www.Padasalai.

Net

www.Padasalai.Net

-II

E = h

h =

E = mc2

m
c

h = mc2

c
=

c
h = mc 2

hc
=
mc 2
h
=
mc

c v-

h
mv

h
= p

www.Padasalai.Net

2
2
'N'1s 2s 2px12py12pz1.
N2

N 2 : KK ( 2s ) ( *2s ) 2px
2

2 ( N

) ( ) ( )
2

2p y

Na )

2 ( 8 2 ) = 2 ( 6 ) = 3
1

2p z

www.Padasalai.Net

w dhf

s, p d

www.Padasalai.Net

II

ns2np6

Be, Mg 2s2

XA = XB
(or)

AB

H2
H H

XA XB = 0
XA > XB

(H 2O) OH
O H+

XA >> XB

NaCl

Na Cl
+

www.Padasalai.Net

w dhf

[]

[]

[ ]

[]

www.Padasalai.Net

3. p

173 K

Xe, Kr, Ar

Ne, He

93 K

Ne

He

Ar

Kr, Xe

183 K

Xe

Kr

Xe, Kr, Ar

www.Padasalai.Net

(i)
(ii)
(i)

P2 O5
H2SO4
SO3
-H O
2

P2 O5
2HNO3
N2 O5
-H O
2

(ii)

F2 + 2x-
2F- + x2 (x- = Cl-, Br-, r-)
F2 + 2Cl-
2F- + Cl2

www.Padasalai.Net

w dhf

[]

[]

[ ]

AX, AX 3 , AX 5

[]

(i)
(ii)
(i)

(a) P2O3
(b) P2O5
(c) PCl3
(d) PCl5
(e) PH3

[ ]

AX 7

[ ]

www.Padasalai.Net

4.d

ZnS

1200K

2ZnS + 3O2

1200 K

2ZnO + 2SO2

K ZnO

ZnO + C

1673K

Zn + CO

10

www.Padasalai.Net

w dhf

[]

[]

[]

Cr
Cr2O3 [ ]

d-

11

www.Padasalai.Net

5. f

H2SO4
210oC

SiO2, TiO2, ZrSiO4

(Ln3+, Th4+, H3O+, HSO4-,

SO42-, H2PO4-)
HF

Th 3 (PO4)4

Th-

NaOH

12

www.Padasalai.Net

w dhf

[ ]

[]

[]

[]

13

www.Padasalai.Net

1.

[Co(NH3)6]Cl3

IUPAC

[Co(NH3)6]Cl3

[Co(NH 3)6]Cl3

1.

IUPAC

(III)

2.

NH 3

3.

Co 3+

4.

5.

[Co(NH 3)6] 3+

14

www.Padasalai.Net

w dhf

[]

[ ]

[ ]
2
Ni ( CN )4
2+
Ni ( NH 3 )4

[]
44[FeF6 ] Fe ( CN )6
(VB)

4 (i) [ FeF6 ]4- (ii) Fe ( CN )6

[ ]
Cu ( NH3 ) 4 SO4
K 4 Fe ( CN )6

IUPAC

[]

[]

[]

[]
(i) (ii) (iii)
(i)

[]

15

www.Padasalai.Net

16

www.Padasalai.Net

w dhf

[ ]

[]

[]

[ ]

[]

[]

[ ]

[ ]

17

www.Padasalai.Net

II

Na+
Cl

Cl-

Na+

AgBr

18

www.Padasalai.Net

Ag +

Ag+ Br- Ag+ Br- Ag+ Br- Ag+ Br- Ag+

Br- Ag + Br- Ag + Br- Ag + Br- Ag+ BrAg+ Br-

Ag+

Br- Ag + Br- Ag+ Br- Ag+

Br- Ag + Br- Ag + Br- Ag + Br- Ag+ Br-

w dhf

[ ]

[ ]

[]

(or)

[]

AB AB2

19

www.Padasalai.Net

II

100

100

T1 > T2

T1 - T2

T 100
1

T2 -
T1 -

20

www.Padasalai.Net

w dhf

(S)
[ ]

G
[ ]

[ ]

21

www.Padasalai.Net

II

SO3

:
2SO2(g) + O2(g)

V2O5

2SO3(g) H0f = 47 Kcal / mole

:
SO2 O2 2 : 1 700-1200 atm

:400 450C
: V2O5
: 97% SO3
H :47
:

22

www.Padasalai.Net

w dhf
n

1.

