARE TOLD TO DO SO


JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU
1. Kertas soalan ini adalah dalam dwibahasa.
2. Soalan dalam Bahasa Inggeris mendahului
soalan yang sepadan dalam Bahasa Melayu.
3. Calon dibenarkan menjawab keseluruhan
atau sebahagian soalan sama ada dalam
Bahasa Inggeris atau Bahasa Melayu.
4. Calon dikehendaki membaca maklumat di
halaman belakang kertas soalan ini.

Untuk Kegunaan Pemeriksa


Soalan

Markah
penuh

15

18

17

Markah
diperoleh

JUMLAH
Kertas soalan ini mengandungi 11 halaman bercetak
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SULIT

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Answer all questions.


Jawab semua soalan.
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1.

Diagram 1.1 shows the apparatus set-up for an experiment to determine the
melting point of naphthalene. Solid naphthalene is heated in a water bath until
melts completely.
Rajah 1.1 menunjukkan susunan radas bagi bagi ekspeimen untuk menentukan
takat lebur naftalena. Pepejal naftalena dipanaskan dalam kukus air hingga
melebur dengan lengkap.

Thermometer
Termometer
Boiling tube
Tabung didih
Water bath
Kukus Air
Naphthalene
Naftalena

Diagram 1.1
Rajah 1.1
The readings of the temperature of naphthalene are recorded every 30 seconds
from 60.0oC until 95.0oC.
Table 1.1 shows the thermometer readings of the experiment.
Bacaan suhu naftalene telah direkodkan bagi setiap 30 saat daripada 60.0OC
hingga 95.0oC.
Jadual 1.1 menunjukkan bacaan termometer bagi eksperimen itu.

4541/3 PAHANG

SULIT

Initial temperature:.
Suhu awal

Temperature at 30s: ..
Suhu pada 30 saat

4541/3

For
Examiners
Use

Temperature at 60s:
Suhu pada 60 saat

Temperature at 90s:.
Suhu pada 90 saat

Temperature at 120s: .
Suhu pada 120 saat

Temperature at 150s: .
Suhu pada 150 saat

Temperature at 180s: ..
Suhu pada 180 saat

Temperature at 210s: ..
Suhu pada 210 saat

Temperature at 240s: ..
Suhu pada 240 saat

Table 1.1
Jadual 1.1
(a)

Record the temperature for every 30 second interval as shown in Table 1.1.
Rekodkan suhu bagi setiap sela masa 30 saat dalam Jadual 1.1
[3 marks]

4541/3 PAHANG

SULIT

4541/3 For
Examiners
Use

(b)

(i)

(ii)

Plot a graph of temperature against time for the heating of naphthalene on the
graph paper given in page 5.
Plotkan graf suhu melawan masa bagi pemanasan naftalena di atas kertas graf
yang disediakan pada muka surat 5.
[3 marks]

State the melting point of naphthalene, and show on the graph how you
determine this melting point.
Nyatakan takat lebur naftalena, dan tunjukkan di atas graf bagaimana
anda tentukan takat lebur ini.

[3 marks]
( c)

The temperature of naphthalene did not change from 90th second until the 150th second
during the melting process. Explain why.
Suhu naftalena tidak berubah dari saat ke-90 hingga saat ke-150 semasa proses
peleburan itu. Terangkan mengapa.

..
.
[3 marks]

4541/3 PAHANG

SULIT
(b) (i)

4541/3 PAHANG

4541/3

SULIT
d)

4541/3

Naphthalene is an example of a covalent compound and Magnesium chloride


is an example of an ionic compound. Classify the following into covalent or ionic
compounds.
Naftalena adalah satu contoh sebatian kovalen manakala Magnesium klorida adalah
satu contoh sebatian ion. Kelaskan sebatian berikut kepada sebatian kovalen atau
sebatian ion.

