A

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92

ISO 6976 - 1995

Other data source - GERG Technical Monograph No. TPC/1 (1986)

MW as per TABLE 1.
ID
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59

Component
CH4
Methane
C2H6 Ethane
C3H8 Propane
C4H10 N-Butane
C4H10 I-Butane
C5H12 N-Pentane
C5H12 I-Pentane
C5H12 2,2-Dimethylpropane
C6H14 N-Hexane
C6H14 2-Methylpentane
C6H14 3-Methylpentane
C6H14 2,2-Dimethylbutane
C6H14 2,3-Dimethylbutane
C7H16 N-Heptane
C8H18 N-Octane
C9H20 N-Nonane
C10H22 N-Decane
C5H10 Cyclopentane
C6H12 Methylcyclopentane
C7H14 Ethylcyclopentane
C6H12 Cyclohexane
C7H14 Methylcyclohexane
C8H16 Ethylcyclohexane
C6H6 Benzene
C7H8 Toluene
C8H10 Ethylbenzene
C8H10 o-Xylene
C1H4O Methanol
C1H4S Methanethiol
H2
Hydrogen
H2O
Water
H2S
H2S
NH3
Ammonia
HCn
HCN
CO
CO
COS
Carbonyl Sulfide
CS2
Carbon Disulfide
He
Helium
Ne
Neon
Ar
Argon
N2
Nitrogen
O2
Oxygen
CO2
CO2
SO2
SO2
N2O
Dinitrogen Monoxide
K
Krypton
Xe
Xenon
Air

Mole%
86.978821
7.101859
2.094905
0.386079
0.218057
0.066633
0.064865
0
0.046202

TOTAL Mole%

99.999583

0.862475
2.179687

Normalised
Mole%
0.8697918
0.0710189
0.0209491
0.0038608
0.0021806
0.0006663
0.0006487
0
0.000462
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.0086248
0
0.021797
0
0
0
0
0

18.7001324464 using Table 1

T crit (K)
P crit (kPa)
Xi Summ Factors

206.306296742
4654.23368341
0.0515741537

Z mix (15C,1bar)
RD Ideal
RD real

Normalised
Mass%
Unrounded-Rounded
mole*mw
74.620169
-0.00024 13.9540704
11.4199079
-0.00036 2.13553791
4.94004047
-0.00048 0.92379411
1.20000023
0.0004 0.22440163
0.67775883
0.0004
0.1267418
0.25708861
0.00028 0.04807591
0.25026717
0.00028 0.04680029
0
0.00028
0
0.21291648
0.00016 0.03981566
0
0.00016
0
0
0.00016
0
0
0.00016
0
0
0.00016
0
0
0.00004
0
0
-0.00008
0
0
-0.0002
0
0
-0.00032
0
0
0.0004
0
0
0.00028
0
0
0.00016
0
0
0.00028
0
0
0.00016
0
0
0.00004
0
0
-0.00036
0
0
-0.00048
0
0
0.0004
0
0
0.0004
0
0
0.00016
0
0
-0.00024
0
0
-0.00002
0
0
-0.00002
0
0
-0.00012
0
0
-0.00004
0
0
-0.00032
0
0
0.0004
0
0
0.0004
0
0
0
0
0
0
0
0
0
0
0
0
0
1.2920253
-0.00002 0.24161044
0
0
0
5.12982596
-0.0002 0.95928425
0
-0.0002
0
0
0
0
0
-83.8
0
0
-131.29
0
0
-28.9626
0

Rel Mol Mass

100

Hs(15,15) (MJ/m3)
Hi(15,15) (MJ/m3)

CV: vol

Hs(15,15) (MJ/m3)

CV: vol

Hs(15,15) (MJ/m3)

CV: mass Hs(15,15) (MJ/kg)

Wobbe (MJ/m3)

Hi(15,15) (MJ/m3)
Hi(15,15) (MJ/m3)

ID
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59

18.7001324

N O P Q RS

T
R
k0
k15
k25

8.31451 J/mol/K Gas Const 0.00007

0.0446148
0.0422923 Factors to convert CV in kJ/mol to MJ/m3
0.0408738

AA

AB

AC

AD

MM air
Z air (15C,
Density (15

FisCal

KEL

18.6998864 using "un-rounded" Table 1

-0.001315743 %diff from Table 1

S500
-100

-100 %errors

0.7929809003 kg/m3
-100

-100

-100

FisCal

KEL

S500

-100
-100

-100
-100

-100
-100

%errors

%errors from Table 3

%errors from Table 5

-100

-100

-100

%errors.

-100

-100

-100

%errors.

