Desviacin

Coeficiente de Corelacin

Temperatura (K)

Constante de Equilibrio Keq

1000
1100
1200
1300
1400
1500

3.41
161
4030
61100
629000
4750000

1364653.186
0.723

5000000

4500000

4000000

3500000

3000000

2500000

2000000

1500000

f(x) = 0.0006234959x^4 - 2.9404441312x^3 + 5179.904630934x^2 - 4039090.84821

R = 0.998956918

2500000

2000000

1500000

1000000

500000

0
0

200

400

600

800

1000

1200

1400

160

4630934x^2 - 4039090.84821147x + 1176143070.09702

Tabla 2
Polynomial (Tabla 2)

Polynomial (Tabla 2)

1200

1400

1600

T (C)

0.02
0.035
0.08
0.12
0.155
0.175
0.19
0.185

800
900
950
1000
1050
1100
1200
1300

0.2

f(x) = 2.51214159801467E-011x^4 - 1.0978686748772E-007x^3 + 0.0001772489x^2 - 0.1248286727

0.18
R = 0.9991593306
0.16

0.14
0.12
0.1
0.08
0.06
0.04
0.02
0
700

T (C)
800

900

1000

1100

1200

1300

1400

001772489x^2 - 0.1248286727x + 32.3643620586

00

Column C
Polynomial
(Column C)

1300

1400

R
1200 C

Time min

LN(1-R)

t^0,5

a= LN(1-R)/t^0,5

log a

0.85
0.94
0.96
0.97
0.98
0.99

5
10
15
30
60
90

1.8971199849

2.2360679775

0.8484178495

-0.0713902031

2.8134107168

3.1622776602

0.8896785858

-0.0507668626

3.2188758249

3.8729833462

0.8311101642

-0.0803414064

3.5065578973

5.4772255751

0.6402069532

-0.1936796134

3.9120230054

7.7459666924

0.5050399983

-0.2966742251

4.605170186

9.4868329805

0.48542756

-0.3138755704

K promedio

1100 C

Time min

LN(1-R)

t^0,5

a= LN(1-R)/t^0,5

log a

0.4
0.58
0.65
0.84
0.87
0.89

5
10
15
30
60
90

0.5108256238

2.2360679775

0.2284481639

-0.6412123282

0.8675005677

3.1622776602

0.2743277665

-0.5617302323

1.0498221245

3.8729833462

0.271062907

-0.5669299085

1.8325814637

5.4772255751

0.3345820687

-0.4754973379

2.0402208285

7.7459666924

0.2633913764

-0.5793984482

2.2072749132

9.4868329805

0.2326672049

-0.6332648274

K promedio

1050 C

Time min

LN(1-R)

t^0,5

a= LN(1-R)/t^0,5

log a

0.17
0.35
0.44
0.56
0.68
0.77

5
10
15
30
60
90

0.1863295782

2.2360679775

0.0833291206

-1.0792032013

0.4307829161

3.1622776602

0.1362255192

-0.8657415282

0.5798184953

3.8729833462

0.1497084917

-0.824753565

0.8209805521

5.4772255751

0.1498898559

-0.824227758

1.1394342832

7.7459666924

0.1471003334

-0.8323863429

1.4696759701

9.4868329805

0.1549174496

-0.8098996614

K promedio

1000 C

Time min

LN(1-R)

t^0,5

a= LN(1-R)/t^0,5

log a

0.1
0.2
0.29
0.37
0.5
0.55

5
10
15
30
60
90

0.1053605157

2.2360679775

0.047118655

-1.3268071147

0.2231435513

3.1622776602

0.0705641867

-1.1514156594

0.3424903089

3.8729833462

0.0884306175

-1.0533973423

0.4620354596

5.4772255751

0.0843557479

-1.07388532

0.6931471806

7.7459666924

0.0894849162

-1.0482501641

0.7985076962

9.4868329805

0.0841701016

-1.0748421484

K promedio

950 C

Time min

LN(1-R)

