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(Edu - Joshuatly.com) Johor Trial STPM 2010 Chemistry Paper 2 (FA9124A4)
(Edu - Joshuatly.com) Johor Trial STPM 2010 Chemistry Paper 2 (FA9124A4)
composition
1. An orlanicacidhasthefollowing by mass'
C, 4O.OW 6.7%; .O' 53*3%'
-H,
ion)at the followingm/e
ItsmassspectrumshowErrjor pea'kt(inc[idingthe molecular
v a l u e s1:5,43 ,4 5 ,6 0 .
(a) (i) Calculate of the acid'
theempiricalformula [2 marks]
O
F\er"en\
ril
r)
&t #lr '
6'1 17i
pffo 3'13
*L r\
".l' zl
<
^p(eCi,,
Ir - \J
"
Srt'r^^y'
:. eqgdcat
formula'
to suggestits molecular
(ii) Usethe massspectrum [1 mark]
(cH"Q\=60
Qdn --oo
h:Z -Sr*u\q\9 C.Hl.0i
| . rno\ecrr\qn
t'/ (
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CONFIDENTIAL* 4
?H--).ss ar(an\ddo"
* LW
\hQ add *
Y1r2
tH-l= 1p-2's5 = t4 -^, - W,t
SA-i
[ml'-''*t"tdt .ffifn
ffi ,,
thl.W- =016l^ "V-7
^
x.a= Ci'ttxratl
I'.
6lffidrn_1
-/
Ka=q-"r6xt01ry\4il 1/
2. (a) Define
tc\sa+A
-\*d.
(i) FirstelectronaffinitY {f
^/--
\s_ihe edih$l
"": J
gMS
E^ eldtun {" $nn q-): (
il ,^,rKS'q.vqsqhlet
affinity-\*A
(ii) Secondelectron qb$fo
thefirstandsecondelectronaffinityfor an oxygen
(b) Writethe equationto represent
atom.
t g- ) 0 .S$...-...../
Firsterectronarrinity,....Q..$)
0.:.S.S)+{ )
seconderecrronarrinity, O-SC ?
/
[2 marks]
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CONFIDENTIAL-
(c) Thefirstelectron
affinity
for oxygenatomis -141kJmol-1
whereasthesecondelectron
affiiityforoxygenis +798kJmol'1.Explain
whythefirstelectron
affinity
is exothqrmic
while
thesecond etectron
affinity
is endothermic. tk<\^n \tGn&t(U)tz marrsl
1t( S.* eldro ct+{l'\nl
S edlqrnlckcry5pt\ea\[UerUH,
whe( on
te!-nti qdids 4bgn,
su;'dd"il q$t{U
1ie'urtrr*r.
wh1.qr e\edr.on
buqnsn t o l.s{Nqsogd igls,
k 3ddgal
{lr? t tii {Aflrio,r) -tt"rkd*"
5qh"eh r
(d) IntheContactProcess,
sulphurdioxideis changed
to sulphurtrioxideaccordingto the
reaction below;
4500c
+oz(s)
2so21g1 # 2so31s1 A H = -189kJ mol-1
S\x"
tAs;G/ ,p.. v"
5 'hv V
qv
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CONFIDENTIAL-
3d
Mn
1 1 1 1 1
Mn2* 1 1 1 1 1.
Mn3*
[];
1 Q- V'("'i!
(ii)Explainthe relativestabilityof Mn2*ion and Mn3*.,ion. I lZ marksl
>'[ ^, ..( 't\an \ rn flr\ | q r l.iT\
fY\n'*\s
" nror?
Me
rt ., .,n^ zf
CIA.* -
$nce
,^- *t
tA',lhosq. hq\$4\\ed Ug6\\
t,ri. ;;,";,i,;;";";;.;;;; r,,i,,ion,J;,
;;";;,.,",.;^;;;;H
for the colour?
responsible [1 markl
rntit foh}, ,{ (MnQro)*
(b)Thedecomposition of nitratesof Group2 elements(beryllium
temperature to barium)is
shownbelow.
) nrhqtsq
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lotr.uoU p",-qrc\es@t, cWlL /rytt'g d00,'e0d
CONFIDENTIAL*
4. Consider
thefollowing
reaction
scheme:
(A )
CaHeBr
KOHin alcohol
Reflux
c4Hloo ( B ) c c Ha (D)
Oxidation HBT
(C)
C+HeOz C+HgBr( E )
(a) Drawthestructuralformula
for compounds
A, B, C andD. [4 marks]
\ H $ r{ \-\I
F\-C-q-c*(*r-,r '-\ t J!_
H-!-C,
t\\\hL" h n \^yy r'
/
Compound
A Compound
B
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CONFIDENTIAL-
a \1 lt' F lil
$L C-O-\{
/
\-{-c-GC=i-H
J
'\ ./
,..
