Sri Utari (5213414013)

Syarifatur Richana (5213414017)

sistem isotermal

328.15 K

55

logP=A-B/(T+C)

No.

Formula
1 C3 H 6 O
2 C3 H 8 O

A12
A21
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14

Molar Mass

CAS Registry
Number

58.08 67-64-1
60.096 67-63-0
0.624911567
0.5934587123
P data (kpa)
34.393
39.93
44.208
52.026
59.05
60.848
69
71.177
75.068
80.287
85.038
85.942
91.22
94.308

x1
0.0237
0.0642
0.0971
0.1591
0.2353
0.2687
0.3879
0.4314
0.5234
0.6084
0.7216
0.7338
0.8569
0.9214

y1
0.1166
0.2777
0.3625
0.4762
0.5722
0.6024
0.6995
0.7284
0.7655
0.8098
0.8617
0.8729
0.924
0.9629

Name
Acetone
2-Propanol

x2
0.9763
0.9358
0.9029
0.8409
0.7647
0.7313
0.6121
0.5686
0.4766
0.3916
0.2784
0.2662
0.1431
0.0786

MARGULES
Celcius
A

P sat(mmHg)

7.314

1316

240.5

725.3227556848

7.831

1483

217.4

243.6690071238

y2
0.8834
0.7223
0.6375
0.5238
0.4278
0.3976
0.3005
0.2716
0.2345
0.1902
0.1383
0.1271
0.076
0.0371

1
1.811618654
1.7223884129
1.6561011423
1.5446633315
1.428709449
1.3842561497
1.2523115601
1.2132029291
1.1439284402
1.0941321934
1.0459405298
1.04186433
1.0117615011
1.0035087372

2
1.0003679036
1.0026922701
1.0061497151
1.0164956653
1.0361592193
1.0472513118
1.0997570025
1.1242350806
1.1862413155
1.257074653
1.3745644981
1.3889833116
1.5563965886
1.6620155357

P calculate
35.8800924509
41.1756492555
45.0627052535
51.5334357634
58.2493136783
60.8479778815
68.8434506055
71.377842901
76.2649030436
80.3633906505
85.4173789397
85.9419953205
91.0734889206
93.6572223675

P sat(kPa)
96.7014804334
32.4864393678

P
1.4870924509
1.2456492555
0.8547052535
0.4925642366
0.8006863217
2.21184923E-005
0.1565493945
0.200842901
1.1969030436
0.0763906505
0.3793789397
4.67948112E-006
0.1465110794
0.6507776325

y1 calculate
Persen Eror
0.1157163428
4.3238230188
0.2596921311
3.119582408
0.3450817162
1.9333723614
0.461156189
0.9467655338
0.5580950292
1.3559463534
0.5911138031 3.635040149E-005
0.6823428764
0.2268831805
0.7090605035
0.2821738779
0.7591733884
1.5944251127
0.8010025028
0.0951469733
0.8544573673
0.4461287186
0.8602339279 5.444929281E-006
0.9205543645
0.1606128913
0.954687454
0.6900555971
1.0839255587

P-XY Ma
100
80
60

P (kPa)

40
20
0
0

0.2

0.4

x1

P-XY Margules

Pcal-x
Pcal-y
P-x data
P-y data

0.2

0.4

0.6

x1, y1

0.8

1.2

Sri Utari (5213414013)

Syarifatur Richana (5213414017)

sistem isotermal

328.15 K

logP=A-B/(T+C)

No.

Formula

Molar Mass

1 C3 H 6 O
2 C3 H 8 O
A12
A21
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14

CAS Registry
Number

58.08 67-64-1
60.096 67-63-0
0.6219518864
0.5938855607
P data (kpa)
34.393
39.93
44.208
52.026
59.05
60.848
69
71.177
75.068
80.287
85.038
85.942
91.22
94.308

x1

y1
0.0237
0.0642
0.0971
0.1591
0.2353
0.2687
0.3879
0.4314
0.5234
0.6084
0.7216
0.7338
0.8569
0.9214

0.1166
0.2777
0.3625
0.4762
0.5722
0.6024
0.6995
0.7284
0.7655
0.8098
0.8617
0.8729
0.924
0.9629

VAN LAAR
55 Celcius

Name

Acetone

7.314

1316

240.5

2-Propanol

7.831

1483

217.4

y2
0.8834
0.7223
0.6375
0.5238
0.4278
0.3976
0.3005
0.2716
0.2345
0.1902
0.1383
0.1271
0.076
0.0371

1
1.8066873596
1.7183537533
1.6527016413
1.5422625677
1.4272374342
1.3831042034
1.2519600021
1.2130353764
1.144006903
1.0943054488
1.0461098757
1.0420273746
1.011833472
1.003534651

2
1.0003651022
1.0026719548
1.0061037204
1.0163748191
1.0359030494
1.0469225037
1.0991187402
1.1234716293
1.1852148479
1.2558432887
1.3732209975
1.3876458154
1.5554484269
1.6616175487

x2
0.9763
0.9358
0.9029
0.8409
0.7647
0.7313
0.6121
0.5686
0.4766
0.3916
0.2784
0.2662
0.1431
0.0786

LAAR

P sat(mmHg)

P sat(kPa)