t^0,5

a= LN(1-R)/t^0,5

log a

0.1
0.13
0.15
0.2
0.3
0.37

5
10
15
30
60
90

0.1053605157

2.2360679775

0.047118655

-1.3268071147

0.1392620673

3.1622776602

0.0440385324

-1.356167162

0.1625189295

3.8729833462

0.0419622072

-1.3771416765

0.2231435513

5.4772255751

0.0407402522

-1.3899762868

0.3566749439

7.7459666924

0.0460465373

-1.3368030235

0.4620354596

9.4868329805

0.0487028137

-1.3124459473

K promedio

900 C

Time min

LN(1-R)

t^0,5

a= LN(1-R)/t^0,5

log a

0.01
0.05
0.1

5
10
15

0.0100503359

2.2360679775

0.0044946468

-2.3473044273

0.0512932944

3.1622776602

0.0162203639

-1.7899394068

0.1053605157

3.8729833462

0.0272039682

-1.565367742

0.11
0.13
0.14

30
60
90

0.1165338163

5.4772255751

0.0212760666

-1.6721086584

0.1392620673

7.7459666924

0.0179786556

-1.7452427872

0.1508228897

9.4868329805

0.0158981285

-1.7986539972

K promedio

800 C

Time min

LN(1-R)

t^0,5

a= LN(1-R)/t^0,5

log a

0.01
0.015
0.02
0.03
0.04
0.045

5
10
15
30
60
90

0.0100503359

2.2360679775

0.0044946468

-2.3473044273

0.0151136378

3.1622776602

0.0047793519

-2.3206309896

0.0202027073

3.8729833462

0.0052163166

-2.2826360574

0.0304592075

5.4772255751

0.005561065

-2.2548420281

0.0408219945

7.7459666924

0.0052700968

-2.2781814051

0.0460439385

9.4868329805

0.0048534573

-2.3139487895

K promedio

1
f(x) = - 1.01639185553197E-007x^4 + 1.9688230658884E-005x^3 - 0.00125
R = 0.984626381
0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.4

0.3

0.2

0.1

10

20

30

40
50
60
tiempo (min)

70

80

90

(log a )/ 0.5

-0.1427804062

0.7198128474

-0.1015337251

0.7915279861

-0.1606828127

0.6907441051

-0.3873592267

0.4098649429

-0.5933484502

0.2550653999

-0.6277511407

0.235639916

0.7556704168
(log a )/ 0.5

-1.2824246564

0.05219

-1.1234604647

0.07526

-1.1338598169

0.07348

-0.9509946758

0.11195

-1.1587968965

0.06938

-1.2665296548

0.05413

0.07191
(log a )/ 0.5

-2.1584064027

0.0069437423

-1.7314830564

0.0185573921

-1.64950713

0.0224126325

-1.6484555159

0.0224669689

-1.6647726857

0.0216385081

-1.6197993228

0.0239994162

0.0218149836
(log a )/ 0.5

-2.6536142294

0.0022201677

-2.3028313189

0.0049793044

-2.1067946845

0.0078199741

-2.1477706399

0.0071158922

-2.0965003283

0.0080075502

-2.1496842968

0.007084606

0.0062045824
(log a )/ 0.5

-2.6536142294

0.0022201677

-2.7123343241

0.0019393923

-2.7542833531

0.0017608268

-2.7799525736

0.0016597681

-2.6736060471

0.0021202836

-2.6248918946

0.0023719641

0.0020120671
(log a )/ 0.5

-4.6946088546 2.0201850E-005
-3.5798788137

0.0002631002

-3.1307354841

0.0007400559

-3.3442173167

0.000452671

-3.4904855745

0.0003232321

-3.5973079944

0.0002527505

0.0003420019
(log a )/ 0.5

-4.6946088546 2.0201850E-005
-4.6412619792 2.2842205E-005
-4.5652721148

0.00002721

-4.5096840562 3.0925444E-005
-4.5563628102 2.7773921E-005
-4.6278975791

0.000023556

2.54182E-005

884E-005x^3 - 0.0012581048x^2 + 0.0307499094x + 0.7289604469

1200 C
Polynomial (1200 C)
1100 C
1050 C
1000 C
950 C
900 C
800 C

800 C

70

80

90

100

R
1200 C

Time min

LN(1-R)

