VLE Data for Methyl E

X1
12.3
15.51
18.61
21.63
24.01
25.92
27.96
30.12
31.75
34.15
36.09

X2
0
0.0895
0.1981
0.3193
0.4232
0.5119
0.6096
0.7135
0.7934
0.9102
1

Y1
1
0.9105
0.8019
0.6807
0.5768
0.4881
0.3904
0.2865
0.2066
0.0898
0

Y2
0
0.2716
0.4565
0.5934
0.6815
0.744
0.805
0.8639
0.9048
0.959
1

F1
1
0.7284
0.5435
0.4066
0.3185
0.256
0.195
0.1361
0.0952
0.041
0

F2

0
4.212516
8.495465
12.83524
16.36282
19.28448
22.5078
26.02067
28.7274
32.74985
36.09

FID

12.3
11.297484
10.114535
8.794758
7.647185
6.63552
5.4522
4.099332
3.0226
1.40015
0

0
0.37702
1.682952
4.098293
6.924743
9.871725
13.72075
18.56575
22.79232
29.80891
36.09

40
35
30
25
P/kPa

20
p-x1

15

P-y1

10
5
0
0

0.2

0.4

0.6
x1,y1

0.8

1.2

Methyl Ethyl Ketone(1)/Toluene(2) at 50 C

gama1
1.304162
1.188272
1.113828
1.071335
1.043845
1.02306
1.010503
1.003269
0.996978
1

gama2

ln gama1 ln gama2

1
1.00878
1.025464
1.05042
1.077882
1.105251
1.135421
1.163278
1.189447
1.267632

0
0.00874216
0.0251456
0.0491902
0.07499804
0.10007275
0.12700336
0.15124151
0.17348885
0.23715042

GE/X1X2RT

0
0.031727
0.054337
0.067905
0.07242
0.070812
0.06348
0.050785
0.038432
0.018541
0

A12
0.3844

0.389342746
0.342047989
0.312427206
0.29667902
0.283406714
0.266736312
0.248439591
0.234460417
0.226844767

0.5

Column N

0.4

Linear (Column
N)
f(x) = - 0.1880868155x + 0.3844107772
R = 0.9587094211

0.3
Axis Title

0.265561
0.1725
0.107803
0.068906
0.042911
0.022798
0.010448
0.003263
-0.003027
0

GE/RT

Column M
Column L
Column K

0.2

Column R
Column S

0.1

Column T
Column Q

0
0

0.2

0.4

0.6
x

0.8

1.2

A21
GE/RT
GE/X1X2RT ln gama1
ln gama2
0.1963
0
0.3844
0.3844
0
0.02995278 0.36756505 0.265560929 0.008742163
0.05514499 0.34713739 0.172499998 0.025145603
0.07049442 0.32433967 0.107803029 0.049190198
0.07440126 0.30479608 0.068905962 0.074998037
0.0719871 0.28811161 0.042910794 0.100072751
0.06419347 0.26973424 0.022798372 0.127003359
0.05114341 0.25019065 0.010448169 0.151241514
0.03854683 0.23516146 0.003263323 0.173488848
0.0174254 0.21319138 -0.00302651
0.1963
0
0.1963
0
0.1963

olumn N

near (Column
)

P
15.79
17.51
18.15
19.3
19.89
21.37
24.95
29.82
34.8
42.1
60.38
65.39
69.36
80

olumn M

70

olumn L

olumn K

60

olumn R

50

olumn S

olumn T

olumn Q

p/kPa

40
30
20
10
0

VLE Data for Chlorofo

X1

X2
0
0.0932
0.1248
0.1757
0.2
0.2626
0.3615
0.475
0.5555
0.6718
0.878
0.9398
1

Y1
1
0.9068
0.8752
0.8243
0.8
0.7374
0.6385
0.525
0.4445
0.3282
0.122
0.0602
0

Y2
0
0.1794
0.2383
0.3302
0.3691
0.4628
0.6184
0.7552
0.8378
0.9137
0.986
0.9945
1

F1
1
0.8206
0.7617
0.6698
0.6309
0.5372
0.3816
0.2448
0.1622
0.0863
0.014
0.0055
0

F2

0
3.141294
4.325145
6.37286
7.341399
9.890036
15.42908
22.52006
29.15544
38.46677
59.53468
65.03036
69.36