725.3227556848

96.7014804334

243.6690071238

32.4864393678

P calculate
P
35.8687019368
1.4757019368
41.1499835398
1.2199835398
45.0294357941
0.8214357941
51.4931982596
0.5328017404
58.2094557933
0.8405442067
60.8102344663
0.0377655337
68.8175716776
0.1824283224
71.3567507917
0.1797507917
76.2529814899
1.1849814899
80.3579187826
0.0709187826
85.4170449401
0.3790449401
85.9419983716 1.62842167E-006
91.07504486
0.14495514
93.6585150719
0.6494849281

y1 calculate
Persen Eror
0.1154380056
4.29070432
0.2592454011
3.0553056345
0.3446277985
1.8581157123
0.4607992395
1.0241066781
0.5579017698
1.4234448885
0.5909884762
0.0620653656
0.682407848
0.264388873
0.7091721368
0.2525405562
0.7593441596
1.5785441066
0.801183893
0.0883315887
0.8545990522
0.4457359534
0.8603685181 1.8947914539E-006
0.9206041195
0.1589071914
0.9546989298
0.6886848709
1.0850626882

P-XY Van Laar

100
90
80
70

Pcal-x

60

P (kPa)

Pcal-y

50

P-x data

40

P-y data

30
20
10
0
0

0.2

0.4

0.6

x1, y1

0.8

1.2

Pcal-x
Pcal-y
P-x data
P-y data

Sri Utari (5213414013)

Syarifatur Richana (5213414017)

sistem isotermal

328.15 K

55

logP=A-B/(T+C)

No.

Formula
1 C3 H 6 O
2 C3 H 8 O

A12
A21
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14

Molar Mass

CAS Registry
Number

58.08 67-64-1

Acetone

60.096 67-63-0
0.8710722727
0.6760350833
P data (kpa)
34.393
39.93
44.208
52.026
59.05
60.848
69
71.177
75.068
80.287
85.038
85.942
91.22
94.308

x1
0.0237
0.0642
0.0971
0.1591
0.2353
0.2687
0.3879
0.4314
0.5234
0.6084
0.7216
0.7338
0.8569
0.9214

Name

2-Propanol

y1

x2
0.1166
0.2777
0.3625
0.4762
0.5722
0.6024
0.6995
0.7284
0.7655
0.8098
0.8617
0.8729
0.924
0.9629

0.9763
0.9358
0.9029
0.8409
0.7647
0.7313
0.6121
0.5686
0.4766
0.3916
0.2784
0.2662
0.1431
0.0786

WILSON
Celcius

P sat(mmHg)

P sat(kPa)

7.314

1316

240.5

725.3227556848 96.7014804334

7.831

1483

217.4

243.6690071238 32.4864393678

y2
0.8834
0.7223
0.6375
0.5238
0.4278
0.3976
0.3005
0.2716
0.2345
0.1902
0.1383
0.1271
0.076
0.0371

1
1.4517648419
1.4181248618
1.391635889
1.343780966
1.2887150365
1.2659044886
1.19126782
1.1667368064
1.1198163631
1.0826983949
1.0431349684
1.0395772075
1.0118731426
1.0036577593

2
1.0152945329
1.041112932
1.0617427445
1.0996104908
1.1439355605
1.1624443621
1.2228780481
1.2423775026
1.2782431078
1.3039489807
1.3252258262
1.3265431982
1.3280703069
1.3197002892

P calculate
P
35.5287910558
1.1357910558
40.4547288579
0.5247288579
44.2101073049
0.0021073049
50.7133373561
1.3126626439
57.7413214875
1.3086785125
60.5094449401
0.3385550599
69.001924913
0.001924913
71.621716737
0.444716737
76.4689722602
1.4009722602
80.2870245631 2.4563076E-005
84.7753774212
0.2626225788
85.2397268981
0.7022731019
90.02129454
1.19870546
92.7964209109
1.5115790891

y1 calculate
Persen Eror
0.0936477427
3.3023901835
0.2176272765
1.314121858
0.2955673134
0.0047667953
0.4076707911
2.5230896934
0.5078380375
2.2162210203
0.5435988884
0.5563947211
0.6475914504
0.002789729
0.6795813245
0.6248039915
0.7411880302
1.866270928
0.7933858634 3.0594088950E-005
0.8586188521
0.3088296748
0.8654172146
0.8171477297
0.9314168291
1.3140818461
0.9636864468
1.6028110967
1.1752678472

P-XY Wilson
100
80
60

P (kPa)

40
20
0
0

0.2

0.4

0.6

x1, y1

0.8

-XY Wilson

0.4

Pcal-x
Pcal-y
P-x data
P-y data

0.6

x1, y1

0.8

1.2

P-xy
100

P-x data Ma

90

P-y data m

80

P-x data va

P-y data va

70

P-x data wi

60

P (kPa)

P-y data wil

50

P-x calcu m

40

P-y calcu m

30

P-x calcu va

20

P-y calcu va

P-x calcu w

10

P-y calcu w

0
0

0.2

0.4

0.6

0.8

x1, y1

Untuk menentukan letak absis (sumbu x) dan ordinat (sumbu y)

di grafik P-xy pada VLE bersumber dari buku Smith Van Ness halaman 406.

1.2

P-x data Margules

Margules
Van Laar
Wilson

P-y data margules

P-x data van laar
P-y data van laar
P-x data wilson
P-y data wilson
P-x calcu margules
P-y calcu margules
P-x calcu van laar
P-y calcu van laar
P-x calcu wilson
P-y calcu wilson
1

1.2

Kesimpulan :
Metode korelasi untuk aceton dan propanol yang paling c
diantara metode margules, van laar dan wilson adalah
metode margules, karena memberikan nilai persen error
paling kecil diantara kedua persen error lainnya.

A12

A21
persen error
0.624911567 0.593458712
1.083925559
0.621951886 0.593885561
1.085062688
0.8710722727 0.6760350833
1.175267847

n dan propanol yang paling cocok

an laar dan wilson adalah
mberikan nilai persen error yang
ersen error lainnya.