Iligan City National High School

Third Quarter Examinations

Advanced Chemistry
S.Y. 2016-2017

Name:
Score:

Section:

I. Multiple Choice: Write the letter of the correct answer on the space provided
before the number:
1. A spontaneous process is one that
a. is instantaneous
c. releases heat
b. can proceed on its own
d. has positive S
2. In all spontaneous process
a. enthalpy decreases
c. free energy increases
b. useful work can be performedd. Suniverse decreases
3. The entropy change for a reaction is
a. G - H
b. usually zero
d. Sreactants - Sproducts

c. Sproducts - Sreactants

4. The entropy change for evaporation of liquid is

a. positive
b. negative
c. zero

d. no change

5. A measure of disorder or randomness of the particle that made up a

system is called
a. enthalpy
b. free energy
c. entropy
d. law of
disorder
6. If the change in the systems free energy is negative, the reaction is:
a. spontaneous
b. non-spontaneous
c. cannot be determined
d. endothermic
7. The Gibbs free energy change is equal to
a. H - TS
b. H - SS
c. G - TS

d. H + TS

8. A change in concentration over time is the

a. reaction rate
b. transition rate c. activated complex
intermediate product

d.

9. Which of the following is not an acceptable unit for expressing a reaction

rate?
a. M/min

b. L/s

c. Mol/L.min

d. Mol/mL.hr

10. Which of the following does not affect reaction rate?

a. catalysts
c. concentration of reactant
b. surface area of reactants
d. reactivity of products
11. It is a short-lived complex product from an effective collision
a. activated complex
c. intermediate complex
b. by product
d. secondary complex
12. The rate of a chemical reaction can be increased by
a. decreasing the concentration of the reactants
b. increasing the surface area of the reactants
c. removing the catalysts
d. decreasing the reaction temperature
13. Catalysts
a. slow rate reaction
b. lower the activation energy barrier
c. increase the energy of the reactant particles
d. are used up in reaction

14. The activation energy of a reaction maybe lowered by

a. raising the temperature
b. removing the products of the reaction
c. lowering the temperature
d. adding a catalyst
15. The activation energy of a reaction is the amount of energy necessary to
form the
a. products
b. catalyst
c. reaction mechanism
d.
activated complex
16. According to the collision theory, what must happen in order for two
molecules to react?
a. the molecules must collide
b. the molecules must have sufficient energy
c. molecules must be properly oriented
d. all of these
17. A change in concentration over time is the
a. reaction time
b. transition time
d. intermediate product

c. activated complex

18. For a particular reaction, rate = k[A]2[B]. If the concentration of reaction A

is tripled, the rate is increased by a factor of
a. 3
b. 4
c. 6
d. 9
19. According to collision theory, the rate of a reaction does not depend on
a. frequency of collision
b. energy of collision
c. direction of collision
d. orientation of colliding particles
20. At equilibrium,
a. Keq = Q
b. Keq > 1

c. Keq = 1

d. Keq < 1

21. The equilibrium expression for the reaction;

H2(g) +
I2(g)
2HI is
a. [2HI] / [H2][I2]
b. [H2][I2] / [2HI]
c. [H2][I2] / [HI]2
[HI]2 / [H2][I2]
22. Given: SnO2(s)

a. [Sn][CO2]2 / [SnO2][ CO2]2

c. [SnO2] [CO]2 / [Sn][CO2]2

2CO(g)

Sn(s)

d.