For
Examiners
Use

Potassium bromide, zinc nitrate, glucose, methanol,


ethyl ethanoate , sodium chloride
..
Kalium bromida, zink nitrat, glukosa, metanol,
etil etanoat, natrium klorida
Ionic compound
Sebatian ion

Covalent compound
Sebatian kovalen

3
[3 marks]

TOTAL

4541/3 PAHANG

SULIT

4541/3

2. Table 2.1 shows the observation in five test tubes used to investigate the effect of other
metals on rusting. A mixture of jelly solution, potassium hexacyanoferrate(III),
K3Fe(CN)6 solution and phenolphthalein were used as medium in each test tube. The
observations were recorded after one day.
Jadual 2.1 menunjukkan pemerhatian dalam lima buah tabung uji yang digunakan
untuk menyiasat kesan logam lain ke atas pengaratan. Medium yang digunakan di
dalam setiap tabung uji adalah campuran larutan agar, larutan kalium
heksasianoferat(III), K3Fe(CN)6 dan fenolftalein. Pemerhatian direkod selepas satu
hari.
Very low intensity of blue colour
Very low intensity of pink colour
Keamatan warna biru sangat
rendah
Keamatan warna merah jambu
sangat rendah

Test tube 1
Tabung uji 1

No blue spot
Low intensity of pink colour
Tiada tompokan biru
Keamatan warna merah jambu
sangat rendah

Test tube 2
Tabung uji 2

Test tube 3
Tabung uji 3

Iron nail coiled with


stanum strip
Paku besi dililit dengan
kepingan stanum

No blue spot
High intensity of pink colour
Tiada tompokan biru
Keamatan warna merah jambu
tinggi

Test tube 4
Tabung uji 4

Test tube 5
Tabung uji 5

Low intensity blue of blue colour


Low intensity of pink colour
Keamatan warna biru rendah
Keamatan warna merah jambu
rendah

Iron nail coiled with


metal Q strip
Paku besi dililit dengan
kepingan logam Q
Table 2.1 // Jadual 2.1

4541/3 PAHANG https://cikguadura.wordpress.com/

High intensity blue of blue colour


Low intensity of pink colour
Keamatan warna biru sangat tinggi
Keamatan warna merah jambu
rendah

For
Examiners
Use

SULIT

4541/3

For
Examiners
Use

(a) State the observation and inference for test tube 2, 3 and 4.
Nyatakan pemerhatian dan inferens untuk tabung uji 2, 3 dan 4.

Test tube
Tabung uji

Observation
Pemerhatian

Inference
Inferens

[6 marks]

(b) State the hypothesis for the experiment.


Nyatakan hipotesis bagi eksperimen ini.
..
...
..
[3 marks]
(c) For this experiment, state:
Bagi eksperimen ini, nyatakan
(i)

The manipulated variable :


Pembolehubah dimanipulasi :
...

(ii)

The responding variable :


Pembolehubah bergerakbalas :

(iii)

The constant variable :


Pembolehubah dimalarkan :
.........
[3 marks]

4541/3 PAHANG

SULIT
(d)

4541/3

State the one operational definition for the experiment.


Nyatakan satu definisi secara operasi bagi eksperimen ini.

For
Examiners
Use

............................................................................................................................................
[3 marks]

(e)

Based on the observation of test tube 5 in Table 2.1, predict metal Q.


Berdasarkan pemerhatian bagi tabung uji 5 dalam Jadual 2.1, ramalkan logam Q.

[3 marks]

TOTAL

4541/3 PAHANG

SULIT

10

4541/3

3
Experiment I : NaOH + HCl NaCl + H2O

H = - 57.5 kJmol-1

Experiment II : NaOH + CH3COOH CH3COONa + H2O

H = - 55 kJmol-1

The value of the heat of neutralization for the reaction between sodium
hydroxide solution and strong acid solution is higher than the value of the heat
of neutralization for the reaction between sodium hydroxide solution and weak
acid solution.
Nilai haba peneutralan bagi tindak balas antara larutan natrium hidroksida
dengan larutan asid kuat lebih tinggi daripada haba peneutralan larutan natrium
hidroksida dengan larutan asid lemah.
Based on the above statement, you are required to design an experiment to determine and
compare the heat of neutralization between sodium hydroxide solution with a named strong
acid solution and a weak acid solution.
Berdasarkan pernyataan di atas, anda dikehendaki merancang eksperimen untuk
menentukan haba peneutralan di antara larutan natrium hidroksida dengan satu larutan
asid kuat dan satu larutan asid lemah yang dinamakan.
Your planning should include the followings :
Perancangan anda hendaklah mengandungi perkara-perkara berikut:
(a)

