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Trial Pahang 2015 With Ans PDF
Trial Pahang 2015 With Ans PDF
KELAS :...................................................................................................
PEPERIKSAAN PERCUBAAN
SIJIL PELAJARAN MALAYSIA 2015
https://cikguadura.wordpress.com/
4541/1
CHEMISTRY
Kertas 1
September
1 jam
1 jam 15 minit
4.
5.
Lihat sebelah
1.
2.
3.
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79
35
Br and 3581 Br ?
79
81
3
A
B
C
D
4.
Table 1 shows the melting point and boiling point of substances P,Q, R and S.
Jadual 1 menunjukkan takat lebur dan takat didih untuk bahan P, Q, R, dan S.
Substance
Bahan
P
Q
R
S
Melting point C
Boiling point C
Takat lebur C
Takat didih C
- 157
-9
- 13
55
80
196
256
300
Table 1
Jadual 1
Which substance is a liquid at room temperature?
Bahan manakah wujud sebagai cecair pada suhu bilik?
A
B
C
D
5.
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P
Q
R
S
1 mol of oxygen gas, O2 and 1 mol of carbon dioxide gas, CO2 have
1 mol gas oksigen, O2 dan 1 mol gas karbon dioksida, CO2 mempunyai
A
B
C
D
same mass
jisim yang sama
same number of atoms
bilangan atom yang sama
same number of molecules
bilangan molekul yang sama
same number of electrons
bilangan elektron yang sama
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4
6.
The formula for a nitrate ion is NO3- and for a sulphate is SO42-. If the formula of the
nitrate salts of M is MNO 3 2, what is the formula of the sulphate salt of M?
Formula untuk ion nitrat ialah NO3- manakala ion sulfat ialah SO42-. Sekiranya formula
garam nirat M ialah MNO 3 2, apakah formula untuk garam sulfat M?
A
B
C
D
7.
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MSO4
M2SO4
M SO4 2
M SO3 3
Diagram 1 shows three balloons with hydrogen, nitrogen and oxygen gas
respectively.
Rajah 1 menunjukkan tiga biji belon mengandungi gas hidrogen, nitrogen, dan
oksigen setiap satu.
2.5 g of
hydrogen
gas
2.5 g gas
hidrogen
7.0 g of
nitrogen
gas
7.0 g gas
nitrogen
2.5 g of
oxygen
gas
2.5 g gas
oksigen
Diagram 1
Rajah 1
Arrange the gases in descending order of volume.
[Relative atomic mass: H=1, N=14, O=16 and 1 mol of gas occupies 24 dm 3 at room
temperature and pressure]
Susun gas-gas tersebut mengikut susunan menurun isipadu.
[Jisim atom relatif: H=1, N=14, O=16; Isipadu molar gas = 24 dm3mol-1 pada keadaan
bilik)
A
B
C
D
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8.
Diagram 2
Rajah 2
Diagram 2 shows melamine plates. Melamine plates usually used at home because
of the good appearance, hardy and unbreakable. Melamine plates consist of mixture
including melamine with molecular formula C3H6N6. Find the relative molecular mass
of melamine.
[Relative atomic mass: H=1, N=14, C=12]
Rajah 2 menunjukkan pinggan melamin. Pinggan melamin biasanya digunakan di
rumah kerana selain rupanya yang cantik, ia juga tahan lasak dan tidak mudah
pecah. Pinggan melamin terdiri daripada bahan campuran termasuk melamin yang
mempunyai formula molekul C3H6N6. Hitungkan jisim molekul relatif melamin. [Jisim
atom relatif: H=1, N=14, C=12]
A
B
C
D
9.
121
126
130
132
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6
10.
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Boiling point C
Takat didih C
-188
-35
59
Table 2
Jadual 2
Which of the following best explain why the boiling point increases down the
group?
Antara berikut, yang manakah menjelaskan dengan tepat mengapa takat didih
meningkat apabila menuruni kumpulan?
A
B
C
D
11.
share electrons
berkongsi elektron
accept electrons
menerima elektron
donate electrons
menderma elektron
transfer electrons
memindahkan elektron
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12.
Among the following compounds, which one contains particles bonded by strong
electrostatic forces?
Antara sebatian-sebatian berikut, yang manakah mengandungi zarah yang terikat
dengan daya elektrostatik yang kuat?
A
B
C
D
13.
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Ammonia
Ammonia
Naphthalene
Naftalena
Potassium oxide
Kalium oksida
Carbon dioxide
Karbon dioksida
The number of valence electrons of atoms X and Y are 2 and 7 respectively. Which
of the following chemical formulae and types of bonding are true for the compound
formed between X and Y?
Bilangan elektron valens atom X dan Y ialah 2 dan 7 untuk setiap satu. Yang
manakah antara berikut menunjukkan formula kimia dan jenis ikatan yang terbentuk
antara X dan Y?
Chemical Formula
Sifat kimia
A
B
C
D
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XY2
XY2
X2Y
X2Y
Type of Bonding
Jenis Ikatan
Ionic
Ion
Covalent
Kovalen
Ionic
Ion
Covalent
Kovalen
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14.
Diagram 3
Rajah 3
Diagram 3 shows a picture of cooking gas cylinder which is always used at home.
Butane in cooking gas burns to release gas X. Both butane and gas X are
Rajah 3 menunjukkan gambar silinder gas memasak yang sering digunakan di
rumah. Butana dalam gas memasak terbakar membebaskan gas X. Kedua-dua
butana dan gas X adalah
A
B
C
D
15.
ionic compounds
sebatian ion
organic compounds
sebatian organik
covalent compounds
sebatian kovalen
hydrocarbon compounds
sebatian hidrokarbon
Sugar solution
Larutan gula
Molten naphthalene
Leburan naftalena
Solid sodium chloride
Pepejal natrium klorida
Molten lead II bromide
Leburan plumbum II bromida
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9
16.
17.
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Diagram 4 shows a chemical cell using magnesium and copper as the electrodes.
Rajah 4 menunjukkan satu sel kimia menggunakan magnesium dan kuprum sebagai
elektrod
Magnesium
Magnesium
Copper
Kuprum
Diagram 4
Rajah 4
Which of the following half equations represents the reaction at the copper
electrode?
Antara berikut, yang manakah merupakan persamaan setengah yang menunjukkan
tindak balas pada elektrod kuprum?
A
B
C
D
Cu2+ + 2e Cu
2 H+ + 2e H2
Cu Cu2+ + 2e
2 Cl- Cl2 + 2e
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18.
Diagram 5
Rajah 5
A student has an iron ring as shown in Diagram 5. He wants to make the ring more
beautiful and durable to give to his friend as a present. What is the best way to do it?
Seorang pelajar mempunyai sebentuk cincin besi seperti yang ditunjukkan dalam
Rajah 5. Pelajar tersebut ingin menjadikan cincin tersebut lebih cantik dan tahan
lama untuk dihadiahkan kepada rakannya. Bagaimanakah cara terbaik untuk
mencantikkan cincin tersebut?
A
B
C
D
19.
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11
20.
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Potential difference V
Beza keupayaan V
0.3
0.8
1.9
Table 3
Jadual 3
Positive terminal
Terminal positif
R
T
S
22.
Acid rain causes the land to become acidic. Farmers neutralize acidity in the soil
by adding
Hujan asid menyebabkan tanah menjadi berasid. Petani boleh meneutralkan
keasidan tanah dengan menambah
A
B
C
D
Sulphur
Sulfur
Zinc nitrate
Zink nitrat
Soda lime
Kapur tohor
Ammonium sulphate
Ammonium sulfat
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12
23.
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HCl
0.1 mole dm
CH3COOH
-3
0.1 mole dm
-3
Rajah 6
Diagram 6
Which of the following statements is true?
Yang manakah antara pernyataan berikut adalah benar?
A
B
C
D
24.
Silver nitrate
Argentum nitrat
Ammonium klorida
Ammonium chloride
Zinc sulphate
Zink sulfat
Magnesium carbonate
Magnesium karbonat
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13
25.
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Zinc
Zink
Lead
Plumbum
Copper
Kuprum
Aluminium
Aluminium
26.
Diagram 7
Rajah 7
Diagram 7 shows a bottle of salt which has been used for cooking at home. This salt
can react with silver nitrate salt to produce an insoluble salt. Name the insoluble salt.