Compound
C Compound
D
tt *:,l" ti{"itins
unitrorthe
porvmer,?''T
tpry"'oound
D.
t,!,-.=[$^
n*Gh
[1 mark]
(ii)statethe suitableconditions
requiredto to
gnvertcompound,B
comPound
c'
qg&tud ,/
| t marksl
Reasent:
, ...;.Kflt'0.'A . .- ..:...
condition:
,ffi teftlyZ t
(d)(i) Drawthe optical
uisomers
ruuruels
for
rorComp
uompound
E. [1 mark]
fl
.'Ct.
c\a\i 'cHr
n ,l
|\)c- "t-cn,cf\3
A A A
{ . q E',/
(ii) Namethe mixturethatcontainsequimolar
quantities
of opticalisomers
ison butis
optically
inactive.
[1 mark]
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(
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CONFIDENTIAL* t4
(b) Thefrequencies,
f of the linesin the Lymanseriesof hydrogenspectrumaregiven
by theexpression
below.
f =cRuf1-1)
' \ 1'
nt)
6. (a)(i) Definethetermstandarderectrode
potentiar.
[1 mark]
[4 marks]
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CONFIDENTIAL"
16
(b)Predicttheproductthatwouldbe
obtainedfromthe etectrolysis
of thefollowing
aqueoussolutionsusingptatinum
electrodes: r{\
(i) Coppe(lt)chtoride
(ii) Hydrochlor.ic
acid
(iii) Potassium
hydroxide
[6 marksJ
(c) An industrially
importantsourceof hydrogenis the reaction
below:
Enthalpy
changeof combustion
,
AH" / kJmol-l
[4 marksJ
7. (a)(i) statethetwoindustriar
stagesof preparing
nitrogengasfromair.
q0
v:)?..
(c) At temperature
of 320K anda pressure of 1.0x105Pa,0.50g of thegaseous
d{"1]
No2/N2o4 mixturetakesup a vorumeof 190cm! o'*9
Calculate
theaveragerelative molecular Giveyouranswer 0'\%7"
massof themixture.
correctto 3 significant
figures. [2 marks]
(d) Theequation
for the decomposition pentoxide,
of dinitrogen NzOs,
is as shownbelow.
Thereaction
aboveis a firstorderreaction
andthe half-life
is 2.7x 103s.
(i) Writethe rateequationfor the reaction.
(ii) Determinetherateconstant.
(iii) Determine
therateof reaction
whentheconcentration
of NzOsis
3.1x 102moldm-3. [5 marks]
(b)Givetwousesof aluminium
andrelatetheusesto itsproperties [4 marks]
(c ) Explain
whyan aqueous
solution
of ammonia
doesnotcontainNHooH
molecules. [2 marks]
(d)Writean equation
to showthe roleof ammonia
as a
(i) base and
(ii) complexing
agent [2 marks]
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CONFIDENTIAL- 20
9. (a) Methylbenzene
reactswithchlorineundertwodifferentsetsof conditions
to give
compound
A or compound
B.
ra
Y
fn,
cl
A
6' B
(i) Describetheconditions
usedto produce
A andB respectively.
(ii) Describe
a reaction
bywhichyoucoulddistinguish
between
A andB. Statethe
reagents
andtheobservations
witheachcompound. [5 marks]
(b)Duringaromaticsubstitution,
theposition
of theincoming group,the neWsubstituent,
is determinedbythe natureof thegrouparreadypresentin thering.
Usethisknowledge to devisetwostepsyntheses of 3-nitrobenzoic
acid,startingwith
methylbenzene.
ldentifythe reagentsat eachstep,anddrawthe structural
formulaeof the
intermediates.
[3 marks]
(c)Benzocaine
canbe synthesized
from4-nitrobenzoic
acidin twostages.
PooH cooH
PoocH,cH3
rb
>a
c
--------) lol
-^t.
DrA
---.---+Y
NO,
YNHz
NHz
Suggestreagents
andconditions
forstepsC andD. [3 marks]
(d)Foreachof thefollowing
compounds,
describe
onesimplechemical
testbywhichyou
coulddistinguish
it frompropanone,
CH3COCH3.
(i) methylethanoate, CH3COOCH3
(ii) propanal,
CH3CH2CHO.
Foreachteststatethereagents
youwoulduse,andtheobservations
youwould
makewitheachcompound undergoing
thetest.
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CONFIDENTIAL* 22
10.Thestructure
belowshowspartof a proteinmolecule.
CHz
7 I I
CHz CHz
I I I
OH cooH CH,
I
CH,
I
CH,
I
NHz
( i i )p H= 1 3
[4 marks]
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