FID

15.79
14.36871
13.82486
12.92714
12.5486
11.47996
9.52092
7.299936
5.64456
3.63323
0.84532
0.359645
0

gama1

0
0.292769
0.539778
1.119712
1.46828
2.597123
5.577612
10.69703
16.19585
25.84198
52.27145
61.11553
69.36

0.485941
0.499663
0.522942
0.529224
0.542993
0.615351
0.683545
0.756705
0.825537
0.977612
0.997635
1

80
70
60
50
p/kPa

40
Column V

30

Column V

20
10
0
0

0.2

0.4

0.6
x1,y1

0.8

1.2

or Chloroform(1)/1,4-Dioxane(2) at 50 C
gama2
1
1.003515
1.000394
0.993196
0.993398
0.985951
0.944356
0.880598
0.804222
0.701087
0.438813
0.378351

ln gama1
-0.721668
-0.6938218
-0.6482847
-0.636343
-0.6106592
-0.4855631
-0.3804632
-0.2787821
-0.191721
-0.0226426
-0.002368
0

Axis Title

ln gama2

GE/RT

0
0.00350918
0.00039408
-0.0068271
-0.0066241
-0.0141488
-0.0572517
-0.1271542
-0.2178794
-0.3551227
-0.8236826
-0.9719317

0.1
2.22044604925031E-016
-0.3 -0.1
-0.2
-0.3
-0.4
-0.5
-0.6
-0.7
-0.8
-0.9
-1
-1.1
-1.2

GE/X1X2RT

0
-0.06407733
-0.08624407
-0.11953121
-0.13256787
-0.17079242
-0.21208628
-0.247476
-0.25171086
-0.24534941
-0.12036952
-0.06073572
0

A12
A21
-0.7566
-1.1791

-0.75818813
-0.78960037
-0.82532359
-0.8285492
-0.88200439
-0.91884737
-0.99238495
-1.01940349
-1.11277266
-1.12373057
-1.07352519

Column AI
0.1

0.3

0.5

0.7

0.9

1.1

Linear (Column
AI)
Column AH
Column AG
Column AF
Column AM
Column AN

f(x) = - 0.422492344x - 0.7566003129

R = 0.9088658542

Column AO
Column AL
Column AP
Column AQ

Axis Title

GE/RT

GE/X1X2RT
ln gama1
ln gama2
ln gama1
ln gama2
0
-0.7566
-0.7566
0
-0.7566
0
-0.067271
-0.795977 -0.721667958 0.003509179 -0.6869001 -0.00358615
-0.0883988
-0.809328 -0.693821844 0.000394078 -0.6603134 -0.0068461
-0.1203292 -0.83083325
-0.6482847 -0.006827113 -0.614966 -0.01489706
-0.134576
-0.8411 -0.636342996 -0.006624092 -0.592384
-0.020124
-0.1679932
-0.8675485 -0.61065923 -0.01414878 -0.5320663 -0.03834086
-0.2098904 -0.90933375 -0.485563055 -0.057251742 -0.4329861 -0.08358012
-0.2387236
-0.9572875 -0.380463212 -0.127154231 -0.3191669 -0.16594155
-0.2447712 -0.99129875 -0.278782146 -0.217879355 -0.2422329 -0.24794346
-0.2294002
-1.0404355 -0.191720979 -0.355122668 -0.1426442
-0.406983
-0.1207792
-1.127555 -0.022642647 -0.823682619 -0.0223038 -0.82947889
-0.0652697
-1.1536655 -0.002367979 -0.971931747 -0.0056199 -0.99648074
0
-1.1791
0
-1.1791
0
-1.1791

Column AI
Linear (Column
AI)
Column AH
Column AG
Column AF
Column AM
Column AN
Column AO
Column AL
Column AP
Column AQ