Rajah 7 menunjukkan sebotol garam yang digunakan untuk memasak di rumah.
Garam ini boleh bertindak balas dengan garam argentum nitrat menghasilkan sejenis
garam tak larut. Namakan garam tak larut yang terhasil
A
B
C
D
Sodium nitrate
Natrium nitrat
Sodium chloride
Natrium klorida
Silver chloride
Argentum klorida
Siver sulphate
Argentum sulfat
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14
27.
Which of the following equation represents the most suitable reaction to prepare an
insoluble salt?
Manakah antara persamaan kimia berikut menunjukkan tindak balas yang paling
sesuai untuk menyediakan garam tak terlarutkan.
A
B
C
D
28.
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PbNO 3 2
Ba NO 3 2
Pb
PbOH 2
+
+
+
+
2KCl
2KCl
H2SO4
2HCl
PbCl2 +
BaCl2 +
PbSO4 +
PbCl2 +
2KNO3
2KNO3
H2
2H2O
Table 4 shows the result of a series of tests carried out on a solution of salt J.
Jadual 4 menunjukkan keputusan beberapa siri ujian yang dijalankan terhadap satu
larutan garam J.
Test
Observation
Ujian
Pemerhatian
Add dilute sulphuric acid
No changes
Tambahkan asid sulfurik cair
Tiada perubahan
Add leadII nitrate solution , then
White precipitate dissolves when
heat it
heated.
Tambahkan plumbum II nitrat,
Mendakan putih larut apabila
kemudian panaskan
dipanaskan
Add sodium hydroxide solution until White precipitate is formed.
in excess
It is insoluble in excess sodium
Tambahkan larutan natrium
hydroxide solution
hidroksida sehingga berlebihan
Mendakan putih terbentuk.
Mendakan tidak larut dalam natrium
hidroksida berlebihan
Add ammonia solution until in
White precipitate is formed.
excess
It is insoluble in excess ammonia
Tambahkan larutan ammonia
solution
berlebihan
Mendakan putih terbentuk
Mendakan tidak larut dalam larutan
ammonia berlebihan
Table 4 / Jadual 4
Based on the results of the experiment, what is salt J?
Berdasarkan keputusan eksperimen, apakah garam J?
A
Magnesium chloride
Magnesium klorida
B
Zinc sulphate
Zink sulfat
C
Zinc chloride
Zink klorida
D
Magnesium sulphate
Magnesium sulfat
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29.
Diagram 8
Rajah 8
Diagram 8 shows ceramic vase which are made from clay. Name the main
component of clay.
Rajah 8 menunjukkan pasu seramik yang diperbuat daripada tanah liat. Namakan
komponen utama tanah liat.
A
B
C
D
30.
Kaolin
Kaolin
Perspex
Perspeks
Silicon dioxide
Silikon dioksida
Aluminium oxide
Aluminium oksida
Photosynthesis
Fotosintesis
Rusting of iron
Pengaratan besi
Fermentation
Penapaian
Precipitation reaction
Tindak balas pemendakan
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31.
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The chemical equation shows a reaction between sodium thiosulphate solution with
hydrochloric acid solution.
Persamaan kimia di bawah menunjukkan tindak balas antara larutan natrium tiosulfat
dan larutan asid hidroklorik
Na2S2O3 + 2HCl
2NaCl +
SO2 + S + H2O
Which of the following changes cannot be used to determine the rate of reaction?
Antara berikut, perubahan manakah yang tidak boleh digunakan untuk
menentukan kadar tindak balas?
A
B
C
D
32.
Table 5 shows the total volume of gas collected at regular intervals in a reaction.
Jadual 5 menunjukkan jumlah isipadu gas yang dikumpul pada sela masa yang
sekata bagi satu tindak balas.
Time / min
0.0
0.5
0.00
8.00
1.0
2.0
2.5
3.0
3.5
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1.5
17
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33.
Diagram 9
Rajah 9
A slice of meat which has been cut into smaller pieces takes a shorter time to
cook if compared to a slice of meat which did not cut to smaller pieces
Sekeping daging yang dipotong kepada kepingan-kepingan kecil akan
mengambil masa yang lebih cepat untuk dimasak berbanding sekeping daging
yang tidak dipotong.
Based on the above statement, choose the
. best explanation.
Berdasarkan pernyataan di atas, pilih penjelasan yang paling sesuai.
A
B
The smaller the size of reactant, the higher the kinetic energy of the particles
Lebih kecil saiz bahan tindak balas, lebih tinggi tenaga kinetik zarah-zarah.
The smaller the size of reactant, more particles in reactant will exist
Lebih kecil saiz bahan tindak balas, semakin banyak jumlah zarah yang
wujud.
The smaller the size of reactant, the lower activation energy needs for a
reaction to occur.
Lebih kecil saiz bahan tindak balas, lebih rendah tenaga pengaktifan yang
diperlukan untuk tindak balas.
The smaller the size of reactant, the bigger the total surface area.
Lebih kecil saiz bahan tindak balas, lebih besar luas jumlah permukaan
bahan tindak balas tersebut
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Situation A
Situasi A
Situation B
Situasi B
Diagram 10
Rajah 10
34.
Diagram 10 shows Puan Siti dry the cloth at two different places, which are situation
A: outside home, while situation B: inside home. Which situation can dry the cloth
faster and why?
Rajah 10 menunjukkan Puan Siti menjemur pakaian pada dua tempat yang berbeza,
iaitu situasi A: di luar rumah, manakala situasi B: di dalam rumah. Situasi manakah
yang dapat mengeringkan baju dengan lebih cepat dan mengapa?
Situation
Reason
Situasi
Sebab
A
A
There are more air particles outside home
compared to inside the home.
Lebih banyak zarah udara terdapat di luar rumah
berbanding di dalam rumah.
B
A
Temperature outside home is higher than inside
home.
Suhu di luar rumah lebih tinggi berbanding di dalam
rumah
C
B
The smaller space inside home can provide more
heat compared to outside home.
Ruang yang sempit di dalam rumah boleh
menghasilkan lebih banyak haba berbanding di luar
rumah.
D
B
There are air movement inside the home compared
to outside the home.
Terdapat pergerakan udara di dalam rumah
berbanding di luar rumah.
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19
35.
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Table 6 shows the experiments carried out to study the rate of reaction between zinc
carbonate and nitric acid.
Jadual 6 menunjukkan eksperimen yang dijalankan untuk mengkaji kadar tindak
balas antara zink karbonat dan asid nitrik
Experiment
Eksperimen
I
II
0.2
Table 6
Jadual 6
Which of the following graph represents the two experiments?
Antara berikut, graf manakah menunjukkan graf untuk kedua-dua eksperimen?
A
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36.
Which of the following is correct about the conversion of unsaturated fats to saturated
fats?
Antara berikut, yang manakah betul tentang penukaran lemak tak tepu kepada lemak
tepu?
A
Intermolecular forces of attraction become weaker
Daya tarikan antara molekul menjadi lemah
B
The boiling point of the fats increases
Takat didih lemak meningkat
C
Physical state changes from solid to liquid
Keadaan fizikal berubah daripada pepejal ke cecair
D
Relative molecular mass of the oil molecule decreases
Jisim relatif molekul minyak berkurang
37.
H H H Br
| | |
|
HCCCCH
|
|
| |
H H H H
4541/1 PAHANG
21
38.
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When propane is burned in excess oxygen, carbon dioxide and water are formed and
is represented by the equation
Apabila propana terbakar dalam oksigen berlebihan, karbon dioksida dan air
dihasilkan dan persamaan yang terhasil adalah
a C3H8 +
b O2
c CO2 +
d H2O
A
B
C
D
39.
b
5
5
5
5
c
1
1
3
3
d
3
5
8
4
Fuel is needed for machine to operate and vehicles to move. Both butane and butene
can be used as fuel because the reaction of combustion in air is an exothermic. What
are the others similar characteristics that butane and butene have?
Bahan api diperlukan untuk sesebuah mesin beroperasi dan kenderaan untuk
bergerak. Kedua-dua butana dan butena boleh digunakan sebagai bahan api kerana
tindak balas pembakaran keduanya adalah eksotermik, Apakah ciri-ciri sepunya lain
yang dipunyai oleh butana dan butena?
I
Exist as gas at room temperature.
Wujud sebagai gas pada suhu bilik
II
Decolourise the purple colour of acidified potassium manganateVII.