Ln(-ln(1-r))

ln t

0.85
0.94
0.96
0.97
0.98
0.99

5
10
15
30
60
90

1.8971199849

0.6403369388

1.6094379124

2.8134107168

1.0343975255

2.302585093

3.2188758249

1.1690321759

2.7080502011

3.5065578973

1.2546349003

3.4011973817

3.9120230054

1.3640546329

4.0943445622

4.605170186

1.5271796258

4.4998096703

1100 C

Time min

LN(1-R)

Ln(-ln(1-r))

ln t

0.4
0.58
0.65
0.84
0.87
0.89

5
10
15
30
60
90

0.5108256238

-0.6717269921

1.6094379124

0.8675005677

-0.1421391127

2.302585093

1.0498221245

0.0486207446

2.7080502011

1.8325814637

0.6057256088

3.4011973817

2.0402208285

0.7130580513

4.0943445622

2.2072749132

0.7917586837

4.4998096703

1050 C

Time min

LN(1-R)

Ln(-ln(1-r))

ln t

0.17
0.35
0.44
0.56
0.68
0.77

5
10
15
30
60
90

0.1863295782

-1.6802382475

1.6094379124

0.4307829161

-0.8421509907

2.302585093

0.5798184953

-0.5450401636

2.7080502011

0.8209805521

-0.1972558579

3.4011973817

1.1394342832

0.1305318964

4.0943445622

1.4696759701

0.385041948

4.4998096703

1000 C

Time min

LN(1-R)

Ln(-ln(1-r))

ln t

0.1
0.2
0.29
0.37
0.5
0.55

5
10
15
30
60
90

0.1053605157

-2.2503673273

1.6094379124

0.2231435513

-1.4999399868

2.302585093

0.3424903089

-1.0715119167

2.7080502011

950 C

Time min

LN(1-R)

Ln(-ln(1-r))

ln t

0.1
0.13
0.15
0.2
0.3
0.37

5
10
15
30
60
90

0.1053605157

-2.2503673273

1.6094379124

0.1392620673

-1.9713977444

2.302585093

0.1625189295

-1.8169607948

2.7080502011

0.2231435513

-1.4999399868

3.4011973817

0.3566749439

-1.0309304332

4.0943445622

0.4620354596

-0.7721136385

4.4998096703

900 C

Time min

LN(1-R)

Ln(-ln(1-r))

ln t

0.01
0.05
0.1

5
10
15

0.0100503359

-4.6001492268

1.6094379124

0.4620354596

-0.7721136385

3.4011973817

0.6931471806

-0.3665129206

4.0943445622

0.7985076962

-0.225010673

4.4998096703

0.0512932944

-2.970195249

2.302585093

0.1053605157

-2.2503673273

2.7080502011

0.11
0.13
0.14

30
60
90

800 C

Time min

LN(1-R)

Ln(-ln(1-r))

ln t

0.01
0.015
0.02
0.03
0.04
0.045

5
10
15
30
60
90

0.0100503359

-4.6001492268

1.6094379124

0.1165338163

-2.1495737798

3.4011973817

0.1392620673

-1.9713977444

4.0943445622

0.1508228897

-1.8916490462

4.4998096703

0.0151136378

-4.1921577765

2.302585093

0.0202027073

-3.9019386579

2.7080502011

0.0304592075

-3.4913669501

3.4011973817

0.0408219945

-3.1985342614

4.0943445622

0.0460439385

-3.0781591536

4.4998096703

Ln(-ln(1-R))

f(x) = 0.2671867539x + 0.3359734783

R = 0.9166682859
1
f(x) = 0.5110393501x - 1.3613196032
R = 0.9436671869
f(x) = 0.6621509362x - 2.5125553981
R = 0.9562217549

0
1

-1

-2

-3

-4

-5

1.5

2
2.5
f(x) = 0.6734219468x
- 3.1202486812
R = 0.95713857

f(x) = 0.5131811206x - 3.1491324158

R = 0.9859035609
f(x) = 0.8086389758x - 5.1477484059
R = 0.7393882076

f(x) = 0.5365058108x - 5.4082649356

R = 0.9875141485

3.