Problem Statement
Pernyataan masalah

(b)

Hypothesis
Hipotesis

(c)

All the variables


Semua pemboleh ubah yang terlibat

(c)

List of materials and apparatus


Senarai bahan dan alat radas

(d)

Procedure of the experiment


Prosedur eksperimen

(e)

Tabulation of data
Penjadualan data
[17 marks]
END OF QUESTION PAPER
KERTAS SOALAN TAMAT

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4541/3 PAHANG

SULIT

11

INFORMATION FOR CANDIDITES


1. This question paper consists of three questions. Answer all questions.
2. Write your answers for Question 1 and Question 2 in the spaces provided in the
question paper.
3. Write your answers for Question 3 on the helaian tambahan. You may use
equation, diagrams, tables, graphs and other suitable methods to explain your
answer.
4. Show your working, it may help you to get marks.
5. If you wish to change your answer, neatly cross out the answer that you have done.
Then write down the new answer.
6. The diagrams in the questions are not drawn to scale unless stated.
7. Mark allocated for each question or part question are shown in brackets.
8. The time suggested to answers Question 1 and Question 2 is 45 minutes and
Question 3 is 45 minutes.
9. You may use a non-programmable scientific calculator.
10. Hand your answer sheets at the end of the examination.

Marks awarded:
Mark
3
2
1
0

4541/3 PAHANG

Description
Excellent
: The best response
Satisfactory
: An average response
Weak
: An inaccurate response
No response or wrong response

4541/3

ANSWER SCHEME
CHEMISTRY
PAPER 1
(TRIAL 2015)

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25

B
D
B
B
C
A
A
B
A
B
D
C
A
C
D
A
A
C
B
B
B
C
D
D
C

26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50

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C
A
A
A
D
A
C
D
B
A
B
C
D
C
B
A
D
A
C
B
C
D
D
C
B

Marking Scheme
Chemistry Paper 2 (4541/2)
SPM Trial Exam 2015
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Question
1

(a)

(i)

Marking Criteria
Diffusion
a: sublimation

Sub
mark
1

Mark

1
1

(ii)

Solid

(b)

Gas

(iii)

Molecule

(i)

Formula that shows the simplest ratio of atoms of each


elements in a compound

(ii)

Any suitable named metal


Any suitable named acid

1
1

Sample answer :
- Zinc (r: formula) (r: Copper // Argentum)
- Sulphuric acid
(iii)

Repeat heating, cooling and weighing process untill constant


mass is obtained

(iv)

Any suitable oxide metal lower than Hydrogen in reactivity


series
Sample answer : PbO // AgO

1
1

Total

Question
2

(a)

Marking Criteria

Sub
mark

(i)

CaCO3 + 2HCl CaCl2 + CO2 + H2O

(ii)

1- Correct formula of reactants and products


2- Correct balance
30/24000 mol // 0.00125 mol

1
1
1

(iii)

0.00125 x 6.02 x 1023 // 7.505 x 1020

(iv)

1. correct ratio mol //mol of CaCO3


2. correct mass with correct unit
Sample answer :
1. 1 mol CO2 : 1 mol CaCO3
0.00125 mol CO2 : 0.00125 mol CaCO3

2. Mass CaCO3 = 0.00125 x 100 g // 0.125 g


(b)

(i)
(ii)
(iii)

1
1

C5H8NO4Na
Ionic compound (r : ionic bond)
169

Question

Mark

1
1
1
Total

Marking Criteria

(a)
T

Sub
mark
1
1
1

1
1
1
9

Mark
3

(b)
(c)
(d)

T
P2R // H2O
(i)
(ii)

(iii)

S
- Atom S is more reactive than atom Q.
- Valence electron in atom S is further away from the nucleus
compare to atom Q.
- The attraction force between the proton in the nucleus of
atom S is weaker than atom Q // Atom S is more easier to
released electron than atom Q.
- Act as a catalyst

1
1
1
1

1
3

1
Total

1
10

Question
4

Marking Criteria

Sub
mark

Mark

(a)

Positively charged ion // Positive ion

(b)

Cu2+ and H+

(c)

- Copper
- Cu2+ received 2 electrons (to form copper)