Menyahwarna ungu kalium manganat VII berasid
III
Cannot dissolve in water.
Tidak larut dalam air
IV
Terbakar di udara berlebihan menghasilkan gas yang mengeruhkan air kapur
Burn in excess air to produce a gas that turns limewater cloudy.
A
B
C
D
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40.
The lorry tyres are made from vulcanized rubber. What property of vulcanized rubber
makes it suitable to be used for making these lorry tyres?
Tayar lori diperbuat daripada getah tervulkan. Apakah ciri getah tervulkan yang
paling sesuai menyebabkan ia digunakan sebagai tayar lori?
A
Resist to heat
Tahan haba
B
Harder and stronger
Keras dan kuat
C
Resist to oxidation
Tahan pengoksidaan
D
Can maintain their elasticity
Boleh mengekalkan sifat elastik
41.
42.
43.
CuO
Mg
Cl2
Ag+
+
+
+
+
Zn
2 AgNO3
S2Cl-
ZnO +
MgNO 3 2 +
2Cl+
AgCl
Cu
2 Ag
S
+2
+3
+4
+6
4541/1 PAHANG
23
44.
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The manufacture of sulphuric acid in the Contact Process involves the following
steps.
Pembuatan asid sulfurik dalam Proses Sentuh melibatkan langkah berikut.
S
SO2
SO3
H2SO4
Based on the equation above, which of the following is the correct oxidation number
of sulphur?
Berdasarkan persamaan di atas, yang manakah antara berikut merupakan nombor
pengoksidaan yang betul untuk sulfur?
S
SO2
SO3
H2SO4
A
0
+2
+3
+4
B
0
+2
+6
+6
C
0
+4
+6
+6
D
0
+4
+6
+8
45.
HCl
NaCl
+ H2O + CO2
H = +11.8 kJmol-1
A
B
C
D
4541/1 PAHANG
Heat change
Perubahan haba
Heat absorbed
Haba diserap
Hear absorbed
Haba diserap
Heat released
Haba dibebas
Heat released
Haba dibebas
Type of reaction
Jenis tindak balas
Exothermic
Eksotermik
Endothermic
Endotermik
Endothermic
Endothermic
Exothermic
Eksotermik
24
46.
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HCl
KCl
H2O
H = -57 kJ mol-1
Which neutralization reaction has the same value of the heat of neutralisation?
Manakah tindak balas peneutralan yang mempunyai nilai haba peneutralan yang
sama?
A
B
C
D
47.
HCl
+
CH3COOH
NaOH +
CH3COOH
NH3
+
HNO3
+
NH4Cl
KOH
CH3COOK
+
H2O
NaNO3
+
H2O
NH4OH
CH3COONH4 +
H2O
In an experiment, excess zinc powder is added to 50 cm3 0.1 mol dm-3 copper II
sulphate solution. The thermochemical equation is as shown:
Dalam satu eksperimen, serbuk zink ditambah secara berlebihan kepada 50 cm3
0.1 mol dm-3 larutan kuprum II sulfat. Persamaan termokimia untuk tindak balas itu
adalah seperti berikut:
Mg
Zn2+
Zn
Mg2+
H = -210 kJ mol-1
50
x
50
0.1
x
x
4.2
210000
50
50
x
x
4.2
0.1
x
x
210000
1000
50
x
50
4.2
x
x
0.1
210.00
50
x
50
0.1
x
x
4.2
210.00
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48.
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Diagram 11 shows the energy level diagram for the reaction between silver ions and
chloride ions.
Rajah 11 menunjukkan rajah aras tenaga untuk tindak balas antara ion argentum
dan ion klorida.
Energy
Ag+aq + Cl
aq
H = - 65.5 kJmol-1
AgCls)
Diagram 11
Rajah 11
49.
Hilmi has the following symptoms: fever, headache, muscle and joint pains. The
medicine that can be taken to relieve the symptoms is
Hilmi mempunyai gejala-gejala seperti berikut: demam, pening kepala, sakit otot, dan
sakit sendi. Ubat yang boleh diambil untuk menangani gejala-gejala itu adalah
A
B
C
D
Codeine
Kodeina
Penicilin
Penisilin
Paracetamol
Parasetamol
Amphetamine
Amfetamin
4541/1 PAHANG
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50.
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4541/1 PAHANG
SULIT
NAMA :....................................................................................................
KELAS :...................................................................................................
PEPERIKSAAN PERCUBAAN
SIJIL PELAJARAN MALAYSIA 2015
4541/2
https://cikguadura.wordpress.com/
CHEMISTRY
Kertas 2
September
2 jam
2 jam 30 minit
2.
3.
4.
5.
Soalan
Markah
Penuh
10
10
11
11
20
20
20
10
20
Markah
diperoleh
C
JUMLAH
------------------------------------------------------------------------------------------------------------------------------Kertas soalan ini mengandungi 33 halaman bercetak
4541/2
Section A
Bahagian A
[60 marks]
[60 markah]
Answer all the questions in this section.
Jawab semua soalan dalam bahagian ini.
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1.
Diagram 1.1 shows the observation of an experiment when solid iodine is put into a gas
jar to prove the kinetic theory of matter.
Rajah 1.1 menunjukkan pemerhatian satu eksperimen apabila pepejal iodin diletakkan di
dalam satu balang gas bagi membuktikan teori kinetik jirim.
Gas jar
Balang gas
Diagram 1.1
Rajah 1.1
(a) (i) Name the process in this experiment.
Namakan proses dalam eksperimen itu.
......................................................................................................................
[1 mark]
[1 markah]
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[Lihat sebelah]
4541/2
(a) (ii) Draw the arrangement of the iodine particles in the solid and gaseous state.
Lukiskan susunan zarah-zarah iodin dalam keadaan pepejal dan gas.
Solid / Pepejal
Gas/Gas
[2 marks]
[2 markah]
Diagram 1.2
Rajah 1.2
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[Lihat sebelah]
4
(i)
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(ii)
State the name of two reactants to prepare hydrogen gas in the laboratory.
Nyatakan nama bagi dua bahan tindak balas untuk menyediakan gas hidrogen di
dalam makmal.
[2 marks]
[2 markah]
(iv)
State how to determine that the reaction between copper(II) oxide with hydrogen
gas has been completed.
Nyatakan bagaimana untuk menentukan bahawa tindak balas yang berlaku
antara kuprum(II) oksida dengan gas hidrogen telah lengkap.
................................................................................................................................
[1 mark]
[1 markah]
(iii)
State another metal oxide whose empirical formula can be determined using the
same method.
Nyatakan satu oksida logam lain yang formula empiriknya boleh ditentukan
dengan menggunakan kaedah yang sama.
.................................................................................................................................
[1 mark]
[1 markah]
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Carbon dioxide gas
Gas karbon dioksida
Syringe
Picagari
Calcium carbonate powder
Serbuk kalsium karbonat
Hydrochloric acid
Asid hidroklorik
Diagram 2.1
Rajah 2.1
2
Diagram 2.1 shows the set up apparatus of an experiment to investigate the reaction
between calcium carbonate and hydrochloric acid. A student collect the gas released by
using a syringe. 30 cm3 of carbon dioxide gas was collected at room condition.
Rajah 2.1 menunjukkan susunan radas satu eksperimen bagi mengkaji tindak balas di
antara kalsium karbonat dan asid hidroklorik. Seorang pelajar mengumpul gas yang
terbebas dengan menggunakan picagari. 30 cm3 gas karbon dioksida telah dikumpulkan
pada keadaan bilik.
(a) (i)
[2 marks]
[2 markah]
(ii)
[1 mark]
[1 markah]
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(iii)
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[1 mark]
[1 markah]
(iv) Calculate the maximum mass of calcium carbonate needed to produce carbon
dioxide gas in the syringe.
Hitungkan jisim maksimum kalsium karbonat yang diperlukan untuk
menghasilkan gas karbon dioksida di dalam picagari tersebut.
[Relative atomic mass: Ca=40, C=12, O=16]
[Jisim atom relatif: Ca=40, C=12, O=16]
[2 marks]
[2 markah]
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Diagram 2.2
Rajah 2.2
(b)
(i)
(ii)
..
[1 mark]
[1 markah]
State the types of compound for MSG.
Nyatakan jenis sebatian bagi MSG.
..