FisCal

KEL

S500

-100
-100

-100
-100

-100
-100

40.4698975215 Ideal Sup

36.5652632343 Ideal Inf
Using Table 3
40.5778302215 Real Sup
Using Table 5
40.5780520699 Real Sup

Table 3 figures are the "preferred option".

Table 5 figures are derived from Table 3 and then rounded to 2 decimal places.

51.1712579767 Real Sup

50.4426757233

Using Table 3
36.6627823244 Real Inf
Using Table 5
36.6632466056 Real Inf

AE

AF

AG

AH

AI

AJ

AK

AL

AM

AN

AO

AP AQ

kg/kmol
kg/m3

Figures in this colour from GERG Technical Monograph TPC/1 (1986)

ISO 6976:1995
just
TABLE 5
kJ/mol
comparing
MJ/m3
T crit(K)
P crit (kPa) D crit kg/m3 mVol crit cm Comprs crit Acentric Fac Comp(15, 1Summ Factor2nd Virial C CVsup25
CVinf25
CVsup20
CVinf20
CVsup15
CVinf15
CVsup0
CVinf0
Component Table 5
CVsup15
CVinf15
190.555
4598.8
164.1
97.76
0.284
0.0115
0.9980
0.0447
47
890.63
802.60
891.09
802.65
891.56
802.69
892.97
802.82 Methane
37.706125
37.706
33.948
305.83
4880
203
148.1
0.284
0.0908
0.9915
0.0922
199.1
1560.69
1428.64
1561.41
1428.74
1562.14
1428.84
1564.34
1429.12 Ethane
66.066497
66.07
60.43
369.82
4250
217
203.2
0.281
0.1454
0.9821
0.1338
415
2219.17
2043.11
2220.13
2043.23
2221.10
2043.37
2224.01
2043.71 Propane
93.935433
93.94
86.42
425.14
3784
228
254.9
0.273
0.1928
0.9650
0.1871
799
2877.40
2657.32
2878.57
2657.45
2879.76
2657.60
2883.82
2658.45 N-Butane
121.79168
121.79
112.4
408.13
3648
221
263
0.283
0.1756
0.9680
0.1789
738
2868.20
2648.12
2869.38
2648.26
2870.58
2648.42
2874.20
2648.83 I-Butane
121.40344
121.4
112.01
469.69
3364
232
311
0.268
0.251
0.9370
0.251
1398
3535.77
3271.67
3537.17
3271.83
3538.60
3272.00
3542.89
3272.45 N-Pentane 149.65554
149.66
138.38
460.39
3381
236
305.7
0.27
0.2273
0.9480
0.228
1170
3528.83
3264.73
3530.24
3264.89
3531.68
3265.08
3535.98
3265.54 I-Pentane
149.36288
149.36
138.09
433.75
3199
238
303.2
0.269
0.197
0.9550
0.2121
1027
3514.61
3250.51
3516.01
3250.67
3517.43
3250.83
3521.72
3251.28 Neo-Pentan 148.76021
148.76
137.49
506.4
3030
233
369.9
0.266
0.2957
0.9130
0.295
2053
4194.95
3886.84
4196.58
3887.01
4198.24
3887.21
4203.23
3887.71 N-Hexane
177.55324
177.55
164.4
497.5
3010
235
366.7
0.267
0.2791
0.9140
0.2933
1853
4187.32
3879.21
4188.95
3879.38
4190.62
3879.59
4195.61
3880.09 2-Methylpen 177.23097
177.23
164.08
504.4
3120
235
366.7
0.273
0.275
0.9170
0.2881
1809
4189.90
3881.79
4191.54
3881.97
4193.22
3882.19
4198.24
3882.72 3-Methylpen 177.34093
177.34
164.19
488.7
3080
240
359.1
0.272
0.231
0.9310
0.2627
1626
4177.52
3869.41
4179.15
3869.59
4180.83
3869.80
4185.84
3870.32 2,2-Dimethy 176.81693
176.82
163.66
499.9
3130
241
357.6
0.269
0.2473
0.9250
0.2739
1634
4185.28
3877.17
4186.93
3877.36
4188.60
3877.57
4193.63
3878.11 2,3-Dimethy 177.14554
177.15
163.99
539.2
2740
232
431.9
0.264
0.3506
0.8660
0.3661
3165
4853.43
4501.30
4855.29
4501.49
4857.18
4501.72
4862.87
4502.28 N-Heptane 205.42133
205.42
190.39
568.4
2490
232
492.4
0.259
0.3942
0.8020
0.445
4687
5511.80
5115.66
5513.88
5115.87
5516.01
5116.11
5522.40
5116.73 N-Octane
233.28476
233.28
216.37
594.4
2280
232
552.8
0.255
0.4437
0.7100
0.5385
6855
6171.15
5730.99
6173.46
5731.22
6175.82
5731.49
6182.91
5732.17 N-Nonane 261.18965
261.19
242.4
617.8
2090
233
610.7
0.248
0.4902
0.5840
0.645
9826
6829.77
6345.59
6832.31
6345.85
6834.90
6346.14
6842.69
6346.88 N-Decane 289.06366
289.06
268.39
511.61
4502
270
259.8