(d)

(i)

Hydrogen (r: formula)

(ii)

- Put the burning wooden splinter into the mouth of the test
tube containing the gas
- the pop sound produced

(e)
(f)

1
1

2
1

1
1

Zinc

(i)

The voltage reading of Cell S increase (when the zinc


electrode is replaced with magnesium) //
The voltage reading of Cell S is higher when the zinc
electrode is replaced with magnesium

(ii)

Magnesium is more electropositive than zinc //


Magnesium is higher than zinc in the electrochemical series

Total

10

Question
5

(a)

(i)

(ii)

Marking Criteria
H2SO4 + 2NaOH Na2SO4 + 2H2O
- Correct formula of reactants and products
- Balanced equation

Sub
mark
1
1

Mark

1. Correct no of mol of NaOH


2. Correct ratio mol
3. Correct molarity with correct unit
Sample answer :
1. mol NaOH : 0.1 x 25 /1000 // 0.0025
2. 0.0025 mol NaOH : 0.00125 mol H2SO4
3. Molarity H2SO4 = 0.1 mol dm-3

1
1
1

(iv)
burrette
Sulphuric acid

Sodium hydroxide
+ phenolphthalein
- Functional diagram
- Labelled diagram
(v)

(b)

- 25 cm3
- Concentration of H+ in the hydrochloric acid is half of
sulphuric acid // Concentration of H+ in the sulphuric acid is
double of hydrochloric acid
- Bee sting is acidic, toothpaste is basic//alkaline
- Toothpaste neutralises the bee sting

1
1
1
1

1
1
Total

2
2

2
11

Question
6

Marking Criteria

Sub
Mark
1

Total
Mark
1

1+1

(i) Dehydration

(ii) C3H7OH C3H6 + H2O

(a)

Hydroxyl group // -OH group

(b)

(c)

(d)

(e)

(i)
(ii)

1. Correct reactants and products


1. Propene change purple colour of Potassium manganate
(VII) to colourless while propane purple colour remain
unchanged
2. propene can undergoes addition reaction because it is
unsaturated hydrocarbon // consist double bond between
carbon atoms
3. propane cannot undergoes addition reaction because it is
saturated hydrocarbon // consist single bond between
carbon atoms
ester
1. pour [5-10 cm3] ethanol into a boiling tube of [5-10
cm3] pentanoic acid
2. put a few drops of concentrated sulphuric acid into the
boiling tube and heat gently
TOTAL

1
1

1
2

1
11

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Question
7

(a)

Marking Criteria
(i)

Sub
Mark

1. correct name of the process


2. correct formula of reactants and product of step X
3. balance chemical equation of step X
4. correct formula of reactants and product of step X
5. balance chemical equation of step X

Total
Mark

Answer :
Contact Process

(b)

(c)

(d)

Step X : 2SO2 + O2 2SO3

1+1

Step Y : SO3 + H2SO4 H2S2O7

1+1

1. Dissolve in rain water to produce acid rain


2. Increase the acidity of water in the river // disturbs the
ecosystem // aquatic organisms may die
NH4SO4

1
1

(ii) 1. Urea
2. % of N in urea = 28 / 60 x 100 = 46.67%
3. % of N in fertilizers X = 28 / 132 x 100 = 21.21%
4. Percentage of N atoms by mass in urea is higher than
ammonium sulphate

1
1
1
1

(i)

P : Fibre glass
Q : Bronze
R : Duralumin
S : Ceramics
T : Lead crystal glass

1
1
1
1
1

Properties:
Durable / light /inert to chemical / insulator
(any 2 answers)

1+1

Uses : Plastic plate / toys / shopping bag


(any 1 answer)

1
4

1
TOTAL

20

Question
8

(a)

Marking Criteria
(i) - correct label of axis and unit
-correct plot
-correct curve

Sub
Mark
1
1
1

Total
Mark

(ii) - volume lead(II) nitrate 2.5 cm3


-no of mol of Pb2+
2.5 x 1 // 0.0025 mol
1000
- no of mol of I5 x 1 // 0.005 mol
1000
- correct ratio
0.0025 mol Pb2+ react with 0.005 mol I-