[1 mark]
[1 markah]
(iii)
[1 mark]
[1 markah]
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1
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13
14
15
16
17
18
2
3
U
W
4
5
6
Diagram 3.1
Rajah 3.1
3
Diagram 3.1 shows the Periodic Table of elements. The letters P, Q, U and W do not
represent the actual symbols of the elements.
Rajah 3.1 menunjukkan suatu Jadual Berkala Unsur. Huruf P, Q, U dan W tidak
mewakili simbol sebenar unsur berkenaan.
(a)
(i)
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Characteristic
Ciri
Located in Period 2 and has 6 valence electrons
Terletak di kala 2 dan mempunyai 6 elektron valens
Has electron arrangement of 2.8.8.1
Mempunyai susunan elektron 2.8.8.1
Has a stable duplet electron arrangement
Mempunyai susunan elektron duplet yang stabil
Table 3
Jadual 3
Referring to Table 3, indicate the positions of R, S and T by writing the
letters in the correct boxes of the above Periodic Table
Merujuk kepada ciri dalam Jadual 3, tuliskan abjad R, S dan T pada
kedudukan yang betul dalam Jadual Berkala Unsur di atas.
[3 marks]
[3 markah]
[Lihat sebelah]
(b)
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(c)
(d)
Element P and R can react to form a liquid. Write the chemical formula of the
compound formed.
Unsur P dan unsur R boleh bertindak balas menghasilkan suatu cecair. Tuliskan
formula kimia bagi sebatian yang terbentuk.
.................................................................................................................................
[1 mark]
[1 markah]
Both elements of Q and S can react with water.
Kedua-dua unsur Q dan S boleh bertindak balas dengan air.
(i)
(ii)
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Palm oil
Minyak kelapa sawit
sawit
Margarine
Marjerin
180oC
2 atm
Element W
Unsur W
+ flavouring, salt,
vitamin & colouring
+ perisa, garam,
vitamin & pewarna
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+ Milk
+ Susu
White fat emulsion and milk
Emulsi putih lemak dan susu
Diagram 3.2
Rajah 3.2
(e)
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4
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Copper plate
Kepingan
kuprum
Zinc plate
Kepingan
zink
Cell R
Sel R
Copper(II)
sulphate
solution
Larutan
kuprum(II)
sulfat
Copper plate
Kepingan kuprum
Cell S
Sel S
Diagram 4
Rajah 4
(a)
(b)
(c)
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(d)
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.....................................................................................................................
[1 mark]
[1 markah]
(ii)
(e)
(f)
(ii)
.....................................................................................................................
[1 mark]
[1 markah]
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5
(a)
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(ii)
[3 marks]
[3 markah]
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(iii)
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[2 marks]
[2 markah]
(v)
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home remedy
rawatan di rumah
Take a toothpaste
Ambil ubat gigi
Diagram 5.1
Rajah 5.1
(b)
Diagram 5.1 shows home remedy to treat a bee sting. In your opinion, give a
rational reason why the toothpaste is apply on the bee sting site?
Rajah 5.1 menunjukkan rawatan di rumah untuk merawat sengatan lebah. Pada
pandangan anda, mengapakah ubat gigi disapukan ke atas kawasan sengatan
lebah tersebut?
.
..................................................................................................................................
..................................................................................................................................
[2 marks]
[2 markah]
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6.
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Propene
Propena
Reaction I
Tindak balas I
porcelain chips
serpihan porselin
heat
dipanaskan
Propanol
Propanol
Diagram 6.1
Rajah 6.1
(a) State the functional group of propanol.
Nyatakan kumpulan berfungsi bagi propanol.
...................................................................................................................................
[ 1 mark ]
[ 1 markah]
(b) Draw the structural formulae for two isomers of propanol.
Lukiskan formula struktur bagi dua isomer propanol.
[ 2 marks]
[ 2 markah]
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Name reaction I.
Namakan tindak balas I
...................................................................................................................................
[ 1 mark ]
[ 1 markah]
(ii)
Write the balanced chemical equation for the conversion of propanol to propene
in reaction I.
Tuliskan persamaan kimia yang seimbang bagi penukaran propanol kepada
propena dalam tindak balas I.
................................................................................................................................
[ 1 mark]
[ 1 markah]
(d)
Propane and propene are hydrocarbons. Compare the observation when acidified
potassium manganate(VII) solution is added into propane and propene.
Propana dan propena adalah hidrokarbon. Bandingkan pemerhatian apabila larutan
kalium manganat(VII) berasid ditambahkan ke dalam propana dan propena.
....................................................................................................................................
.....................................................................................................................................
....................................................................................................................................
.....................................................................................................................................
[ 3 marks]
[ 3 markah]
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(e)
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Diagram 6.2
Rajah 6.2
Diagram 6.2 shows the liquid car perfume that is usually placed inside the car to
give a fragrance smell like apples. The liquid fragrance smell like apples contains
ethyl pentanoate, with the molecular formula of C4H9COOC2H5.
Rajah 6.2 menunjukkan cecair minyak wangi kereta yang biasanya diletakkan di
dalam kereta untuk memberikan bau wangi seperti epal. Cecair wangi yang berbau
epal ini mengandungi etil pentanoate, dengan formula molekul C4H9COOC2H5.
(i)
(ii)
Describe briefly how the liquid fragrance smell like apples can be prepared in
the laboratory.
Huraikan secara ringkas bagaimana cecair wangi yang berbau seperti epal
boleh disediakan di dalam makmal.
..........................................................................................................................
..........................................................................................................................
..........................................................................................................................
[ 2 marks]
[2 markah]
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Bahagian B
Section B
[20 markah]
Jawab mana-mana satu soalan dalam bahagian ini.
Answer any one question from this section.
https://cikguadura.wordpress.com/
7. Diagram 7.1 shows the flow map for the industrial manufactured of sulphuric acid.
Rajah 7.1 menunjukkan peta alir bagi pembuatan asid sullfurik dalam industri.
Sulphur
Sulfur
+ H2SO4
Step Y
Langkah Y
+ O2
Heat
Panaskan
Oleum
Oleum
Sulphur dioxide
Sulfur dioksida
+ H2O
+ O2
Step X
Langkah X
Sulphur trioxide
Sulfur trioksida
Sulphuric acid
Asid sulfurik
Diagram 7.1
Rajah 7.1
(a) (i)
(iii)
Excess gas that produced during the manufacture of sulphuric acid can cause
environmental pollution. Explain how.
Gas berlebihan yang dibebaskan semasa pembuatan asid sulfurik boleh
menyebabkan pencemaran alam sekitar. Terangkan bagaimana.
[2 marks]
[2 markah]
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(b)
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Diagram 7.2 shows the steps to produce fertilizers X from the reaction between
sulphuric acid and the product of Haber Process.
Rajah 7.2 menunjukkan langkah-langkah untuk menghasilkan baja X daripada
tindak balas di antara asid sulfurik dan produk proses Haber.
Sulphuric Acid
Asid sulfurik
react
bertindak balas
Product of
Haber Process
Produk Proses
Haber
(i)
Fertilizers X
Baja X
Diagram 7.2
Rajah 7.2
Diagram 7.3
Rajah 7.3
(ii) A farmer found that the crops in his farm is infertile as shown in Diagram 7.3. His
friend suggested two fertilizers to improve the fertility of the soil, urea, CO(NH2)2 and
fertilizers X. Choose the best fertilizer for the growth of the plants. Explain your
answer.
[Relative atomic mass: C=12, O=16, N=14, S=32, H=1]
Seorang petani mendapati tanaman di kebunnya tidak subur seperti yang
ditunjukkan dalam rajah 7.3. Rakannya telah mencadangkan dua jenis baja yang
boleh menambah kesuburan tanah, urea, CO(NH2)2 dan baja X.
Pilih baja yang terbaik untuk penanaman tumbuhan. Terangkan jawapan anda.
[Jisim atom relatif: C=12, O=16, N=14, S=32, H=1]
[4 marks]
[4 markah]
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(c) Table 7.1 shows five different manufactured substances in industry, P, Q, R, S and T
and their uses.
Jadual 7.1 menunjukkan lima bahan buatan berbeza dalam industri, P, Q, R, S, T dan
kegunaannya
Manufactured substances in
industry
Bahan buatan dalam industri
P
Q
R
S
T
Uses
Kegunaan
To make boats and badminton racket
Membuat bot dan reket badminton
To make medals and statues
Membuat medal dan tugu
To make the body of aeroplanes
Membuat badan kapal terbang
To make kitchen ware and internal wall of furnace
Membuat peralatan dapur dan dinding relau
To make prism and lenses
Membuat prisma dan kanta
Table 7.1
Jadual 7.1
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8.
