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Surface Area and Porosity PDF
Surface Area and Porosity PDF
by
Neal Leddy
CMA Analytical Workshop
2012
Adsorption
Adsorption Isotherms
Iostherm types
Type I
Pores are typically microporus with the exposed
surface residing almost exclusively inside the
microspores, which once filled with adsorbate, leave
little or no external surface for further adsorption.
Type II
Most frequently found when adsorption occurs on
nonporous powders or powders with diameters
exceeding micropores.
Inflection point occurs near the completion of the
first adsorbed monolayer
Type III
Characterised by heats of adsorption less than the
adsorbate heat of liquification, adsorption
proceeds as the adsorbate interaction with an
adsorbed layer is greater than the interaction with
the adsorbent surface
Type IV
Occur on porous adsorbents with pores in the range
of 1.5 100nm. At higher pressures the slope shows
increased uptake of adsorbate as pores become
filled, inflection point typically occurs near
completion of the first monolayer
Type V
Are observed where there is small adsorbateabsorbent interaction potentials (similar to type III),
and are also associated with pores in the 1.5
100nm range
Adsorbate
BET
Wm
(weight of monolayer)
Relative
Pressure
P/Po
1.10536e-01
7.5355
1.3195e+1
1.53021e-01
8.1192
1.7804e+1
1.99422e-01
8.7403
2.2803e+1
2.48028e-01
9.4102
2.8045e+1
2.97227e-01
10.1099
3.3472e+1
Summary
Slope = 108.451
Intercept = 1.195e+00
Correlation coefficient, r = 0.99999
C constant= 91.759
Surface Area = 31.762 m/g
C Constant
Relative error
0.70
10
0.19
50
0.04
100
0.02
1000
0.0002
Infinity
Langmuir
Macroporous
>50nm
Mesoporus
2-50nm
Microporus
<2nm
Adsorption/Desorption Isotherm
5.787e-01 cc/g
2.103e+00 cc/g
2.192e+00 cc/g
2.054e+00 cc/g
2.146e+00 cc/g
4.257e-01 cc/g
4.358e-01 cc/g
1.904e+00 cc/g
3.505e+01
1.698e+01
1.710e+01
1.698e+01
1.710e+01
1.838e+00
2.261e+00
2.376e+01
Other Methods
Degas
Analysis