-5

3.5

ln t

4.5

5
1200 C
Linear (1200
C)
Linear (1200
C)
1100 C
Linear (1100
C)
1050 C
Linear (1050
C)
1000 C
Linear (1000
C)
950 C
Linear (950
C)
900 C
Linear (900
C)
800 C

800 C

Ea = 85

kcal/mol

R
8.5
8.5
8.5
8.5
8.5
8.5
8.5
8.5

f(x) = - 4.25166141
0.0000 R = 0.9983650884
6.5
7.0

-2.0000

-4.0000

-6.0000

-8.0000

-10.0000

-12.0000

T (C)

T (K)

Constante de Equilibrio Keq

ln k

Ea/R

800
900
950
1000
1050
1100
1200
1300

1073
1173
1223
1273
1323
1373
1473

0.0000154
0.000342
0.00199
0.00775
0.0217
0.0702
0.774

-11.0811
-7.9807
-6.2196
-4.8601
-3.8304
-2.6564
-0.2562

-10000.0000
-10000.0000
-10000.0000
-10000.0000
-10000.0000
-10000.0000
-10000.0000

f(x) = - 4.2516614123x + 28.4450284567

0.0000 R = 0.9983650884
6.5
7.0
7.5

8.0

8.5

9.0

9.5

-2.0000

-4.0000

Col
-6.0000

-8.0000

-10.0000

-12.0000

1/T
0.0009
0.0009
0.0008
0.0008
0.0008
0.0007
0.0007

9.0

-9.3197
-8.5251
-8.1766
-7.8555
-7.5586
-7.2833
-6.7889

9.5

Column H

lnk

1/T*10000

-20.4008
-16.5058
-14.3962
-12.7155
-11.3890
-9.9397
-7.0450

9.3
8.5
8.2
7.9
7.6
7.3
6.8

lnk=
T (C)

T (K)

800

1073

T (C)

T (K)

850

1123

T (C)

T (K)

900

1173

T (C)

T (K)

950

1223

T (C)

T (K)

1000

1273

T (C)

T (K)

1050

1323

1/T

lnk

0.000931966 -11.1794175 1.39586E-005

1/T

lnk

0.000890472 -9.4151959 8.14765E-005

1/T

lnk

0.000852515 -7.80137681 0.0004091712

1/T

lnk

0.000817661 -6.31951349 0.0018008194

1/T

lnk

0.000785546 -4.95405734 0.0070547273

1/T

lnk

0.000755858 -3.69181028 0.0249268366

28.445
t (min)
5
10
15
30
60
90

t (min)
5
10
15
30
60
90

t (min)
5
10
15
30
60
90

t (min)
5
10
15
30
60
90

t (min)
5
10
15
30
60
90

t (min)
5
10
15
30
60
90

T (C)

T (K)

1100

1373

T (C)

T (K)

1150

1423

T (C)

T (K)

1200

1473

T (C)

T (K)

1250

1523

T (C)

T (K)