K c (RT) g
Kp Kc
[]

PCl5

Kc K p

[]

HI

N 2O 4(g)
2NO 2(g) , H = +59.0KJ/mol

[ ]

[]

Kp =

Kc Kp

23

[ ]

www.Padasalai.Net

i)
ii)
iii)
iv)

n
n

1.

t1 =
u

2.303
a
log
a
k1
a
u

t1 =
u

2.303
u
log
k1
( u1)

w dhf

[]

k = Ae Ea / RT

i ii
iii

[]

[]

24

www.Padasalai.Net

[]

[ ]

%
%

[ ]

[ ]

(A) C
sec1
%

25

www.Padasalai.Net

A(g) + B(g)

tpidNtfkhw; wp

(g)

+ D(g)

A B

D
C
C D

26

www.Padasalai.Net

w dhf

[ ]

i)
ii)

i)
[ ]
ii)
iii)
[ ]

[]


[]

[]
i)
ii)

[]

[]

[]

[]

27

www.Padasalai.Net

HA- NaA-

NaA-
Na+ + ANaA

HA-
H + + A-

HA
Ka =
[H +] =

H + A -
[ HA ]

[HA ] K a

(1)

A -

[HA]
[A]
[H +] = Ka

[ ]
[ ]

(2)

log[H+] = log Ka log

[ ]
[ ]

(3)

log[H+] = pH

(4)

log Ka = pKa

(5)

pH = pKa log

pH = pKa + log

[ ]
[ ]

[ ]

[ ]

28

www.Padasalai.Net

pH = pKb + log

[ ]
[ ]

w dhf

[ ]

[]

[ ]

[]

[]

[]

29

[ ]

www.Padasalai.Net

II

Zn (S ) + Cu (2+aq )
Zn (2+aq ) + Cu (S )

Zn(S)
Zn(2+aq ) + 2e-

Zn
Cu 2+ Cu

Cu (2+aq ) + 2e -
Cu ( S)

e-

e-

Zn

Cu

(-)

(+)

Zn2+

So 2+
Cu2+
4

ZnSO4

CuSO4

30

www.Padasalai.Net

Zn 2+
Cu2+
Cu

w dhf

IUPAC

[]

EMF-
[ ]

[]

emf
[]

(SHF)

[ ]

[ ]

31

www.Padasalai.Net

H2 SO 4 413K

C2 H 5 O H + HO C2H5

2
4

C2H5OC2H5+H2O
413K

con.H SO

C2H5 O C2H5 + NaBr

C 2 H 5 Br + Na O C2H5

C2 H 5 I

+
C2 H 5 I

+ Ag2O

C2H5 O C2H5 + 2AgI

32

www.Padasalai.Net

w dhf

[ ]

[]
i) Cl2
ii) O2
iii) H2SO4

[]

HI
[ ]

[]

C4H10

33

www.Padasalai.Net

18.

NaOH

H
NaOH

CH3

C +H

CH2

CHO

CH

CH3

CH2

CHO

OH

CH2

CHO

OH

CH2

CHO + H2O

H
CH3

C + CH2

CH3

CHO

CH2

CHO

H
CH3

CH2

CHO

OH

CH3

CH
OH

34

CH2

CHO

www.Padasalai.Net

w dhf

[]

[ ]

[ ]

[ ]

[]

[]

[]

(i)

[ ]

(ii)
[ ]

35

www.Padasalai.Net

-S -

-S

Na
nCH2 = CH CH = CH2 + nCH = CH2
-( CH2 CH = CH CH2 CH CH2 )n|
|
C 6H 5
C6H5

- S

O
O
||
||
nH2N(CH2)6NH2 + nHO C (CH2)4 C OH

H
H O
O
|
|
||
||
-(- N (CH2)6 N C (CH2)4 C)n

36

www.Padasalai.Net

w dhf

[]

[]

[]

[]

[]

37

www.Padasalai.Net

1 & 3 Mark Questions & Answers

5 & 10 Mark Questions & Answers
Q-70 Compulsory Problems
Question Bank

For Gem Complete Material

Contact: Sumathi Gunaseelan, Trichy
: 9080228421

38