Kendriya Vi a, Ashok nagar, Chennai -83 2011-2012 Half-Yearly Examination Sub:Chemistry Class:42 Time: 3 hours” Maximum marks:70 BAH. 0S M € 1) Calculate the mass percent of sodium in Na,SO, (Na=23; $=32; O=16). 2) Using s,p,d notation describe the orbital with the following quantum 12. (yh numbers: n=: 3) Explain why cations are smaller than anions? 4) Calculate the bond order of Hy aoe @ : at a eon 5) What is Boyle point? a, oO oe 6) Define lattice enthalpy. 7) What are trans-uranium elements? 8) What areisochores and/iso-bafs? 2m = ao v 9} Determine the empirical formula of sn oxide of iron which nas ga Fe and 30.1% of O. (Fe= 56, O = 16) a ot & 10) Calculate the concentration of nitric acid in moles per litre which has a density of 1.41g/ml. Mass ese nitric acid is 69%. Oath § cod 11) What is the SI unit of mass? How is it defined. (@) 12) Draw the boundary surface diagrams of all the d-orbitals. 13) If the velocity of the electron in Bohr's first orbit is 2.19x10° m/s, Calculate the de-Broglie wavelength associated with itoe & AY ws ye 14) a. Predict the formula ofthe binary compound formed between Mg and N. . Explain why Be has higher ionisation enthalpy than B. @ 15) Describe the change in hybridisation of Al atom in the reaction: X AlCl, + Cl’ > AlCl g 16) Distinguish between 9 and n bonds. 17) Caleulate the volume occupied by 8.8g of CO, at 31.1°C anc\t'bar Ssure. BS 4 0d R =0,083 bar LK? mol” 2 @ Z fer) @ Le 4S 2°“ O%Calculate the temperature of 4 mol of a gas occupying S dm? at 3.32 bar. R =.083 bar dm? K* mol”. 18) ina process, 701 J of heat is absorbed by a system and 394 J of work is done by the system. What is the change in internal energy for the re es wo) © pe” ae . A ov oy 3m \ wR 19} a) Why do liquids boil at lower temperature’at high altitude? a b) What happens in a liquid at critical temperaturd?+V c) Viscosity of a liquid decreases as temperature fereases. Why? qerd? 20) Derive a relationship between molar mass ahd defsity of a gaseous substance using ideal gas equation. oe Fp) Draw the shape of BCI; according to VSEPRT. QV D Pp a e At , =O b) Which hybridisation is undergone bysne carbon atoms in HCHO. TCD) \ pen ene \e What is the total number of o“and-70 bonds in CoH2- Sas ce 22) For the reaction : 2A, + Bay > 2D AUB= -105 KI and ASB= -44.1 JK". Calculate AGB for the reaction, and gs predict whether fineréattion may occur spontaneously. Be 5 4abH a ie ; A ») = X Sh = (> oat ash an é we ees ; & ) vos ee ) Za 5 “Oe ay)Cw 3) a) Define H-bond. a yw b) What are the two types of H-bonds. Give one Ee. a 24) Define fonisation enthipy. Why is the Second ionisation enthalpy greater than the frst ionisation enthalpy. Why N atom hapbih fonsation enthalpy? 25) Briefly describe a) noble gases _b) chalcogeNs” ¢) transition elements 26) a)Give the electronic configuration of Cu» (Cu= 29). byIf n=3, give the possible values of Azimuthal Quantum number and Magnetic Quantum number. Uncertainty 27) Define Hund rule, Paul's Exclusion Principle and Heisenbe Principle. ) 5m a 28) a) Derive the relationship between C, and C,. (3m) Na b) Explain open and isolated gee giving examples. (2m) (oR) Me cys The combustion of one mole of benzene produces CO2% and H:Ove along with 3267 KI of heat. Calculate the standard enthalpy of formation of benzene. Given: Std enthalpy of formation of COz) and H2Ojiq) are - 393.5 Kimo!” and - 285.83KImol" respt. 