PROBLEM SET on Module 7: Solutions

Name: ______________________________________

Section: _______ Date: _______________

Instruction: Write your complete and organized solutions on clean sheets of short bond papers.
Use only the front pages of your solution sheets. Do not write at the back. Box your final answer.
Staple this questionnaire with your solution sheets.
1. How many grams of potassium dichromate (K 2Cr2O7) are required to prepare a 250-mL solution
whose concentration is 2.16 M?
2. Describe how you would prepare 5.00 x 10 2 mL of a 1.75 M H2SO4 solution, starting with an
8.61 M stock solution of H2SO4.
3. (a) What volume of 0.115 M HClO 4 solution is required to neutralize 50.0 mL of 0.0875 M
NaOH?
HClO4
+
NaOH

H 2O
+
NaClO4
(b) How many grams of NaClO4 form?
4. A sample of 0.892 g of potassium chloride (KCl) is dissolved in 54.6 g of water. What is the
percent by mass of KCl in the solution?
5. Hydrogen peroxide is a powerful oxidizing agent used in concentrated solution in rocket fuels
and in dilute solution as a hair bleach. An aqueous solution of H 2O2 is 30.0% by mass and has a
density of 1.11 g/mL. Calculate its
(a) Molality (b) Mole fraction of H2O2 (c) Molarity
6. A 1.37 M solution of citric acid (H3C6H5O7) in water has a density of 1.10 g/cm3. Calculate the
(a) mass percent (b) molality (c) mole fraction
7. What mass of glycerin (C3H8O3), a nonelectrolyte, must be dissolved in 200.0 g water to give a
solution with a freezing point of -1.50oC? Kf for water = 1.86 C-kg/mol
8. A solution is prepared by dissolving 27.0 g urea, (NH 2)2CO, in 150.0 g water. Calculate the
boiling point of the solution. Kb for water = 0.51 C-kg/mol
9. A solution contains 3.75 g of a nonvolatile pure hydrocarbon in 95 g acetone. The boiling
points of pure acetone and the solution are 55.95 oC and 56.50oC, respectively. The molal boilingpoint constant of acetone is 1.71 oC-kg/mol. What is the molar mass of the hydrocarbon?
Honor Code
On my honor, I hereby certify that I did not engage in any form of cheating in answering this
problem set, nor did I coerce or tolerate anyone to do the same. I also understand that any
proven violation of this code on my part shall mean my automatic failure in this course. So help
me God.
______________________
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