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(a) A student has carried out an experiment to construct an ionic equation for the
formation of lead (II) iodide. Seven test tubes of the same size were labelled 1 to 7. A
fixed volume of 5.0 cm3 of 1.0 mol dm-3 potassium iodide solution was poured in each
test tube. The volume of 1.0 mol dm-3 lead (II) nitrate solution that added is shown in
Table 8. The height of precipitate formed in each test tube was measured. The results
are shown in Table 8.
Seorang pelajar telah menjalankan eksperimen untuk membina persamaan ion bagi
pembentukan plumbum (II) iodida. Tujuh tabung uji yang sama saiz dilabelkan dengan
nombor 1 hingga 7. Isipadu tetap larutan kalium iodida 1.0 mol dm-3 sebanyak 5 cm3
dituangkan ke dalam setiap tabung uji. Isipadu larutan plumbum (II) nitrat 1.0 mol dm-3
ditambahkan ke dalam tabung uji seperti yang ditunjukkan di dalam Jadual 8. Tinggi
mendakan yang terbentuk dalam setiap tabung uji diukur. Keputusan eksperimen
ditunjukkan di dalam Jadual 8.
Test tube
Tabung uji
Volume of 1.0 moldm-3
lead(II) nitrate solution / cm3
Isipadu 1.0 moldm-3
plumbum(II) nitrat / cm3
Height of precipitate /cm
Tinggi mendakan / cm
0.5
1.0
1.5
2.0
2.5
3.0
3.5
1.1
2.2
3.4
4.4
5.5
5.5
5.5
Table 8
Jadual 8
(i)
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(ii) Determine the number of moles of lead (II) ions and iodide ions that are
required for the formation of lead (II) iodide. Your answer should consist of
the following:
Tentukan bilangan mol bagi ion plumbum (II) dan ion iodida yang diperlukan
bagi pembentukan plumbum (II) iodida. Jawapan anda hendaklah mengandungi
perkara berikut :
The volume of lead (II) nitrate solution that had reacted completely with 5.0
cm3 of 1.0 mol dm-3 potassium iodide
Isipadu larutan plumbum(II) nitrat yang bertindak balas lengkap dengan 5.0
cm3 1.0 moldm-3 larutan kalium iodida.
Calculate the number of moles of iodide ions that has reacted with 1 mol of
lead(II) ions.
Kirakan bilangan mol ion iodida yang bertindak balas dengan 1 mol ion
plumbum(II)
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(b) Diagram 8 shows the reaction between oxide metal T which is black in colour with
sulphuric acid to form blue salt solution of compound W.
Salt solution W reacts with barium nitrate solution to form salt solution X and insoluble
salt, Solid Y.
Rajah 8 menunjukkan tindak balas di antara oksida logam T yang berwarna hitam
dengan asid sulfurik untuk membentuk larutan garam W yang berwarna biru.
Larutan garam W bertindak balas dengan larutan barium nitrat menghasilkan larutan
garam X dan pepejal Y.
Oxide Metal T
Oksida Logam T
H2SO4
Salt Solution W
Larutan Garam W
Water
Air
+ Ba(NO3)2
Salt Solution X
Larutan Garam X
Solid Y
Pepejal Y
Diagram 8
Rajah 8
Based on Diagram 8 :
Berdasarkan Rajah 8 :
(i) Identify oxide metal T, salt W, salt X and solid Y.
Kenal pasti oksida logam T, garam W, garam X dan pepejal Y.
[4 marks]
[4 markah]
(ii) State one observation when salt solution W reacts with barium nitrate solution
and name the type of reaction occurred.
Nyatakan satu pemerhatian apabila larutan garam W bertindak balas dengan
larutan barium nitrat dan namakan jenis tindak balas yang berlaku.
[2 marks]
[2 markah]
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(iii) Salt solution W reacts with 50 cm3 of 1.0 mol dm-3 barium nitrate solution.
Write the chemical equation for the reaction and calculate the mass of solid Y
produced.
[Relative formula mass of solid Y: 233]
Larutan garam W bertindak balas dengan 50 cm3 1.0 mol dm-3 larutan barium
nitrat. Tuliskan persamaan kimia bagi tindak balas tersebut dan kirakan jisim
pepejal Y yang terhasil.
[Jisim formula relatif bagi pepejal Y : 233]
[4 marks]
[4 markah]
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SECTION C
Bahagian C
[20 markah]
Answer any one question from this section.
Jawab mana-mana satu soalan dalam bahagian ini.
https://cikguadura.wordpress.com/
9.
Table 9 shows the experiments which are carried out to investigate factors that affect the
rate of reaction of zinc powder with acid X and acid Y.
Jadual 9 menunjukkan ekperimen yang dijalankan untuk mengkaji faktor-faktor yang
mempengaruhi kadar tindak balas antara serbuk zink dengan asid X dan asid Y.
Experiment
Eksperimen
II
III
Reactants
Bahan Tindak balas
2 g zinc powder + 50.0 cm3 of 0.5 mol dm3
acid X
2 g serbuk zink + 50.0 cm3 of 0.5 mol dm3
asid X
2 g zinc powder + 50.0 cm3 of 0.5mol dm3
acid Y
2 g serbuk zink + 50.0 cm3 of 0.5 mol dm3
asid Y
2 g zinc powder + 50.0 cm3 of 0.5 mol dm3
acid Y + 5 drops copper(II) sulphate solution.
2 g serbuk zink + 50.0 cm3 of 0.5 mol dm3
asid Y + 5 titis larutan kuprum(II) sulfat
Products
Hasil Tindak balas
Zinc chloride and gas Z
Zink klorida dan gas Z
Table 9
Jadual 9
(a)
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(ii)
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(iii) Sketch a graph volume of gas Z against time for experiment I, II and III on the
same axes.
Lakarkan graf isipadu gas Z melawan masa bagi eksperimen I, II dan III pada
paksi yang sama.
[ 4 marks]
[4 markah]
(iv) Compare the rate of reaction in experiment II and III . Explain your answer based
on collision theory
Bandingkan kadar tindak balas dalam eksperimen II dan III. Terangkan jawapan
anda berdasarkan teori perlanggaran.
.
[ 5 marks]
[5 markah]
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Diagram 9
Rajah 9
(b) Diagram 9 shows a baker making his dough in order to make bread. The baker
discovers that the bread dough rises faster in a warm place than in a cool place.
From the situation above, identify the factor that affects the rate of rising of dough
and explain how the factor affects the rate of rising of the dough.
Rajah 9 menunjukkan seorang tukang masak membuat adunan roti. Tukang masak
tersebut mendapati bahawa adunan roti menaik dengan lebih cepat di tempat yang
panas berbanding tempat yang sejuk.
Dari situasi di atas, kenal pasti faktor yang mempengaruhi kadar kenaikan doh dan
terangkan bagaimana faktor tersebut mempengaruhi kadar kenaikan doh tersebut.
[ 3 marks ]
[3 markah]
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Respiration Process
Proses Respirasi
Photosynthesis Process
Proses Fotosintesis
Diagram 10.1
Rajah 10.1
Diagram 10.2
Rajah 10.2
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10
(a)
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Based on Diagram 10.1 and 10.2, compare and contrast both processes above.
Your explanation should include the following :
types of chemical reactions
energy content of reactants and products
draw the energy level diagrams
Berdasarkan Rajah 10.1 dan Rajah 10.2, banding bezakan kedua-dua proses di
atas. Penerangan anda perlu memasukkan perkara-perkara berikut :
jenis tindak balas kimia
kandungan tenaga bahan dan hasil tindak balas
lukis gambarajah aras tenaga
[ 8 marks ]
[8 markah]
Spatula
Spatula
Thermometer
Termometer
Metal X
Logam X
Polystyrene Cup
Cawan polistirena
Copper(II) sulphate solution
Larutan kuprum(II) sulfat
Diagram 10.3
Rajah 10.3
(b)
Excess metal X powder is added to 50 cm3 of 0.1 mol dm-3 copper (II) sulphate
solution produce 210 kJmol-1 heat energy. Based on diagram 10.3, suggest metal
X. Calculate the change in temperature of the solution.
[Given that Specific heat capacity of solution : 4.2 J g -1oC-1]
Serbuk logam X berlebihan ditambahkan kepada 50 cm3 0.1 mol dm-3 larutan
kuprum (II) sulfat menghasilkan 210 kJmol-1 tenaga haba. Berdasarkan rajah
10.3, cadangkan logam X. Hitungkan perubahan suhu larutan.