69) ~ 7 (Q ide 29) a) Explain with example solid liquid equilibrium and solid-vapour equilibrium’ with examples. (2m quilibriv ples. (2m) ; pr b) Give one example each for homoapopys sand eee (am) (Q ¢) Calculate K, for the reaction PCls€> PCls + Cl. Given: Concentrations of PCls, PCl, Cl are 1.41 M, 1.59 Mand 1.59 M respt at equilibrium. (tem),Derive the relationship between Kp and K, and give two general characteristics of physical equilibrium. ‘hateliers Principle. Discuss the effect of change in 30) a) Define Le C! um reaction involving NHs formation. temperature and catalyst on the equilib (3m) b) Write the conjugate acid and conjugate base of H0. (1m) c) Why is NH3 a Lewis Base and BC; a Lewis Acid? (2m) (OR) when [Hx0°}= 24x10 M_ (2m) a) Calculate pH tion constant K, of weak acid and ) Derive the relationship between ionisat degree of dissociation a. (3m) @ —_ iesArte aroun - 8 \\ \ KENDRIYA VIDYALAYA SANGATHAN (CHENNAI REGION) COMMON SESSION ENDING EXAMINATIONS 2009-2010 Class: XL Time: 3Hrs Sub:Chemistry Max marks: 70 ‘neral In: ictions: 1. All questions are compulsory. 2, Marks for each questions are indicated against it. 3. Question Nos 1-8 are very short-answer questions and carry I mark each. 4. Question Nos 9-18 are short-answer questions and carry 2 marks each. 5. Question Nos 19-27 are short-answer questions and carry 3 marks each. & Question Nos 28-30 are long-answer questions and carry 5 marks each, 7._Use log tabtes if necessary. Use of caleutators is prohibited, 4, How many significant figures are present in the following @ 2) 0.0025") 2.0034 2, _Cteulate the frequeney of yellow radiation having wavelength 58004". a What isthe basie difference between electron gain enthalpy and electronegativity? «® 4 “Compressibility factor’, a 5. among the following is an extensive property? a) +A 8. Internal energy and Temperatnre. Bs. Whai are poly protic acids? Give one example, ww 7. couple with an example. ap © May are satine hydrides ionie in nature? a Calculate the molecular weight and empirical Weight of a compound conta hydrogen, 24.27% of earbon gin/mol(Aawt of H ing 4.07% of 1d 71-67% of chlorine, Its molecular weight is 98.96 5) Q) WAG is octet rule? Enumerate the violation of octet rule with suitable examples, Q)19, Graphically show the enthalpy diagrams for endothermic and exothermic reactions. (2) ‘The concentration of hydrogen ion in a sample of soda water is 3.8x10° M. Calculate its pH. Q) Balance the following redox reaction in acistie medium Q) C1207? ag + SOS ug) 2 CP gy #802 up Give renetions to prove that HO; can act as oxidising and reducing agent in aciaie medium Q) e any four points of similarity between Li & Mg due to diagonal eaeaauey 2) Give reason for the following: a) Lead di oxide is a powerful oxidising agent, b) BF; is a good Lewis acid. Q) Calculate the number of sigma and pi bonds in a) formaldehyde b) benzoic acid Q) a) Write the [UPAC name of tertiary butyl aleohol b) Draw the structure of Hexane-2, 4-dione Q) (or) Explain homolytic and heterolytic cleavage with example 2) Give the general electronic contiguration of ‘£7 block elements a) b) Account for the following: i) Zn, Cd, Hg are not considered to be tran: . ii) Size of the eation is alw: rent atom (en EXplain sp, sp? and_sp® hybridization with one example each (14141) a) At 25" C and 760mm of Hg pressure a gas occupies 600ml volume. What will be its " cssure at a height where the temperature is 10” C and volume of the gas is 640 ml. (2) —“b) Why ideal gas equation is called ‘equation of state’? a) a) Give Hess’s law of constant heat summation. a b) The equilibrium constant for a reaction is 10.What will be the value of ac’? « (R= 8314V/K ,T = 300K) @ 1) State Lechatliers’ principle. a 1) Give the conditions for the maximum yield of ammonia by Habers’ process Q) Explain the “Solvay process’ for the manufacture of sodium carbonate giving all the