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Weeks5 6
Weeks5 6
Weeks5 6
Angular momentum
Important example of the use of operators in
quantum mechanics
Leads to analysis of spin
Lays the foundation for solutions of the
Schrodinger equation in 3D
L = r p
In quantum mechanics we replace r and p with
the corresponding operators (see section 1.2),
so the angular momentum operator becomes:
L = r p
Cartesian components are:
L x = y p z z p y
L y = z p x x p z
L z = x p y y p x
z zp
z ) ( zp
z ) ( yp
z zp
y ) ( zp
x xp
x xp
y )
= ( yp
Lx , L y = yp
x ( p z z zp
y ( zp
z ) + xp
z p z z )
y yp
x ) ( zp
z p z z )
= ( xp
y y p x ) = iL z
= i ( xp
We find
Lx , L y = iLz
L y , L z = iL x
Lz , Lx = iL y
L2 , L x = L2 , L y = L2 , L z = 0
L+ = Lx + iL y
L = L x iL y
Properties of L+ and L
L+ L = Lx + iL y
)( L iL )
x
= L2x + L2y iL x L y + iL y L x
= L2 L2z i Lx , L y
= L2 L2z + L z
Similarly
L L+ = L2 L2z L z
So
L+ , L = 2Lz
Lz , L+ = L z , L x + i Lz , L y
= i L iL
So
Lz , L+ = L+
Similarly
Lz , L = L
L2 n = n n
and
Lz n = n n
n n2
The algebra.
L z n = n n
L+ Lz n = n L+ n
Lz , L+ = L+
so L+ L z = L z L+ L+
Lz L+ n
) = (
L
)
n
+
n
L z L n
) = (
L
)
n
n
L+ n is an eigenfunction of L z with
eigenvalue n +
L n is an eigenfunction of L z with
eigenvalue n
More algebra.
L2 n = n n
2
L+ L n = n L+ n
L L2 n = n L n
L2 commutes with L x and L y , so it must
commute with L and L
+
(
L ( L
L2 L+ n
2
) = ( L
) = ( L
n
)
)
L+ max = 0 so L L+ max = 0
From above
L L+ = L2 L2z L z
so
L2 L2z Lz max = 0
ie
2
= max ( max + )
= min ( min )
It follows that
min = max
Neighbouring values of on the L z ladder
differ by , so
n
=
2
Finally, we have
Eigenvalues of L2 are = ( + 1) 2 , with an
integer or half integer
For each value of , eigenvalues of L z can be
written as = m , where m varies in integer
steps between and +
L = r p = i r
In spherical polars
1
1
= e r + e
+ e
r
r
r sin
So
L = i e
e
sin
e z = e r cos e sin
and
Lz = e z . L Lz = i
For L2 we find
2
1
1
2
2
L =
sin
+ 2
2
sin
sin
We want to solve
L2 Ym ( , ) = ( + 1) 2 Ym ( , )
L z Ym ( , ) = m Ym ( , )
Ym ( , ) are the common eigenfunctions of L2
and L z with eigenvalues ( + 1) 2 and m
respectively
The solutions Ym ( , ) are called spherical
harmonics. Derivations of them can be found in
textbooks and in other units.
1
Y00 =
4
3
Y10 =
cos
4
3
Y11 =
sin exp(i )
8
5
2
Y20 =
3cos
1)
(
16
15
Y21 =
cos sin exp(i )
8
Y2 2
15
=
sin 2 exp(2i )
32
Sx , S y = i Sz
S y , S z = i S x
Sz , Sx = i S y
S 2 = Sx2 + S y2 + Sz2
All of the previous analysis follows through,
and we can conclude that:
Eigenvalues of S 2 are s ( s + 1) 2 , with s an
integer or half integer
Eigenvalues of Sz are ms , where ms varies in
integer steps between s and s
For spin, the half integer solutions matter.
Atoms with no orbital angular momentum and
a single unpaired electron split into two beams
in a Stern-Gerlach experiment.
1
Electrons are spin-half particles, ie s =
2
0 1
x =
1
0
0 i
y =
0
i
1 0
z =
Sx = x
2
Sy = y
2
Sz = z
2
Sx , S y =
4 1 0 i 0 i 0 1 0
2 i 0 i 0
=
i
0
i
4
1 0
= i
=
i
S
z
2 0 1
Eigenvalue
Eigenvector
Sx
+
2
1
2
Sx
S y
+
2
S y
Sz
+
2
1
0
Sz
0
1
1
2
1
1
1
2
1
2
1
1
1
i
1
i
1 0
2
2
2
Sx = S y = Sz =
4 0 1
2
so
3 2 1 0
2
S =
4 0 1
As expected, S 2 commutes with Sx , S y , Sz
All of the above eigenvectors are also
3 2
2