[Muatan haba tentu larutan : 4.2 J g -1oC-1]
[ 4 marks ]
[4 markah]
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(c)
Materials needed
Bahan-bahan yang diperlukan
Procedure of experiment
Prosedur eksperimen
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This question paper consists of three sections: Section A, Section B and Section C.
Kertas soalan ini mengandungi tiga bahagian: Bahagian A, Bahagian B danBahagian C.
2.
Answer all questions in Section A. Write your answers for Section A in the spaces provided in the
question paper.
Jawabsemua soalan dalam Bahagian A. Tuliskan jawapan bagi Bahagian A dalam ruang yang
disediakan dalam kertas soalan
3.
Answer one question from Section B and one question from Section C.
Write your answers for Section B and Section C on the `answer sheet provided by the invigilators.
Answer questions in Section B and Section C in detail.
You may use equations, diagrams, tables, graphs and other suitable methods to explain your answer.
Jawab satu soalan daripada Bahagian B dan satu soalan daripada Bahagian C. Tuliskan jawapan
bagi Bahagian B dan Bahagian C pada kertas tulis yang dibekalkan oleh pengawas peperiksaan.
Jawab Bahagian B dan Bahagian C dengan terperinci. Anda boleh menggunakan persamaan,
gambar rajah, jadual, graf dan cara lain yang sesuai untuk menjelaskan jawapan anda.
4.
The diagrams in the questions are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan
5.
Marks allocated for each question or sub-part of the question is shown in brackets.
Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan dalam kurungan.
6.
7.
If you wish to change your answer, neatly cross out the answer that you have done. Then write down
the new answer.
Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan itu.
8.
9.
You are advised to spend 90 minutes to answer questions in Section A, 30 minutes for Section B and
30 minutes for Section C.
Anda dicadangkan mengambil masa 90 minit untuk menjawab soalan dalam Bahagian A, 30 minit
untuk Bahagian B dan 30 minit untuk BahagianC.
10. Tie together your answer sheets at the end of the examination.
Ikat semua kertas jawapan anda di akhir peperiksaan.
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SULIT
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NAMA :....................................................................................................
KELAS :...................................................................................................
PEPERIKSAAN PERCUBAAN
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4541/3
CHEMISTRY
Kertas 3
September
1 jam
1 jam 30 minit
Markah
penuh
15
18
17
Markah
diperoleh
JUMLAH
Kertas soalan ini mengandungi 11 halaman bercetak
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SULIT
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1.
Diagram 1.1 shows the apparatus set-up for an experiment to determine the
melting point of naphthalene. Solid naphthalene is heated in a water bath until
melts completely.
Rajah 1.1 menunjukkan susunan radas bagi bagi ekspeimen untuk menentukan
takat lebur naftalena. Pepejal naftalena dipanaskan dalam kukus air hingga
melebur dengan lengkap.
Thermometer
Termometer
Boiling tube
Tabung didih
Water bath
Kukus Air
Naphthalene
Naftalena
Diagram 1.1
Rajah 1.1
The readings of the temperature of naphthalene are recorded every 30 seconds
from 60.0oC until 95.0oC.
Table 1.1 shows the thermometer readings of the experiment.
Bacaan suhu naftalene telah direkodkan bagi setiap 30 saat daripada 60.0OC
hingga 95.0oC.
Jadual 1.1 menunjukkan bacaan termometer bagi eksperimen itu.
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SULIT
Initial temperature:.
Suhu awal
Temperature at 30s: ..
Suhu pada 30 saat
4541/3
For
Examiners
Use
Temperature at 60s:
Suhu pada 60 saat
Temperature at 90s:.
Suhu pada 90 saat
Temperature at 120s: .
Suhu pada 120 saat
Temperature at 150s: .
Suhu pada 150 saat
Temperature at 180s: ..
Suhu pada 180 saat
Temperature at 210s: ..
Suhu pada 210 saat
Temperature at 240s: ..
Suhu pada 240 saat
Table 1.1
Jadual 1.1
(a)
Record the temperature for every 30 second interval as shown in Table 1.1.
Rekodkan suhu bagi setiap sela masa 30 saat dalam Jadual 1.1
[3 marks]
4541/3 PAHANG
SULIT
4541/3 For
Examiners
Use
(b)
(i)
(ii)
Plot a graph of temperature against time for the heating of naphthalene on the
graph paper given in page 5.
Plotkan graf suhu melawan masa bagi pemanasan naftalena di atas kertas graf
yang disediakan pada muka surat 5.
[3 marks]
State the melting point of naphthalene, and show on the graph how you
determine this melting point.
Nyatakan takat lebur naftalena, dan tunjukkan di atas graf bagaimana
anda tentukan takat lebur ini.
[3 marks]
( c)
The temperature of naphthalene did not change from 90th second until the 150th second
during the melting process. Explain why.
Suhu naftalena tidak berubah dari saat ke-90 hingga saat ke-150 semasa proses
peleburan itu. Terangkan mengapa.
..
.
[3 marks]
4541/3 PAHANG
SULIT
(b) (i)
4541/3 PAHANG
4541/3
SULIT
d)
4541/3
For
Examiners
Use
Covalent compound
Sebatian kovalen
3
[3 marks]
TOTAL
4541/3 PAHANG
SULIT
4541/3
2. Table 2.1 shows the observation in five test tubes used to investigate the effect of other
metals on rusting. A mixture of jelly solution, potassium hexacyanoferrate(III),
K3Fe(CN)6 solution and phenolphthalein were used as medium in each test tube. The
observations were recorded after one day.
Jadual 2.1 menunjukkan pemerhatian dalam lima buah tabung uji yang digunakan
untuk menyiasat kesan logam lain ke atas pengaratan. Medium yang digunakan di
dalam setiap tabung uji adalah campuran larutan agar, larutan kalium
heksasianoferat(III), K3Fe(CN)6 dan fenolftalein. Pemerhatian direkod selepas satu
hari.
Very low intensity of blue colour
Very low intensity of pink colour
Keamatan warna biru sangat
rendah
Keamatan warna merah jambu
sangat rendah
Test tube 1
Tabung uji 1
No blue spot
Low intensity of pink colour
Tiada tompokan biru
Keamatan warna merah jambu
sangat rendah
Test tube 2
Tabung uji 2
Test tube 3
Tabung uji 3
No blue spot
High intensity of pink colour
Tiada tompokan biru
Keamatan warna merah jambu
tinggi
Test tube 4
Tabung uji 4
Test tube 5
Tabung uji 5
For
Examiners
Use
SULIT
4541/3
For
Examiners
Use
(a) State the observation and inference for test tube 2, 3 and 4.
Nyatakan pemerhatian dan inferens untuk tabung uji 2, 3 dan 4.
Test tube
Tabung uji
Observation
Pemerhatian
Inference
Inferens
[6 marks]
(ii)
(iii)
4541/3 PAHANG
SULIT
(d)
4541/3
For
Examiners
Use
............................................................................................................................................
[3 marks]
(e)
[3 marks]
TOTAL
4541/3 PAHANG
SULIT
10
4541/3
3
Experiment I : NaOH + HCl NaCl + H2O
H = - 57.5 kJmol-1
H = - 55 kJmol-1
The value of the heat of neutralization for the reaction between sodium
hydroxide solution and strong acid solution is higher than the value of the heat
of neutralization for the reaction between sodium hydroxide solution and weak
acid solution.
Nilai haba peneutralan bagi tindak balas antara larutan natrium hidroksida
dengan larutan asid kuat lebih tinggi daripada haba peneutralan larutan natrium
hidroksida dengan larutan asid lemah.
Based on the above statement, you are required to design an experiment to determine and
compare the heat of neutralization between sodium hydroxide solution with a named strong
acid solution and a weak acid solution.
Berdasarkan pernyataan di atas, anda dikehendaki merancang eksperimen untuk
menentukan haba peneutralan di antara larutan natrium hidroksida dengan satu larutan
asid kuat dan satu larutan asid lemah yang dinamakan.