reactions involved. @ jor) ‘Write the chemical formulae and preparation of the following a) Plaster of Paris b) quick time c) staked (tet)Q) wm Explain the eclipsed & staggered confirmations of ethane according to Sawhorse & * Newman projection formulae, @) (a) Inhalation of ¢ i) b)Define Biochem a Ore (ty gyptaw the boundary surface diagrams of 3d or als. Q) ‘7 Explain any three rules for filling up of electrons in various orbitals ofan atom. (3) (or) \_ A) Hall filed and completely fitled orbitals are more stable Why is it so? Explain, Q) ») The quantum no of four electrons are given below. Arrange them in the increasing Srder of their energies identifying the orbitals @) Si a me 7 +12 i an 12 2 =i 4) Discuss the structure of Diborane Q) b) What happens, when- ) Con.HNOs is added to Aluminium foil. if) Borax is strongly heated. Bi) Boron triftouride reacts with Sodium hydride, 8) (or) What are silicones? How are they prepared? Mention their Properties and uses, (424141) 2) Explain the following name reactions with relevant chemical equations : H) Wurtz reaction“ tiyDecarboxylation —itiy Ozonolysis of alkenes (3) b) Draw the cis & trans isomers of ne ii) 34-dimethythey-3-ene Qy for) #) Explain the follow ing wit examples Cyclic polymerisation of alkenes iii) Friedal eraft’s alkylation (3) 7 How doo. Huckle's rate exptain the aromatie character of Organic compounds? (2) i) Markovnikovs ricpe Sheena maw pole KENDRIYA VIDYALAYA, CLRISCHENNAL-20 - UMULATIVE EXAMINATION, 2008-09 SUB:CHEMISTRY M.Marks : 70 Time’: 3hrs : AML questions are compulsory. 1 mark each, Question number I to 8 is very short answer questions, carryi Question number 9 (0 18 is short answer questions, carrying 2 marks each, Answer these about 30 words each. 4. Question number 19 to 27 is short answer questions, carrying 3 marks each, Answer these in about 40 words each. 5 ing § marks each. 5. Question number 28 to 30 are very long-answer questions, ¢: 6. Use log tables if necessary. .Use of Calculators is not permitted. 1) Which quantum number predicts shape of the orbital?” (7 .2.” Why is the ionization enthalpy of Be more than that of B uw 3. Write the lewis dot symbol of ‘F” atom 2 DIB) AU’ =- 10.5 KJ and AS 44,10JK Calculate AG’ for the reaction and predict whether the reaction may occur spontaneously. 1b) Give reasons for the following. j) The dissolution of ammonium chloride in water is endothermic still it dissolves in water. ii) A real crystal has more entropy than an ideal crystal (OR) a) Enthalpies of formation of CO (g) , CO 2 (g) No O (g) and N2Ox (g) are ~ 110, 393.81 and 9,7 KJmol ~! respectively. find the value of A ,H for the reactions, NOU(g) +3CO(Z). ——*_N.O(2) + 3C0 2(8) by) Predict in which of the followings entropy increases/ decreases.i) A liquid crystallizes into a solid 1i) Fa (g) 92H @). . 30, Describe the effect of 2) Addition of He 'b) Addition of CH s OH ©) Removal of CO d) Removal of CH;O1 e) Addition of both Hy, & CQ on the equilibrium of the reaction 24b(g)+CO(y + CH: OH) (OR) Which of the following reactions will get affested by increasing. pressure? Also mention whether the change will cause the reaction to go to forward or backward : directions? WCOCKY) Z COW+ChL) Gi)CHAg)+ 282 (QF CSA)H+2HLSE) Gi2COI+C(S) TH COA) trace COM) FP CaO (8) + CO 8? ig) CO ig ~” CH OB) penpeegeasesveeseenee sens CEOREREN TESS EHEEESEEESEE ONS LORELEI MTRS KENDRIYA VIDYALAYA SANGATHAN CHENNAI REGION F ASHOK NAGAR CLUSTER (\ Cumulative Examination — 2004 Class : XI Std. CHEMISTRY Marks : 70 . (THEORY) Time : 3 hrs. General Instructions 1, All questions are compulsory 2. Marks for each question are indicated against