1
1

-correct number of mol of iodide ions react with 1 mol


lead(II) ions
1 mol Pb2+ react with 2 mol I-

-correct formula of reactants and products


-correct balance

1
1

Pb2+ + 2 I- PbI2
(b)

(i) Oxide T : CuO // copper(II) oxide

Salt W : CuSO4 // copper(II) sulphate

Salt X : Cu(NO3)2 // copper(II) nitrate

Solid Y : BaSO4 // barium sulphate

-White precipitate formed


-double decomposition reaction

1
1

(ii)
2

Question

Marking Criteria

Sub
Mark

(iii) -correct chemical equation


CuSO4 + Ba(NO3)2 Cu(NO3)2 + BaSO4

Total
Mark

-No of mol of barium nitrate


50 x 1 // 0.05
1000

- ratio
1 mol Ba(NO3)2 : 1 mol BaSO4
0.05 mol Ba(NO3)2 : 0.05 mol BaSO4

- correct mass & unit of BaSO4


0.05 x 233 g // 11.65 g

TOTAL

20

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Question
9

(a)

Marking Criteria
(i) Acid X : hydrochloric acid
Acid Y : sulphuric acid
Gas Z : hydrogen gas

Sub
Mark
1
1
1

Total
Mark

Reject : formula
-correct method and reagent to identify gas Z
-correct observation

1
1

Answer :
Put a burning wooden splinter to the mouth of test tube
pop sound produce

(ii) -No of mol of acid Y


50 x 0.5 // 0.025
1000
- ratio
1 mol H2SO4 : 1 mol H2
0.025 mol H2SO4 : 0.025 mol H2
- correct volume of gas Z
0.025 x 24 dm3 // 0.6 dm3

1
3
1

Question
(iii)

Marking Criteria

Sub
Mark

Total
Mark

Volume of gas / cm3


III
II
I
time / s
-

Both axis labeled & unit


Correct curve I & labeled
Correct curve II & labeled
Correct curve III & labeled

(iv) 1. Rate of reaction in Experiment III is higher than in


Experiment II
2. In Experiment III presence of copper(II) sulphate as a
catalyst.
3. Activation energy in experiment III is lower than experiment
II.
4. more colliding particles can overcome the activation energy
in exp. III.
5. The frequency of effective collisions in exp III is higher.
(b)

-Temperature
-at warm place, kinetic energy of particles increases/higher
-Rate of rising of the dough increases/higher
TOTAL

1
1
1
1

1
1
1

1
1
1
1
1

3
20

Question
10

(a)

Marking Criteria

Sub
Mark

Type of chemical reaction


1. Diagram 10.1 : exothermic reaction.
2. Diagram 10.2 : endothermic reaction.
Energy content of reactants and products :
3. Diagram 10.1 : The energy content in the reactants is
higher than the energy content in the products
4. Diagram 10.2 : the energy content in the reactants
less than the energy content in the products .

Total
Mark

1
1

1
1

5-label energy and correct level diagram 10.1


6-correct equation & H Energy level diagram 10.1
Energy
TenagaC6H12O6 + 6O2

-1

H = -x kJmol

1+1

6H2O + 6CO2

7-label energy and correct level diagram 10.2


8-correct equation & H Energy level diagram 10.2
Energy
Tenaga

C6H12O6 + 6O2

1+1

-1

H = +y kJmol
6H2O + 6CO2 + sunlight

8
(b)

1. Number of moles of CuSO4 = (0.1)(50) //


0.005 mol
1000
2. Heat change, mc = 210 x 0.005 J // 1.05 kJ // 1050 J
3. Metal X : Zn // Mg

1
1
1

4. = 1050
. oC // 5.0oC
(50)(4.2)

Question
(c)

Marking Criteria

Sub
Mark

Total
Mark

Material and apparatus


1. Lead(II) nitrate solution // barium nitrate solution //
Calcium nitrate solution
2. copper(II) sulphate solution // magnesium sulphate // zinc
sulphate (any suitable soluble sulphate of +2 cation)

1
1

Procedure:
1. Measure 50 cm3 of copper (II) sulphate solution 0.5 mol
dm-3 using measuring cylinder and pour into polystyrene
cup
2. Measure initial temperature of the solution.
3. Measure 50 cm3 of lead(II) nitrate solution 0.5 mol dm-3
using measuring cylinder and pour into another
polystydsrene cup
4. Measure initial temperature of the solution.
5. Mix the solution, stir by using thermometer and measure
the maximum temperature of the mixture.