0.275
0.1923
0.9470
0.2302
1248
3319.59
3099.51
3320.88
3099.76
3322.19
3100.03
3326.14
3100.77 Cyclopenta 140.50306
140.5
131.11
532.73
3784
264
318.8
0.272
0.2395
0.9210
0.2811
1860
3969.44
3705.34
3970.93
3705.59
3972.46
3705.86
3977.04
3706.60 Methylcyclo 168.00448
168
156.73
569.46
3397
262
374.8
0.269
0.2826
0.8760
0.3521
2938
4628.47
4320.36
4630.19
4320.63
4631.95
4320.92
4637.27
4321.75 Ethylcyclop 195.89583
195.9
182.74
553.5
4074
271.8
309.6
0.274
0.2144
0.9180
0.2864
1936
3952.96
3688.86
3954.47
3689.13
3956.02
3689.42
3960.67
3690.23 Cyclohexan 167.30919
167.31
156.03
572.12
3471
267
367.7
0.268
0.2333
0.8860
0.3376
2699
4600.64
4292.53
4602.35
4292.78
4604.09
4293.06
4609.34
4293.82 Methylcyclo 194.71757
194.72
181.56
609
3040
250
449
0.269
0.2426
0.8240
0.4195
4167
5263.05
4910.92
5264.98
4911.19
5266.95
4911.49
5272.88
4912.29 Ethylcycloh 222.75144
222.75
207.72
562.16
4898
304.4
256.6
0.269
0.21
0.9260
0.272
1613
3301.43
3169.38
3302.15
3169.48
3302.86
3169.56
3305.03
3169.81 Benzene
139.68555
139.69
134.05
591.8
4106
291.3
316.3
0.264
0.2566
0.8830
0.3421
2770
3947.89
3771.83
3948.84
3771.95
3949.81
3772.08
3952.72
3772.42 Toluene
167.04656
167.05
159.53
617.2
3606
283.5
374.5
0.263
0.3011
0.8230
0.4207
4197
4607.15
4387.07
4608.32
4387.20
4609.53
4387.37
4613.14
4387.77 Ethylbenze 194.94764
194.95
185.55
630.33
3734
288
368.6
0.263
0.3136
0.8040
0.4427
4628
4596.31
4376.23
4597.46
4376.34
4598.64
4376.48
4602.17
4376.80 o-Xylene
194.48707
194.49
185.09
512.64
8092
272
117.8
0.224
0.556
0.8720
0.3578
2633
764.09
676.06
764.59
676.14
765.09
676.22
766.59
676.44 Methanol
32.357418
32.36
28.6
470
7230
332
144.9
0.268
0.153
0.9770
0.1517
547
1239.39
1151.36
1239.83
1151.39
1240.28
1151.41
1241.63
1151.48 Methanethio 52.454297
52.45
48.7
33.2
1297
31
65
0.306
-0.218
1.0006
-0.0048
-14
285.83
241.81
285.99
241.76
286.15
241.72
286.63
241.56 Hydrogen
12.101942
12.102
10.223
647.14
22064
332
55.9
0.229
0.328
0.9450
0.2345
1224
44.02
0.00
44.22
0.00
44.43
0.00
45.07
0.00 Water
1.8791739
1.88
0
373.2
8940
346
98.5
0.284
0.109
0.9900
0.1
229
562.01
517.99
562.19
517.97
562.38
517.95
562.94
517.87 H2S
23.784345
23.78
21.91
405.5
11350
235
72.5
0.244
0.25
0.9880
0.1095
282
382.81
316.79
383.16
316.82
383.51
316.86
384.57
316.96 Ammonia
16.219521
16.22
13.4
456.7
5390
195
138.6
0.197
0.388
0.9120
0.2966
1900
671.50
649.50
671.60
649.50
671.70
649.50
671.90
649.40 HCN
28.407739
28.41
27.47
132.85
3494
304
92.2
0.291
0.053
0.9995
0.0224
10.5
282.98
282.98
282.95
282.95
282.91
282.91
282.80
282.80 CO
11.964915
11.96
11.96
378.8
6349
445
135.1
0.272
0.096
0.9870
0.114
298
548.23
548.23
548.19
548.19
548.15
548.15
548.01
548.01 Carbonyl Sul 23.182526
23.18
23.18
552
7900
440
173.1
0.298
0.109
0.9620
0.1949
875
1104.49
1104.49
1104.41
1104.41
1104.32
1104.32
1104.06
1104.06 Carbon Disu 46.704235
46.7
46.7
5.19
227
70
57.2
0.301
-0.365
1.0005
0.0002
-11.9
Helium
0
0
44.4
2760
484
41.7
0.312
-0.029
1.0005
0.0002
-11.2
Neon
0
0
150.65
4866
529.1
75.5
0.293
0.001
0.9992
0.0283
18.2
Argon
0
0
126.2
3390
313
89.5
0.289
0.039
0.9997
0.0173
7.1
Nitrogen
0
0
154.58
5043
436
73.4
0.288
0.025
0.9992
0.0283
18.4
Oxygen
0
0
304.2
7386
468
94
0.275
0.239
0.9944
0.0748
132.3
CO2
0
0
430.8
7884
525
122
0.269
0.256
0.9790
0.1449
484
SO2
0
0
Dinitrogen Monoxide
Krypton
Xenon
132.55
3769
313
92.5
0.316
0
0.9996
0
10.1
Air

