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Combustion Calorimetry of Organic Bromine Compounds: The Accuracy of Data Obtained With A Moving-Bomb Technique
Combustion Calorimetry of Organic Bromine Compounds: The Accuracy of Data Obtained With A Moving-Bomb Technique
Department
of Organic Chemistry,
University
of Lund,
Lund, Sweden
45
LARS BJELLERUP
Table 1.
Density and refractive indices for the samples used in the heat of combustion
experiments
nn
(gJml)
Compound
1,2-Dibromobutane
1,2-Dibromocyclohexane
1-Bromopropane
2-Bromopropane
2-Bromobutane
20C
25C
20C
25C
17954
17903
13550
13142
12607
17870
17833
13465
13055
12533
15149
15529
1-4346
14255
1'4370
15125
15506
1-4320
1-4226
1-4345
- t::.Hc (kcaIJmole)
1,2-Dibromobutane
1,2-Dibromocyclohexane
I-Bromopropane
2-Bromopropane
2-Bromobutane
61415
86745
49150
49037
64650
t::.Hv (kcalJmole)t
054
060
034
042
030
1080
775
730
845
020
020
020
025
* The uncertainties given in this column are equal to twice the final" over-all" standard deviation.
t The values given in this column refer to the process C a HbBrd(l.) ~ C aHbBrd(g." at saturation pressure
at 25C. The uncertainties given are estimated.
Substance
From heat of
combustion
data
1,2-Dibromobutane (g)
- 2454
1,2-Dibromocyclohexane (Iiq.)
I-Bromopropane (g)
- 3846
- 2202
060
040
2-Bromopropane (g)
2.;Bromobutane (g)
- 2360
- 2869
058
046
040
From other
heat of
reaction data
-
2247
2158
4015
2177
2113
2407
2855
Difference
O44a - 207
063 b
- 296
046 c + 169
034d
- 025
0-40 e I - 089
024' + 0-47
030g
- 014
070
078 b
076
052
057
052
050
46
Acta Chern.
References
L. Bjellerup. Acta Chem. Scand., 13, 1511 (1959); 14, 617 (1960)
D. R. Stull. Ind. Eng. Chem., 39, 517 (1947)
3 R. R. Dreisbach.
Pressure-Volume-Temperature Relationships of Organic Compounds, 3rd
Ed., Handbook Publishers, Sandusky (1952)
4 T. E. Jordan.
Vapor Pressure of Organic Compounds, Interscience, New York (1954)
5 J. B. Conn, G. B. Kistiakowsky and E. A. Smith.
]. Am. Chem. Soc., 60, 2764 (1938)
6 M. W. Lister.
]. Am. Chem. Soc., 63, 143 (1941)
7 J. R. Lacher, A. Kianpour andJ. D. Park.
J. Phys. Chem., 61, 1124 (1957)
8 J. R. Lacher, C. H. Walden, K. R. Lea and ]. D. Park.
J. Am. Chern. Soc., 72, 331 (1950)
9 J. R. Lacher, T.J. Billings, D. E. Campion, K. R. Lea and ]. D. Park.
]. Am. Chern. Soc.,
74, 5291 (1952)
10 J. R. Lacher.
Personal communication (1957)
1
P.A.C.
47