Your planning should include the followings :
Perancangan anda hendaklah mengandungi perkara-perkara berikut:
(a)
Problem Statement
Pernyataan masalah
(b)
Hypothesis
Hipotesis
(c)
(c)
(d)
(e)
Tabulation of data
Penjadualan data
[17 marks]
END OF QUESTION PAPER
KERTAS SOALAN TAMAT
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4541/3 PAHANG
SULIT
11
Marks awarded:
Mark
3
2
1
0
4541/3 PAHANG
Description
Excellent
: The best response
Satisfactory
: An average response
Weak
: An inaccurate response
No response or wrong response
4541/3
ANSWER SCHEME
CHEMISTRY
PAPER 1
(TRIAL 2015)
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
B
D
B
B
C
A
A
B
A
B
D
C
A
C
D
A
A
C
B
B
B
C
D
D
C
26
27
28
29
30
31
32
33
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50
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C
A
A
A
D
A
C
D
B
A
B
C
D
C
B
A
D
A
C
B
C
D
D
C
B
Marking Scheme
Chemistry Paper 2 (4541/2)
SPM Trial Exam 2015
https://cikguadura.wordpress.com/
Question
1
(a)
(i)
Marking Criteria
Diffusion
a: sublimation
Sub
mark
1
Mark
1
1
(ii)
Solid
(b)
Gas
(iii)
Molecule
(i)
(ii)
1
1
Sample answer :
- Zinc (r: formula) (r: Copper // Argentum)
- Sulphuric acid
(iii)
(iv)
1
1
Total
Question
2
(a)
Marking Criteria
Sub
mark
(i)
(ii)
1
1
1
(iii)
(iv)
(i)
(ii)
(iii)
1
1
C5H8NO4Na
Ionic compound (r : ionic bond)
169
Question
Mark
1
1
1
Total
Marking Criteria
(a)
T
Sub
mark
1
1
1
1
1
1
9
Mark
3
(b)
(c)
(d)
T
P2R // H2O
(i)
(ii)
(iii)
S
- Atom S is more reactive than atom Q.
- Valence electron in atom S is further away from the nucleus
compare to atom Q.
- The attraction force between the proton in the nucleus of
atom S is weaker than atom Q // Atom S is more easier to
released electron than atom Q.
- Act as a catalyst
1
1
1
1
1
3
1
Total
1
10
Question
4
Marking Criteria
Sub
mark
Mark
(a)
(b)
Cu2+ and H+
(c)
- Copper
- Cu2+ received 2 electrons (to form copper)
(d)
(i)
(ii)
- Put the burning wooden splinter into the mouth of the test
tube containing the gas
- the pop sound produced
(e)
(f)
1
1
2
1
1
1
Zinc
(i)
(ii)
Total
10
Question
5
(a)
(i)
(ii)
Marking Criteria
H2SO4 + 2NaOH Na2SO4 + 2H2O
- Correct formula of reactants and products
- Balanced equation
Sub
mark
1
1
Mark
1
1
1
(iv)
burrette
Sulphuric acid
Sodium hydroxide
+ phenolphthalein
- Functional diagram
- Labelled diagram
(v)
(b)
- 25 cm3
- Concentration of H+ in the hydrochloric acid is half of
sulphuric acid // Concentration of H+ in the sulphuric acid is
double of hydrochloric acid
- Bee sting is acidic, toothpaste is basic//alkaline
- Toothpaste neutralises the bee sting
1
1
1
1
1
1
Total
2
2
2
11
Question
6
Marking Criteria
Sub
Mark
1
Total
Mark
1
1+1
(i) Dehydration
(a)
(b)
(c)
(d)
(e)
(i)
(ii)
1
1
1
2
1
11
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Question
7
(a)
Marking Criteria
(i)
Sub
Mark
Total
Mark
Answer :
Contact Process
(b)
(c)
(d)
1+1
1+1
1
1
(ii) 1. Urea
2. % of N in urea = 28 / 60 x 100 = 46.67%
3. % of N in fertilizers X = 28 / 132 x 100 = 21.21%
4. Percentage of N atoms by mass in urea is higher than
ammonium sulphate
1
1
1
1
(i)
P : Fibre glass
Q : Bronze
R : Duralumin
S : Ceramics
T : Lead crystal glass
1
1
1
1
1
Properties:
Durable / light /inert to chemical / insulator
(any 2 answers)
1+1
1
4
1
TOTAL
20
Question
8
(a)
Marking Criteria
(i) - correct label of axis and unit
-correct plot
-correct curve
Sub
Mark
1
1
1
Total
Mark
1
1
1
1
Pb2+ + 2 I- PbI2
(b)
1
1
(ii)
2
Question
Marking Criteria
Sub
Mark
Total
Mark
- ratio
1 mol Ba(NO3)2 : 1 mol BaSO4
0.05 mol Ba(NO3)2 : 0.05 mol BaSO4
TOTAL
20
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Question
9
(a)
Marking Criteria
(i) Acid X : hydrochloric acid
Acid Y : sulphuric acid
Gas Z : hydrogen gas
Sub
Mark
1
1
1
Total
Mark
Reject : formula
-correct method and reagent to identify gas Z
-correct observation
1
1
Answer :
Put a burning wooden splinter to the mouth of test tube
pop sound produce
1
3
1
Question
(iii)
Marking Criteria
Sub
Mark
Total
Mark
-Temperature
-at warm place, kinetic energy of particles increases/higher
-Rate of rising of the dough increases/higher
TOTAL
1
1
1
1
1
1
1
1
1
1
1
1
3
20
Question
10
(a)
Marking Criteria
Sub
Mark
Total
Mark
1
1
1
1
-1
H = -x kJmol
1+1
6H2O + 6CO2
C6H12O6 + 6O2
1+1
-1
H = +y kJmol
6H2O + 6CO2 + sunlight
8
(b)
1
1
1
4. = 1050
. oC // 5.0oC
(50)(4.2)
Question
(c)
Marking Criteria
Sub
Mark
Total
Mark
1
1
Procedure:
1. Measure 50 cm3 of copper (II) sulphate solution 0.5 mol
dm-3 using measuring cylinder and pour into polystyrene
cup
2. Measure initial temperature of the solution.
3. Measure 50 cm3 of lead(II) nitrate solution 0.5 mol dm-3
using measuring cylinder and pour into another
polystydsrene cup
4. Measure initial temperature of the solution.
5. Mix the solution, stir by using thermometer and measure
the maximum temperature of the mixture.
1
1
1
1
1
Table:
Initial temperature of
Lead(II) nitrate /oC
Initial temperature
Copper(II) sulphate /oC
Average Initial temperature
of the mixture /oC
Maximum Temperature/oC
Temperature change /oC
1
2
1
3
4
4 - 3
8
TOTAL
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20
Question
1(a)
Explanation/Rubric
Able to record all reading accurately to one decimal point and with unit.
Sample answer:
Initial temperature
: 60.0oC
Temperature at 30s
: 68.0 oC
Temperature at 60s
: 78.0 oC
Temperature at 90s
: 80.0 oC
Temperature at 120s : 80.0 oC
Temperature at 150s : 80.0 oC
Temperature at 180s : 82.0 oC
Temperature at 210s : 85.0 oC
Temperature at 240.0s : 95.0oC
Able to record all readings correctly without decimal point
// Able to record 6-8 readings correctly
Question
1(b)(i)
Maximum
score
Explanation/Rubric
Maximum
score
Sample answer:
Temperature/oC
Time/second
Question
Explanation/Rubric
Maximum
score
Sample answer:
Temperature
Time
Able to give an idea to plot a graph
Question
1(b)(ii)
Explanation/Rubric
Able to state the melting point correctly with 1 decimal place and unit
and show on the graph
Sample answer :
Temperature/oC
Melting point
80.0 oC
Time/ second
Maximum
score
Question
Explanation/Rubric
Able to state the melting point correctly with or without decimal place
but with correct unit only without showing on the graph
// Able to state the melting point on the curve
Maximum
score
Sample answer;
-
Time/ second
1
Able to state the melting point less accurately without unit and without 1
decimal place // Able to show the melting point incorrectly;
Sample answer:
- Melting point of naphthalene : 80 //
Temperature/oC
melting point
Time/ second
No response or wrong response
Question
1(c)
Explanation/Rubric
Able to explain correctly according to 3 information :
-
Question
1(d)
Maximum
score
3
Sample answer :
Heat energy absorbed is used to overcome the forces of attraction
between the molecules so that solid naphthalene can turn into liquid.
