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Chemistry Plan
Chemistry Plan
Chemistry Plan
Equation
H2SO4 + Na2CO3 Na2SO4 + CO2 + H2O
1 mole of sulphuric reacts with one mole of sodium carbonate. So the ratio is one
to one.
The concentration of the acid 0.05-0.15 therefore the midpoint between the two:
0.05 + 0.15 = 0.1
2
Since the sodium carbonate is a solid, its molar mass has to be found first.
Na2CO3 = (23 x 2) + 12 + (16 x 3) = 106
Therefore Na2CO3 has a molar mass of 106g mol-1
I am going to be using a volumetric flask of volume 250cm3, so to make 0.1 mol
solution I have to find the amount of sodium carbonate I need. Therefore:
250 x 0.1 x 106 = 2.65g
1000
So I will use 2.65g of Na2CO3 to dissolve in 250cm3 of water to make a 0.1mol
standard solution.
Method:
2.65g of sodium carbonate must be weighed out using a balance. So an empty
weighing bottle is used as a tare on the balance and then 2.65g of the sodium
carbonate is measured up.
Put the sodium carbonate into the volumetric flask. And wash the weighing
bottle with distilled water, putting the washing into the volumetric flask along
with the sodium carbonate.
Wash out the container distilled water is to be added. Add about 100 cm 3 of
water invert the flask several times (preferably 50 because the solubility of
group one carbonates increases as you go down the group, sodium is only the
second one down) to ensure it is completely dissolved. Then slowly add more
distilled water until the solution reaches about 240cm 3 then shake it 10 times.
Use a pipette to put in the rest of the water until the solution has reached a
volume of 250cm3 and invert the solution further (about 10 times as the sodium
carbonate has now dissolved). This ensures that all the sodium carbonate has
dissolved around the solution evenly. Now we have a 250 cm 3 standard solution.
Using pipette filler draw out 10cm 3 of acid and put it into the conical flask. Add 2
drops of methyl orange into the solution.
Set up apparatus as shown in the diagram and add the standard solution into the
burette. Record the volume on the burette as the start. Release the plug on the
burette and let the solution drip into the conical flask. Do this until the methyl
orange changes colour and reaches an end point. Then proceed to record the
volume shown on the burette. This is only a rough titration so the difference
between the two volumes is only a guide line as to approximately how much
solution should ideally be added to the acid.
Repeat the procedure using the first rough titration as a guideline. Do several
titrations until you have 3 volumes that agree to within 0.1cm 3 of each other
Table of results to show burette readings and titre in the titration experiment
Titration
Rough
Final
burette
reading/c
m3
Initial
burette
reading/c
m3
Titre/cm3
Average titre =
Why this plan is precise and will provide reliable results.
Firstly the amount of sodium carbonate has been precisely calculated.
Also with transferring the sodium carbonate to the volumetric flask, the washings
were transferred, 3 times to ensure the entire solid had gone into the flask.
The flask is inverted several times to ensure that the entire solid has dissolved.
The pipette used is to 10% of the volumetric flask.
The ratio was worked out to prove how many moles of sodium carbonate would
react to the sulphuric acid, it was found to be 1:1.
The right indicator was picked. Sulphuric acid is a strong acid and sodium
carbonate is a weak base meaning methyl orange has to be used.
Risk assessment
Sulphuric acid
Sulphuric acid is a strong acid and will cause burns, and is highly toxic through
ingestion and skin contact. However it is diluted to between 0.05 to 0.15mol in
this experiment therefore it is an irritant.
Lab coats and goggles should be worn to avoid skin contact and eye contact
In case of skin contact it is important to promptly wash the affected area with
water to get rid of the acid.
Bibliography
SAC Chemical Ideas 1.5, pg 12 ISBN: 0 435 63120 9, George Burton, 2000.
(Accessed 06-03-07)
SAC 2000 Activity Sheet M2.4 & EL 2.1 (accessed 06-03-07)
http://www.jtbaker.com/msds/englishhtml/s3242.htm - sourced information about
sodium carbonate. Website contains information effective as of 08/17/06 making
it reliable and up to date
(Accessed 06-03-07)
http://ptcl.chem.ox.ac.uk/MSDS/SU/sulfuric_acid_concentrated.html - sourced
information about sulphuric acid hazard. Website contains information on
hazards and was last updated on 31/08/05 making it reliable and fairly up to
date. (Accessed 06-03-07)