0.9973401067
0.6456648383
0.6471149157

28.9626
0.99958
1.22541

ISO 6976:1995

ID

AR

AS

%errors from Table 3

%errors from Table 5

Page

AT

Atomic Weights
Carbon
12.011
Hydrogen
1.00794
Oxygen
15.9994
Nitrogen
14.00674
Sulphur
32.066
ISO 6976 - 1983
Component
Mole%
Normalised
Methane
86.978821 0.8697918
Ethane
7.101859 0.0710189
Propane
2.094905 0.0209491
N-Butane
0.386079 0.0038608
I-Butane
0.218057 0.0021806
N-Pentane
0.066633 0.0006663
I-Pentane
0.064865 0.0006487
Neo-Pentane
0
0
N-Hexane
0.046202 0.000462
2-Methylpentane
0
0
3-Methylpentane
0
0
2,2-Dimethylbuta
0
0
2,3-Dimethylbuta
0
0
N-Heptane
0
0
2-Methylhexane
0
3-Methylhexane
0
N-Octane
0
0
N-Nonane
0
0
N-Decane
0
0
2,2,4-Trimethylpentane
0
Cyclohexane
0
Methylcyclohexane
0
Benzene
0
0
Toluene
0
0
Hydrogen
0
0
CO
0
0
H2S
0
0
Helium
0
0
Argon
0
0
Nitrogen
0.862475 0.0086248
Oxygen
0
0
CO2
2.179687 0.021797
Water
0
0
Air
0
0
TOTAL

99.99958

Molec Wieght

18.699719

Ideal Density
Summation

AU

AV

AW

Zmix

0.9973528

CV Sup (Ideal)
CV Sup (Real)

40.459696
40.567084 MJ/m3

Ideal RD
Real RD

0.64564
0.6470801

Wobbe (MJ/m3)

50.430672

AX

Table 2
(15,1.01325)
Molec Weigh Ideal RD Ideal Density
16.04260
0.5539
0.6785
30.06940
1.0382
1.2717
44.09620
1.5224
1.865
58.12300
2.0067
2.4582
58.12300
2.0067
2.4582
72.14980
2.491
3.0514
72.14980
2.491
3.0514
72.14980
2.491
3.0514
86.17660
2.9753
3.6477
86.17660
2.9753
3.6477
86.17660
2.9753
3.6477
86.17660
2.9753
3.6477
86.17660
2.9753
3.6477
100.20340
3.4596
4.2379
100.20340
3.4596
4.2379
100.20340
3.4596
4.2379
114.23020
3.9439
4.8312
128.25780 4.4281645
142.28468 4.9124495
114.23020
3.9439
4.8312
84.16080
2.9057
3.5593
98.18760
3.39
4.1527
78.11340
2.6969
3.3037
92.14020
3.1812
3.8963
2.01580
0.0696
0.0852
28.01040
0.9671
1.1846
34.07600
1.1765
1.4412
4.00260
0.1382
0.1693
39.94800
1.3792
1.6895
28.01340
0.9672
1.1848
31.99880
1.1048
1.3533
44.00980
1.5195
1.8613
18.01520
0.622
0.7619
28.96410
1
1.225

0.79088 C9&C10 have zero value at the moment

0.05145

#VALUE!
Rel Mol Mass

-100
STD Density (Real)

