A ay soy = 2A gm +342 Application ofKohirausch's Law 1. For calculation of limiting molar conductivity 2° = 2% ig a te Otte ea (=a) A(A°=A) 2. For calculation of degree of dissociation 3. For calculation of dissociation constant. K, =. 7 ‘Faraday — First law of electrolysis : The amount of | Faraday — Second Law : The amount of diferent substances ‘substance deposited during electrolysis is directly | librated by the same quantity of electricity passing through the proportional fo quanty of elect pase tletosticslaton Is proporonal other chemical equivalent mxixt —_ | weighs Werte) wd 2=% terete f On nF nF ae 7 Nieustemnation Taniicine concn J A oquloon Q=K and a E° cell a log Ke z, Gancentration Cel A cl in which both cleorodes are of tho ie Gp bat We sao of cksea i wa tay dip have diferent concentration i concentration eel Cu Cv"(C\yiCu"(CayCu 4,G° =-2.303R7 log K, Bagg = 2303RT gy Oa 2F Lf Froese of coats ‘NaCl (molten) ‘Cathode : Na"(I) + — Na(s) ‘Anode : Cl —> ¥sCl,+e_ NaCl (aq) Cathode = Hy0 @) re => YaHig) > OF Anode : CI Ch Fe FSO, Cathode €°> 9 Anode: 2H = Ox Tag) SAE H,S0,(cone) Cathode H+ eH “Anode: 280,” (a9) — S;0¥" (aq) +2e~ ABNO,(ag)-Ag electrodes | Cathode : Ag"(aq) +e AgT@) ‘Anode: AgG)> Ag'(aq) + € "ASNO (ag) Pt electrodes | Cathode : Ag"(aq) +e Ag(s) ‘Anode: 2H,0(1 > O3(g) + 41 (aq) + 4e™ ‘CuCitag)- Pr electrodes —| Cathode i Cu‘(ag) +€> Cu(s) “Anode: 2H;0(1)—> Ox(g) + 4H (aq) + 4e Hletrochemical Cll Hlectrolyfe Cal T 1 convert-chemical energy to] 1. is device convert lecrical energy ino chemical energy clea exeay 2. The rol reaction ts mowapontancous snd takes place oly 21 te bee eras eco lek ie cecal caegs eed spontaneous. ‘By covering the surface with palnt or by some chemicals (eg. bisphenol). / Cover the surface by other Prevention of Corrosion | metals (Sn, Zn, etc.) that are inert or react 1 save the object. An electrochemical method sacrificial electrode like Mg, Zn, etc.) which corrodes itself but saves the object.