1
1
1

1
1

Table:
Initial temperature of
Lead(II) nitrate /oC
Initial temperature
Copper(II) sulphate /oC
Average Initial temperature
of the mixture /oC
Maximum Temperature/oC
Temperature change /oC

1
2
1

3
4
4 - 3

8
TOTAL

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20

MARKING SCHEME PAPER 3 CHEMISTRY TRIAL SPM PAHANG 2015


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Question
1(a)

Explanation/Rubric
Able to record all reading accurately to one decimal point and with unit.
Sample answer:
Initial temperature
: 60.0oC
Temperature at 30s
: 68.0 oC
Temperature at 60s
: 78.0 oC
Temperature at 90s
: 80.0 oC
Temperature at 120s : 80.0 oC
Temperature at 150s : 80.0 oC
Temperature at 180s : 82.0 oC
Temperature at 210s : 85.0 oC
Temperature at 240.0s : 95.0oC
Able to record all readings correctly without decimal point
// Able to record 6-8 readings correctly

Able to record 3-5 readings correctly

No response or wrong response

Question
1(b)(i)

Maximum
score

Explanation/Rubric

Maximum
score

Able to plot a graph that contains the following information.


-

Axes labeled with units


All the 8 points transferred correctly
A smooth curve is drawn

Sample answer:

Temperature/oC

Time/second

Question

Explanation/Rubric

Maximum
score

Able to plot the graph that contains the following information.


- Axes labeled without units
// 6-7 points transferred correctly
// a graph is not smooth

Sample answer:
Temperature

Time
Able to give an idea to plot a graph

No response or wrong response or empty table

Question

1(b)(ii)

Explanation/Rubric
Able to state the melting point correctly with 1 decimal place and unit
and show on the graph
Sample answer :
Temperature/oC

Melting point
80.0 oC

Time/ second

Maximum
score

Question

Explanation/Rubric
Able to state the melting point correctly with or without decimal place
but with correct unit only without showing on the graph
// Able to state the melting point on the curve

Maximum
score

Sample answer;
-

Melting point of naphthalene : 80.0 oC // 80 oC //


Temperature/oC
Melting point

Time/ second

1
Able to state the melting point less accurately without unit and without 1
decimal place // Able to show the melting point incorrectly;
Sample answer:
- Melting point of naphthalene : 80 //
Temperature/oC

melting point

Time/ second
No response or wrong response

Question
1(c)

Explanation/Rubric
Able to explain correctly according to 3 information :
-

Question
1(d)

Maximum
score
3

Heat energy absorbed


is used to overcome the forces of attraction between the
molecules/particles
So that the solid naphthalene can turn into liquid

Sample answer :
Heat energy absorbed is used to overcome the forces of attraction
between the molecules so that solid naphthalene can turn into liquid.
Able to explain less accurately

Sample answer :
The heat energy is used to overcome the forces of attraction between
molecules / particles
Able to state an idea

Sample answer :
The heat energy is used / absorbed
No response or wrong response

Explanation/Rubric
Able to classify all the compound correctly
Ionic compound
covalent compound
Potassium bromide
Glucose
Zinc nitrate
methanol
Sodium chloride
ethyl ethanoate
Able to classify any 5 compound correctly.
Able to classify at least 2 compound correctly
No response or wrong response/

Maximum
score

2
1
0

Question
2 (a)

Explanation/Rubric

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Maximum
score

Able to state any 3 observations and their related inferences correctly.