Atomic Weight
12.011
1.00794
15.9994
14.00674
32.066
Composition
Component
Molec Weight Un-rounded Molecular Weight
C H O N S
Methane
16.04276 1 4
16.043
Ethane
30.06964 2 6
30.07
Propane
44.09652 3 8
44.097
N-Butane
58.1234 4 10
58.123
I-Butane
58.1234 4 10
58.123
N-Pentane
72.15028 5 12
72.15
I-Pentane
72.15028 5 12
72.15
Neo-Pentane
72.15028 5 12
72.15
N-Hexane
86.17716 6 14
86.177
2-Methylpentane
86.17716 6 14
86.177
3-Methylpentane
86.17716 6 14
86.177
2,2-Dimethylbuta
86.17716 6 14
86.177
2,3-Dimethylbuta
86.17716 6 14
86.177
N-Heptane
100.20404 7 16
100.204
N-Octane
114.23092 8 18
114.231
N-Nonane
128.2578 9 20
128.258
N-Decane
142.28468 10 22
142.285
Cyclopentane
70.1344 5 10
70.134
Methylcyclopenta
84.16128 6 12
84.161
Ethylcyclopentan
98.18816 7 14
98.188
Cyclohexane
84.16128 6 12
84.161
Methylcyclohexan
98.18816 7 14
98.188
Ethylcyclohexane
112.21504 8 16
112.215
Benzene
78.11364 6 6
78.114
Toluene
92.14052 7 8
92.141
Ethylbenzene
106.1674 8 10
106.167
o-Xylene
106.1674 8 10
106.167
Methanol
32.04216 1 4 1
32.042
Methanethiol
48.10876 1 4
1
48.109
Hydrogen
2.01588
2
2.0159
Water
18.01528
2 1
18.0153
H2S
34.08188
2
1
34.082
Ammonia
17.03056
3
1
17.0306
HCN
27.02568 1 1
1
27.026
CO
28.0104 1
1
28.01
Carbonyl Sulfide
60.0764 1
1
1
60.076
Carbon Disulfide
76.143 1
2
76.143
Helium
4.0026
4.0026
Neon
20.1797
20.1797
Argon
39.948
39.948
Nitrogen
28.01348
2
28.0135
Oxygen
31.9988
2
31.9988
CO2
44.0098 1
2
44.01
SO2
64.0648
2
1
64.065
Dinitrogen Monox
1 2
44.0129
44.0129
Krypton
83.8
Xenon
131.29
Air
28.9626
Carbon
Hydrogen
Oxygen
Nitrogen
Sulphur

ISO 6976 1983 (Tweaked for C9 & C10) starts at column AO

BG
S500
38.90381
38.902
-4.100058 -4.104519 %errors

AY

AZ

BA

BB

BC

BD

BE

Table 6
Table 8
CV Hsup
CV Hinf Z (15,1.013 Summation Component
37696
33938
0.998
0.0447 Methane
66035
60397
0.9914
0.0927 Ethane
93975
86459
0.9806
0.1393 Propane
121782
112387
0.9634
0.1913 N-Butane
121428
112034
0.9659
0.1847 I-Butane
149676
138402
0.944
0.2366 N-Pentane
149336
138062
0.9499
0.2238 I-Pentane
148850
137576
0.9579
0.2052 Neo-Pentane
177556
164401
0.9115
0.2975 N-Hexane
177230
164075
0.9198
0.2832 2-Methylpentane
177342
164187
0.9193
0.2841 3-Methylpentane
176837
163683
0.9307
0.2632 2,2-Dimethylbutane
177179
164024
0.9245
0.2748 2,3-Dimethylbutane
205432
190398
0.8653
0.367 N-Heptane
205133
190099
0.8781
0.3491 2-Methylhexane
205276
190242
0.8781
0.3491 3-Methylhexane
233287
216374
0.7986
0.4488 N-Octane
261189.65
0.7100
0.5385 N-Nonane
289063.66
0.5840
0.645 N-Decane
232645
215732
0.8611
0.3727 2,2,4-Trimethylpentane
167311
156037
0.9183
0.2858 Cyclohexane
194722
181569
0.8811
0.3448 Methylcyclohexane
139694
134057
0.9277
0.2689 Benzene
167054
159537
0.8824
0.3429 Toluene
12102
10223
1.0006
0 Hydrogen
11966
11966
0.9995
0.0224 CO
23807
21967
0.9904
0.098 H2S
1.0005
-0.016 Helium
0.9992
0.0283 Argon
0.9997
0.0173 Nitrogen
0.9993
0.0265 Oxygen
0.9943
0.0614 CO2
0.971
0.17 Water
0.99958
0 Air

BF