2CO2(g);
Keq
for this reaction is

b. [ CO2]2 / [CO]2
d. [CO]2 / [CO2]2

23. If the equilibrium constant is very large,

a. it is still less than 1
b. more product than reactants exist
at equilibrium
c. more reactants than products exist at equilibrium
d. the reaction
barely gets going
24. The equilibrium constant changes with
a. volume
b. pressure
c. temperature
+

d. Q

25. In sealed container, the reaction, CH 4(g)

+
H2O(g)
3H2(g) will produce additional hydrogen gas if
a. carbon monoxide is added
b. water vapor is removed
c. the volume is decreased
d. water vapor is added

CO(g)

26. Which change will increase the production of water vapor in this reaction
at equilibrium?
2H2S(g)
+
3O2(g)
2H2O(g)
+
2SO2(g)
a. adding SO2
b. removing H2S
c. removing O2
d. removing SO2
27. To determine if a reaction is at equilibrium, compare the
a. concentration of reactants and products
b. reaction quotient with the
equilibrium constant

c. temperature of reactants and products

products

d. volume of reactants and

28. A system reaches chemical equilibrium when

a. no new product is formed by the forward reaction
b. the reverse reaction no longer occurs in the system
c. the concentration of the reactants in the system is equal to the
concentration of products
d. the rate at which the forward reaction occurs equals the rate of the reverse
reaction
29.What does the value of Keq greater than 1 mean?
a. more reactants than products exists at equilibrium
b. more products than reactants exists at equilibrium
c. the rate of the forward reaction is high at equilibrium
d. the rate of the reverse reaction is highest at equilibrium
30. The following system is in equilibrium: 2S (s) + SF2(g)
SF4(g) +
SF6(g).
The equilibrium will shift to the right if:
a. the concentration of SF4 is increased
b. the concentration of SF6 is
increased
c. the pressure in the system is increased
d. the pressure in the system is
decreased
31. If the forward reaction of a system in equilibrium is endothermic,
increasing the temperature of the system will
a. shift the equilibrium to the left
b. shift the equilibrium to the
right
c. decrease the rate of the forward reaction c. decrease the rate of the
reverse reaction
32. Which reaction will produce more products when pressure is increased?
a. P4(s)
+ 6CI2(g)
4PCl3(l) b. PCl3(g) + 3NH3(g)
P(NH2)3(g) + 3HCl(g)
c. 4HCl(g) +
O2(g)
2H2O(g) d. 2H202(l)
2H20(l)
+
02(g)
33.An electrochemical cell that produce electricity as the result of
spontaneous redox reaction
a. electrolytic cell
b. voltaic cell
c. oxidation
electrolyte
34.In voltaic cell, reduction occurs at the
a. anode
b. electrolyte
cathode

c. salt bridge

d.

d.

35. A salt bridge is essential to a voltaic cell for all the following reasons
except
a. it allows ions to move from the solution of one cell to other
b. It cause electric current to flow between the two electrodes of cell
c. it relieves the building of positive charge on the anode side of a cell
d. it allows electron to move from the solution
II. Modified True or False: Write true if the statement is true, if the statement
is false, change the underlined and or phrase to make it true.
36. When G for a reaction is negative, the reaction is spontaneous.
37. A spontaneous process cannot occur with no outside interaction.
38. When G for reaction is negative, the reaction is spontaneous.
39. Keq does depend on the initial concentration of reactants and products.
40. For a reaction that has mostly reactants at equilibrium, Keq < 1.
41. At equilibrium, the rates of the forward and reverse reactions are equal.
42. Pure liquids and solids should be included in the equilibrium expression.
43. To determine if a reaction is at equilibrium, compare the reaction quotient
with the equilibrium.
44. A salt-bridge allows ions to move between half-cells.
45. Oxidation always occurs at the cathode.

III. Problem Solving (46 - 50): Show your solutions:

At a certain temperature, Keq = 10.5 for the equilibrium. CO(g) +
CH3OH(g)
Calculate these concentration:

2H2(g)

a. [CO] in an equilibrium mixture containing 0.933 mol/L H 2 and 1.32 mol/L CH3OH.
b. [H2] in an equilibrium mixture containing 1.09 mol/L CO and 0.325 mol/L CH 3OH.
c. [CH3OH] in an equilibrium mixture containing 0.0661 mol/L H 2 and 3.85 mol/L CO.