it. 3. Question numbers 1 to 5 are very short answer questions carrying 1 mark each. Answer these in ‘one word on about one sentence each. 4. Question numbers 6 to 12 are short answer questions carrying 2 marks each. Answer these in about 30 words each 5. Question numbers 13 to 24 are short answer questions of 3 marks each. Answer these in about 40 words each, 6. Question numbers 25 to 27 are long answer questions of § marks each. Answer these in about 70 words each 7. Use long tables if necessary. Use of calculators is not permitted 1, How many significant figures are there in each of the following numbers ? 1 L™ 3.524% 108 0.000217 2. Draw the lewis structure for ae a. SF, b. XeF, 1 3,_State Henry's law. 1 4. Write the solubility product expression for the following salts ? 1 a. Pb3 (AsO4)y b.AgCl 5. Complete the following 1 a. Ca; Ny + Hy O> b.BaO, +H,S0,—> A sample of CaO whose mass 12g, was treated with 0.46g of HO to prepare Ca(OH), 2 as Which compound was the limiting reactant ii) Calculate the theoretical yield of Ca(OH), ?2 . 7. How many atoms of Cl, are there in 25g Cl, 0, ? 2 8. A volume of CO, equal to 201 was collected at 23°c and 1 atm pressure. What would be the volume of CO, if it were collected at 23°c and 0.830 atm ? 2 9, Calculate mass of photon with wave length 3.6° ? 2 10.._-Bfscuss the factors that influence the magnitude of Ionisation Enthalpy ? 2 te What do you understand by the following terms i) acid base titration curve ii) equivalence point 2 J-42. Find the oxidation number of Clin HCI, HC1O, C10, , Ca (OCI) Cl 2 OR Find the oxidation number in each element in . Cr,0,?", Mn 0,7, Br Og", Fe (CN) 1B Explain removal of temporary and permanent hardness of water ? 3 “¥4. What is leaching ? How is silver ore concentrated by leaching process ? 3 15,, a. Give one acid buffer solution 3 eal b. The concentration of H* in a sample of soft drink is 3.8 « 10m what is its PH ? 16. _ The degree of ionisation of 0.1M bromo acetic acid is 0.132. Calculate PH of the solution ? and — pka of bromo acetic acid ? 3 17. Which of the following reaction will get affected by increase of pressure. Also mention whether this change will cause the reaction to go into right (or) left direction ? 3 i) CH yg) + 201g) = COzG) + 2H20) ii) COxg) + CG) + 2C% iii) 4NHy) +5 Ox(g) = 4NO (ey iv) Cy Hagy + Hogg) = CoHy@) asne 18H18. Page) = PCI(g) + Cl(g) Ar H= 124 kj/mol 3 The dissociation of PCls at 473k is represented as given under (3 How the value of kp and composition of equilibrium mixture be affected by i) increasing the pressure ii) increasing the temperature iii) using a catalyst plain giving reason CH, is tetrahedral in shape where as NH is trigonal pyramidal and write bond angle also Calculate bond energy of H-Cl 3 B.E (H-H) = 436 kj/mol B.E (CI-Cl) = 242 kj/mol AfH HCI =-91 kj/mol OR The combustion of 1 mole of benzene takes place at 298k and Latm. After combusion Co, and H,0 are produced & 3267 kj heat is liberated. Caleulate standard enthalpy of formation of benzene. Af H° H,O =-285.83 kj/mol Af H° CO, =-393.5 kj/mol 21,_ADsing Bomb calorimeter, how is internal energy change calculated ? a 22. i) Define Hess's law of heat summation. 3 <7) 60.8 J are required to change the temperature of 25g of ethylene Glycol by I k. Calculate 23. specific heat capacity. ji) What would be IUPAC name and symbol for the element with atomic number 120? 3 Write general configuration and properties off” block elements ? 24. Explain Dalton’s law of partial pressure. A 2.5L fask contains 0.25 mol each of SO,and No at 27°C. Calculate partial pressure exerted by each gas and also the total pressure 5 oe ASNe 11-PHY