1300

1573

1.00000000

0.90000000

1/T

lnk

0.000728332 -2.52149672 0.0803392711

1/T

lnk

0.000702741 -1.43342586 0.2384904859

1/T

lnk

0.000678887 -0.41922267 0.6575577574

1/T

lnk

0.000656599 0.52838805 1.6961959206

1/T

lnk

0.000635728 1.415756516 4.119601833

t (min)
5
10
15
30
60
90

t (min)
5
10
15
30
60
90

t (min)
5
10
15
30
60
90

t (min)
5
10
15
30
60
90

t (min)
5
10
15
30
60
90

1.00000000

0.90000000

0.80000000

0.70000000

0.60000000

0.50000000

0.40000000

0.30000000

0.20000000

0.10000000

0.00000000
0

10

20

30

40

50

60

70

-4.2517 *(1/T)*10000

k*t

(k*T)0.5

1-R

6.97928E-005
0.0001395856
0.0002093784
0.0004187568
0.0008375137
0.0012562705

0.008354209
0.011814636
0.014469914
0.020463549
0.028939829
0.035443907

0.99168059
0.98825488
0.98563427
0.97974441
0.97147492
0.96517687

0.00831941
0.01174512
0.01436573
0.02025559
0.02852508
0.03482313

k*t

(k*T)0.5

1-R

0.0004073825
0.000814765
0.0012221475
0.002444295
0.0048885901
0.0073328851

0.020183719
0.028544089
0.034959227
0.049439812
0.069918453
0.085632267

0.98001861
0.97185944
0.96564479
0.95176244
0.93246986
0.91793172

0.01998139
0.02814056
0.03435521
0.04823756
0.06753014
0.08206828

k*t

(k*T)0.5

1-R

0.0020458562
0.0040917124
0.0061375686
0.0122751372
0.0245502744
0.0368254115

0.045231142
0.063966494
0.078342636
0.110793218
0.156685272
0.191899483

0.95577654
0.93803643
0.92464755
0.89512383
0.85497310
0.82538983

0.04422346
0.06196357
0.07535245
0.10487617
0.14502690
0.17461017

k*t

(k*T)0.5

1-R

0.009004097
0.0180081941
0.0270122911
0.0540245822
0.1080491644
0.1620737467

0.094889921
0.134194613
0.164354164
0.232431887
0.328708327
0.402583838

0.90947304
0.87441987
0.84844148
0.79260373
0.71985295
0.66859028

0.09052696
0.12558013
0.15155852
0.20739627
0.28014705
0.33140972

k*t

(k*T)0.5

1-R

0.0352736366
0.0705472732
0.1058209098
0.2116418196
0.4232836393
0.6349254589

0.18781277
0.265607367
0.32530126
0.460045454
0.65060252
0.7968221

0.82876986
0.76674012
0.72230972
0.63125495
0.52173133
0.45075916

0.17123014
0.23325988
0.27769028
0.36874505
0.47826867
0.54924084

k*t

(k*T)0.5

1-R

0.1246341831
0.2492683663
0.3739025494
0.7478050988
1.4956101977
2.2434152965

0.353035668
0.49926783
0.611475714
0.864757249
1.222951429
1.497803491

0.70255213
0.60697491
0.54254963
0.42115378
0.29436010
0.22362081

0.29744787
0.39302509
0.45745037
0.57884622
0.70563990
0.77637919

k*t

(k*T)0.5

1-R

0.4016963556
0.8033927112
1.2050890668
2.4101781337
4.8203562673
7.230534401

0.6337952
0.896321768
1.097765488
1.552474842
2.195530976
2.688965303

0.53057434
0.40806787
0.33361572
0.21172334
0.11129945
0.06795121

0.46942566
0.59193213
0.66638428
0.78827666
0.88870055
0.93204879

k*t

(k*T)0.5

1-R

1.1924524295
2.384904859
3.5773572885
7.154714577
14.309429154
21.464143731

1.091994702
1.544313718
1.891390306
2.674829822
3.782780611
4.632941153

0.33554651
0.21345831
0.15086192
0.06891856
0.02275932
0.00972611

0.66445349
0.78654169
0.84913808
0.93108144
0.97724068
0.99027389

k*t

(k*T)0.5

1-R

3.2877887871
6.5755775741
9.8633663612
19.726732722
39.453465445
59.180198167

1.813226072
2.564288902
3.140599682
4.441478664
6.281199364
7.692866707

0.16312703
0.07697390
0.04325685
0.01177851
0.00187116
0.00045607

0.83687297
0.92302610
0.95674315
0.98822149
0.99812884
0.99954393

k*t

(k*T)0.5

1-R

8.4809796028
16.961959206
25.442938809
50.885877617
101.77175523
152.65763285

2.912212149
4.118489918
5.044099405
7.133433789
10.08819881
12.35546975

0.05435535
0.01626906
0.00644726
0.00079797
0.00004157
0.00000431

0.94564465
0.98373094
0.99355274
0.99920203
0.99995843
0.99999569

k*t

(k*T)0.5

1-R

20.598009165
41.19601833
61.794027495
123.58805499
247.17610998
370.76416497

4.538502965
6.418412446
7.860917726
11.11701646
15.72183545
19.25523734

0.01068940
0.00163124
0.00038552
0.00001486
0.00000015
0.00000000

0.98931060
0.99836876
0.99961448
0.99998514
0.99999985
1.00000000

80
0
85
0
90
0
95
0
10
00
10
50
11
00

60

70

80

90

100