Sample answer:
6
Test
tube
2

Observations
Pemerhatian
Low intensity of pink
colour/ solutions

//
No blue spot

Inferences
Inferen
Iron(II) / Fe2+ ions are not formed
/produced in the solutions //
Zinc/Zn corroded / oxidized slowly //
less OH- ions formed //
Iron / Fe does not rust/
corrode/oxidised

Low intensity of blue


colour /solutions
//

Less Iron(II) / Fe2+ ions formed /


produced in the solutions //
Iron / Fe rusted/ corroded/ oxidized
slowly //

Low intensity of pink


colour/ solutions

less OH- ions formed //

High intensity of pink


colour/ solutions

Iron(II) / Fe2+ ions are not formed


/produced in the solutions //
Magnesium/Mg corroded /oxidized
faster // more OH- ions formed

//
No blue spot

Iron / Fe does not rust/


corrode/oxidised //

Able to state at least 5 observations and their related inferences


correctly // less correctly

Able to state at least 4 observation af inferens


Able to state at least 3 observation af inferens
Able to state at least 2 observation af inferens
Able to state at least 1 observation af inferens
No response or wrong response

4
3
2
1
0

correctly//
correctly
correctly
correctly

Question
2 (b)

Explanation/Rubric
Able to state the relationship between the manipulated variable and the
responding variable and state the direction correctly.

Maximum
score
3

Sample answer
When a less electropositive metal than iron is in contact with iron
nail/ferum/Fe, the metal speeds up rusting/corrosion of iron but when a
more electropositive metal is in contact with iron/ferum/Fe, the metal
inhibits rusting/corrosion of iron //
When the metal in contact with iron is lower than iron/ferum/Fe in
electrochemical series, the rusting/corrosion of iron is faster but when
the metal in contact with iron is higher than iron/ferum/Fe in
electrochemical series, the iron does not rust/ rusting/corrosion of iron
slower//
The further the distance between less electropositive metals and
iron/Fe in electrochemical series that in contact with iron, the higher is
the intensity/more of blue spots formed but the further the distance
between more electropositive metals and iron/Fe in electrochemical
series that in contact with iron, the higher is the intensity/more of pinc
colour formed.
Able to state the relationship between the manipulated variable and the
responding variable without stating the direction/ less accurately

Sample answer
When different metal in contact with iron, the more blue spot/rust
formed
Able to give an idea of hypothesis

Sample answer
Pair of metal will produce rust
No response or wrong response

Question
2 (c)

Explanation/Rubric
Able to state all the variables in this experiment correctly.
Sample answer
(i) Manipulated variables : Type/different metal // position of metal in
electrochemical series
(ii) Responding variable : Rusting / corrosion // presence of blue/pink
colour
(iii) Constant variable : Size/mass of iron nail // type of nail // clean iron
nails // temperature // medium in which the iron
nail are kept
Able to state any two variables correctly

Able to state any one variable correctly

No response or wrong response

Question
2 (d)

Maximum
score
3

Explanation/Rubric
Able to give one operational definition of the experiment correctly with
the following aspects:
i.what you do
ii.what you observe
Sample answer
Blue spot form when less electropositive metal is in contact with iron
nail and dipped/put into jelly solutions that contain potassium
hexacyanoferrate (III) and phenolphthalein//
Rusting occurs when iron nail is in contact with tin/less electropositive
metal and form blue colouration in potassium hexacyanoferrate(III)
solution and phenolphthalein
//
No blue spot form when more electropositive metal is in contact with
iron nail and dipped/put into jelly solutions that contain potassium
hexacyanoferrate (III) and phenolphthalein //
Rusting does not occurs when iron nail is in contact with Mg/Zn/more
electropositive metal and form blue colouration in potassium
hexacyanoferrate(III) solution and phenolphthalein
// (based on test tube 1)
Blue spot form when iron nail dipped into jelly solutions that contain
potassium hexacyanoferrate (III) and phenolphthalein

Maximum
score
3

Question

Explanation/Rubric
Able to give the operational definition for rusting incompletely with any
one of the following aspects:
i.what you do
ii.what you observe

Maximum
score
2

Sample answer
Metal is put into jelly blue spot form
Able to give an idea of operational definition for rusting

Sample answer
Iron corrodes/rust/oxidised
No response or wrong response

Question
2 (e)

Explanation/Rubric
Able to predict the metal Q correctly

Maximum
score
3

Sample answer
Copper/Cu // Silver/Ag
Able to predict the metal Q less correctly

Sample answer
Gold/Au
Able to give an idea of predicting the metal

Sample answer
Mercury/Hg
No response or wrong response

Question

Explanation/Rubric
https://cikguadura.wordpress.com/

3 (a)

