S GD-T TUYN QUANG

Trng THPT Kim Xuyn

THI CHN HC SINH GII CP TNH

LP 12 THPT NM HC 2010-2011
Mn: HA HC
Thi gian lm bi: 180 pht
( khng k thi gian pht )

Cu 1: (3,5 im):
1/ Cho Al vo 200 ml dung dch cha HCl 0,8M v FeCl3 0,8M, sau khi phn ng xong
thu c 1,344 lt H2 ktc. Tnh khi lng mi mui thu c.
2/ Tin hnh in phn (vi in cc tr mng ngn xp) 500 ml dung dch HCl 0,01M
v NaCl 0,1M.
a) Nhn xt s thay i ca pH dung dch trong qu trnh in phn.
b) V th bin thin ca pH dung dch theo thi gian in phn, bit cng
dng in khng i bng 1,34A, hiu sut in phn100% v th tch dung dch
coi nh khng i trong qu trnh in phn.
Cu 2: (3 im):
1/ Mui X mu trng tan trong nc. Dung dch X khng phn ng vi H2SO4 long,
phn ng vi HCl cho kt ta trng tan trong dung dch NH3. Khi axit ha dung dch to
thnh bng dung dch HNO3 li c kt ta trng xut hin tr li. Cho Cu vo dung dch
X, them H2SO4 v un nng th c kh mu nu bay ra v c kt ta xut hin. Lp lun
xc nh cng thc ca X.
2/ ha tan NaNO3, Na2CO3 v NaHCO3 vo nc ta c dung dch A. hy nhn bit cc
anion c trong dung dch A.
3/ Hon thnh cc phn ng theo s sau:
D
+Mg
o
A
F O2 G
[O] Kh
NaOH H
E A
B ( t , xt , p ) C
+ HCl
E
Cu 3: (3 im):
Nung nng 18,56 gam hn hp A gm FeCO3v mt oxit st trong khng kh ti khi phn
ng xy ra hon ton thu c kh CO2 v 16 gam cht rn l mt oxit st duy nht. Cho
kh CO2 hp th ht vo 400 ml dung dch Ba(OH)2 0.15M thu c 7,88 gam kt ta.
1/ Xc nh cnh thc ca oxit st.
2/ Cho hn hp B gm 0,04 mol Cu v 0,01 mol oxit st trn vo 40 ml dung dch HCl
2M cho n khi phn ng xy ra hon ton ta thu c dung dch D. Cho dung dch D
phn ng vi lng d AgNO3.Tnh khi lng kt ta thu c.
Cu 4: (3 im):
1/ Cho 5 hp cht v c A,B,C,D.E
A,B,C,D,E u tc dng vi dung dch HCl v to ra H2O
Hn hp A,B,C,D,E tc dng vi dung dch HCl to ra dung dch X cha 2 cht
tan. Cho dung dch X tc dng vi dung dch NaOH d thu c kt ta Y. Nhit
phn trong khng kh n khi lng khng i ta thu c mt cht rn. Lp
lun xc nh cc cht A,B,C,D,E trn v vit cc phng trnh phn ng xy
ra. Bit:

 Hiu tng khi lng phn t ca X v Y bng 92,5

Tng khi lng phn t ca X v Y bng 486,5
2/ Hp cht v c X c to thnh t cc n cht A,B,C ph bin thuc chu k nh.
X tan nhiu trong nc, khng tc dng vi axit, baz, mui v khng thy phn.
o
X t
Y + Kh C
Y lm mt mu KMnO4 trong mi trng H2SO4
Lp lun xc nh A,B,C v X. Vit cc phn ng xy ra (A,B,C c khi lng tng
dn).
Cu 5: ( 3,5 im):
1/ Cho 4,82 gam mui kp c cng thc p(NH4)2SO4.qFex(SO4)y.tH2O ha vo nc ta
thu c dung dch A.
Nu cho a tc dng vi dung dch BaCl2 d thu c 4,66 gam kt ta.
Nu cho A tc dng vi dung dch Ba(OH)2 d un nng thu c kt ta B v 0,01
mol kh C. Nung B trong khng kh ti khi lng khng i thu c 5,46 gam cht
rn. Xc nh cng thc mui kp.
2/ xc nh nng Cu2+ t do c trong 500 ml dung dch c iu ch t 0,1 mol
CuSO4 v 2 mol NH3.
Bit [Cu(NH3)42+] c hng s bn l 2.1013 v cp NH4/NH3 c pKa = 9,2.
Cu 6: (4 im):
1/ Ngi ta tin hnh o tc u ca phn ng:
2NO + 2H2 N2 + H2 nhit To K theo thc nghim v kt qu c nghivaof
bng nh sau:
TN
[NO] ban u (mol.l-1)
[H2] ban u (mol.l-1) Tc u (mol.l-1).s-1
1
0,50
0,20
0,0048
2
0,50
0,10
0,0024
3
0,25
?
0,0012
4
0,50
1,0
?
Tnh hng s tc K ( l2.mol-2.s-1) v vit biu thc nh lng tc phn ng.
Xc nh tr s ca cc cn trng c nh du ?.
2/ Mt hn hp kh gm 1 mol N2 v 3 mol H2 c gia nhit ti 387oC. Ti p
sut 10 atm, hn hp cn bng cha 3,85% mol NH3. Xc nh Kp v Kc.
( Hc sinh c s dng bng h thng tun hon)
HT..
Ngi ra :
GV: Th Hoa
Trng THPT Kim Xuyn