Able to explain less accurately
Sample answer :
The heat energy is used to overcome the forces of attraction between
molecules / particles
Able to state an idea
Sample answer :
The heat energy is used / absorbed
No response or wrong response
Explanation/Rubric
Able to classify all the compound correctly
Ionic compound
covalent compound
Potassium bromide
Glucose
Zinc nitrate
methanol
Sodium chloride
ethyl ethanoate
Able to classify any 5 compound correctly.
Able to classify at least 2 compound correctly
No response or wrong response/
Maximum
score
2
1
0
Question
2 (a)
Explanation/Rubric
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Maximum
score
Observations
Pemerhatian
Low intensity of pink
colour/ solutions
//
No blue spot
Inferences
Inferen
Iron(II) / Fe2+ ions are not formed
/produced in the solutions //
Zinc/Zn corroded / oxidized slowly //
less OH- ions formed //
Iron / Fe does not rust/
corrode/oxidised
//
No blue spot
4
3
2
1
0
correctly//
correctly
correctly
correctly
Question
2 (b)
Explanation/Rubric
Able to state the relationship between the manipulated variable and the
responding variable and state the direction correctly.
Maximum
score
3
Sample answer
When a less electropositive metal than iron is in contact with iron
nail/ferum/Fe, the metal speeds up rusting/corrosion of iron but when a
more electropositive metal is in contact with iron/ferum/Fe, the metal
inhibits rusting/corrosion of iron //
When the metal in contact with iron is lower than iron/ferum/Fe in
electrochemical series, the rusting/corrosion of iron is faster but when
the metal in contact with iron is higher than iron/ferum/Fe in
electrochemical series, the iron does not rust/ rusting/corrosion of iron
slower//
The further the distance between less electropositive metals and
iron/Fe in electrochemical series that in contact with iron, the higher is
the intensity/more of blue spots formed but the further the distance
between more electropositive metals and iron/Fe in electrochemical
series that in contact with iron, the higher is the intensity/more of pinc
colour formed.
Able to state the relationship between the manipulated variable and the
responding variable without stating the direction/ less accurately
Sample answer
When different metal in contact with iron, the more blue spot/rust
formed
Able to give an idea of hypothesis
Sample answer
Pair of metal will produce rust
No response or wrong response
Question
2 (c)
Explanation/Rubric
Able to state all the variables in this experiment correctly.
Sample answer
(i) Manipulated variables : Type/different metal // position of metal in
electrochemical series
(ii) Responding variable : Rusting / corrosion // presence of blue/pink
colour
(iii) Constant variable : Size/mass of iron nail // type of nail // clean iron
nails // temperature // medium in which the iron
nail are kept
Able to state any two variables correctly
Question
2 (d)
Maximum
score
3
Explanation/Rubric
Able to give one operational definition of the experiment correctly with
the following aspects:
i.what you do
ii.what you observe
Sample answer
Blue spot form when less electropositive metal is in contact with iron
nail and dipped/put into jelly solutions that contain potassium
hexacyanoferrate (III) and phenolphthalein//
Rusting occurs when iron nail is in contact with tin/less electropositive
metal and form blue colouration in potassium hexacyanoferrate(III)
solution and phenolphthalein
//
No blue spot form when more electropositive metal is in contact with
iron nail and dipped/put into jelly solutions that contain potassium
hexacyanoferrate (III) and phenolphthalein //
Rusting does not occurs when iron nail is in contact with Mg/Zn/more
electropositive metal and form blue colouration in potassium
hexacyanoferrate(III) solution and phenolphthalein
// (based on test tube 1)
Blue spot form when iron nail dipped into jelly solutions that contain
potassium hexacyanoferrate (III) and phenolphthalein
Maximum
score
3
Question
Explanation/Rubric
Able to give the operational definition for rusting incompletely with any
one of the following aspects:
i.what you do
ii.what you observe
Maximum
score
2
Sample answer
Metal is put into jelly blue spot form
Able to give an idea of operational definition for rusting
Sample answer
Iron corrodes/rust/oxidised
No response or wrong response
Question
2 (e)
Explanation/Rubric
Able to predict the metal Q correctly
Maximum
score
3
Sample answer
Copper/Cu // Silver/Ag
Able to predict the metal Q less correctly
Sample answer
Gold/Au
Able to give an idea of predicting the metal
Sample answer
Mercury/Hg
No response or wrong response
Question
Explanation/Rubric
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3 (a)
Able to state the problem statement with the named strong acid
solution and weak acid solution accurately
Sample answer :
Does the heat of neutralisation between hydrochloric acid and sodium
hydroxide solution is higher than the heat of neutralisation between
ethanoic acid and sodium hydroxide solution?
Able to state the problem statement less accurately
Sample answer :
Does the heat of neutralization between strong acid and weak acid
with strong alkali different ? //To study the heat of neutralization
between strong and weak acid with strong alkali.
Able to state an idea about problem statement
Sample answer :
Heat of neutralisation is affected by the strength of acid.
No response or wrong response
Question
3 (b)
Explanation/Rubric
Able to state the relationship between the manipulated variable and the
responding variable and state the direction correctly.
Maximum
score
3
Maximum
score
3
Sample answer :
The reaction between hydrochloric acid/strong acid and sodium
hydroxide will give the higher value of heat of neutralization than the
reaction between ethanoic acid/weak acid with sodium hydroxide.
Able to state the relationship between the manipulated variable and the
responding variable without stating the direction/ less accurately
Sample answer
Different strength of acid react with sodium hydroxide, different value of
heat of neutralisation
Able to give an idea of hypothesis
Sample answer
The strength of acid affect the heat of neutralisation
No response or wrong response
Question
3 (c)
Question
3 (d)
Explanation/Rubric
Able to state all the variables accurately
Sample answer :
Manipulated variable: Hydrochloric Acid and Ethanoic Acid (any
suitable named strong and weak acid)
// Strong acid and weak acid
Responding variable : Heat of neutralisation
Fixed variable
: Concentration and volume of NaOH
solution//NaOH solution//polystyrene cup //
Concentration and volume of acid solution
Maximum
score
3
Explanation/Rubric
Able to list down the materials and apparatus completely
Sample answer :
Materials : [0.5-2.0 mol dm-3 ] sodium hydroxide solution,
[0.5-2.0 mol dm-3 ] hydrochloric acid, [0.5-2.0 mol dm-3 ]
ethanoic acid (any suitable strong and weak named acid),
Apparatus :Polystyrene/plastic cup, thermometer, [50-100cm3]
measuring cylinder
Able to give the list of the apparatus and materials correctly but not
complete
Sample answer :
sodium hydroxide solution, hydrochloric acid / ethanoic acid,
Polystyrene/plastic cup, thermometer,
Able to give an idea on the list of the apparatus and substances
correctly
Any one materials and one apparatus with thermometer
No response or wrong response
reject : no thermometer
Maximum
score
3
Question
3 (e)
Explanation/Rubric
Able to state all the steps of the experiment accurately
Example
1. [25-100 cm3 ] of sodium hydroxide solution is poured into a
polystyrene cup using a measuring cylinder.
2. The initial temperature of sodium hydroxide solution is recorded.
3. [25-100 cm3 ] of hydrochloric acid is measured into another
polystyrene cup.
4. The initial temperature of hydrochloric acid is recorded.
5. Hydrochloric acid is then poured quickly into a cup containing
sodium hydroxide solution.
6. The mixture is stirred using thermometer and the highest
temperature is recorded.
7. Repeat steps 1 to 6 using ethanoic acid instead of hydrochloric
acid.
Maximum
score
3
1
0
Question
3 (f)
Explanation/Rubric
Able to construt the table that contains the following information
1. Columns and rows
2. Headings in the table
3. With unit
Sample answer:
Initial temperature/ oC
Highest temperature
of the mixture/o C
Pair of acid/alkali
Acid
Alkali
Maximum
score
2
Average
NaOH/HCl
NaOH/CH3COOH
Able to construt the table that contains the following information
1. Columns and rows
2. Headings in the table
3. Without unit
Highest
temperature of
the mixture
Alkali
//
Sample answer :