Able to state the problem statement with the named strong acid
solution and weak acid solution accurately
Sample answer :
Does the heat of neutralisation between hydrochloric acid and sodium
hydroxide solution is higher than the heat of neutralisation between
ethanoic acid and sodium hydroxide solution?
Able to state the problem statement less accurately
Sample answer :
Does the heat of neutralization between strong acid and weak acid
with strong alkali different ? //To study the heat of neutralization
between strong and weak acid with strong alkali.
Able to state an idea about problem statement
Sample answer :
Heat of neutralisation is affected by the strength of acid.
No response or wrong response

Question
3 (b)

Explanation/Rubric
Able to state the relationship between the manipulated variable and the
responding variable and state the direction correctly.

Maximum
score
3

Maximum
score
3

Sample answer :
The reaction between hydrochloric acid/strong acid and sodium
hydroxide will give the higher value of heat of neutralization than the
reaction between ethanoic acid/weak acid with sodium hydroxide.
Able to state the relationship between the manipulated variable and the
responding variable without stating the direction/ less accurately

Sample answer
Different strength of acid react with sodium hydroxide, different value of
heat of neutralisation
Able to give an idea of hypothesis

Sample answer
The strength of acid affect the heat of neutralisation
No response or wrong response

Question
3 (c)

Question
3 (d)

Explanation/Rubric
Able to state all the variables accurately
Sample answer :
Manipulated variable: Hydrochloric Acid and Ethanoic Acid (any
suitable named strong and weak acid)
// Strong acid and weak acid
Responding variable : Heat of neutralisation
Fixed variable
: Concentration and volume of NaOH
solution//NaOH solution//polystyrene cup //
Concentration and volume of acid solution

Maximum
score
3

Able to give any two variables accurately

Able to give any one variable accurately


No response or wrong response

Explanation/Rubric
Able to list down the materials and apparatus completely
Sample answer :
Materials : [0.5-2.0 mol dm-3 ] sodium hydroxide solution,
[0.5-2.0 mol dm-3 ] hydrochloric acid, [0.5-2.0 mol dm-3 ]
ethanoic acid (any suitable strong and weak named acid),
Apparatus :Polystyrene/plastic cup, thermometer, [50-100cm3]
measuring cylinder
Able to give the list of the apparatus and materials correctly but not
complete
Sample answer :
sodium hydroxide solution, hydrochloric acid / ethanoic acid,
Polystyrene/plastic cup, thermometer,
Able to give an idea on the list of the apparatus and substances
correctly
Any one materials and one apparatus with thermometer
No response or wrong response
reject : no thermometer

Maximum
score
3

Question
3 (e)

Explanation/Rubric
Able to state all the steps of the experiment accurately
Example
1. [25-100 cm3 ] of sodium hydroxide solution is poured into a
polystyrene cup using a measuring cylinder.
2. The initial temperature of sodium hydroxide solution is recorded.
3. [25-100 cm3 ] of hydrochloric acid is measured into another
polystyrene cup.
4. The initial temperature of hydrochloric acid is recorded.
5. Hydrochloric acid is then poured quickly into a cup containing
sodium hydroxide solution.
6. The mixture is stirred using thermometer and the highest
temperature is recorded.
7. Repeat steps 1 to 6 using ethanoic acid instead of hydrochloric
acid.

Maximum
score
3

Able to state 5 steps of the experiment


Steps 2, 4, 5, 6, 7

Able to state 2 minimum steps correctly


Steps 5, 6
No response or wrong response

1
0

Question
3 (f)

Explanation/Rubric
Able to construt the table that contains the following information
1. Columns and rows
2. Headings in the table
3. With unit
Sample answer:
Initial temperature/ oC

Highest temperature
of the mixture/o C

Pair of acid/alkali
Acid

Alkali

Maximum
score
2

Average

NaOH/HCl
NaOH/CH3COOH
Able to construt the table that contains the following information
1. Columns and rows
2. Headings in the table
3. Without unit

// Able to state an idea about the tabulation of data


Tabulation of data has the following elements :
1. minimum 2 columns and 2 rows
Sample answer :
Initial temperature
Pair of acid/alkali
Acid

Highest
temperature of
the mixture

Alkali

//
Sample answer :

No response or wrong response


END OF MARKING SCHEME

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