d PA

1. =A 1 P A ( k 1 +k 3 )
dz

d PB
2. = A 1 ( k 1 P A k 2 PB )
dz

d PC
3. =A 1 ( k 3 P Ak 2 P B )
dz

dT
4. =B2 ( k 1 P Ak 2 P B ) + B3 ( k 3 P A +k 2 PB ) C 1 ( T T c )
dz

d Tc
5. =D1 ( T T c )
dz

a1
k 1=exp ( b1 )
T

a2
k 2=exp ( b2 )
T

a3
k 3 =exp ( b3 )
T

Reemplazando;

1.
d PA
dz
a
T ( ( ) a
=A 1 P A exp b1 1 + exp ( b 3 3 )
T )
d PB a a
2.
dz (
= A 1 P A exp ( b1 1 )P B exp ( b2 2 )
T T )
d PC a a
3.
dz (
=A 1 P A exp ( b3 3 )P B exp ( b 2 2 )
T T )
a a a a
4.
dT
dz ( T T ) ( T A T )
=B2 P A exp ( b 1 1 )P B exp ( b 2 2 ) + B 3 exp ( b3 3 )P + P B exp ( b2 2 ) C 1 ( T T c )
 d Tc
5. =D1 ( T T c )
dz

Ecuaciones variacionales;

1.
d S1
dz ( ( a
T ) a
T ) ( ( a
=A 1 exp b 1 1 +exp ( b3 3 ) S1 A 1 P A exp b 1 1
T )( Ta )+ exp(b aT )( Ta )) S
1
2 3
3 3
2 4

d S1
dz ( ( )[
a
T
a
T ] a
T [a
=A 1 exp b1 1 S1 + 12 P A S 4 +exp ( b 3 3 ) S 1 + 32 P A S4
T ])

2.
d S2
dz ( a
T ) ( a
T ) ( a a
T T ( ) a a
( ))
=A 1 exp b 1 1 S 1+ A 1 exp b2 2 S2 + A1 P A exp (b 1 1 ) 12 PB exp (b2 2 ) 22 S 4
T T

.
d S2
dz ( ( )[ a
T
a
T ] ( )[ a
T
a
=A 1 exp b1 1 S1 + 12 P A S 4 exp b 2 2 S2 + 22 PB S 4
T ])

3.
d S3
dz ( a
T ) ( a
T ) ( a a
T T ( ) a a
( ))
=A 1 exp b 3 3 S 1+ A 1 exp b2 2 S2 + A 1 P A exp ( b3 3 ) 32 P B exp ( b 2 2 ) 22 S 4
T T

d S3
dz ( ( )[a
T
a
T ] ( )[
a
T
a
= A1 exp b 3 3 S1 + 32 P A S4 +exp b2 2 S2 + 22 P B S 4
T ])
 a a a a
dT
dz ( T T ) ( T A T )
=B2 P A exp ( b 1 1 )P B exp ( b 2 2 ) + B3 exp ( b3 3 ) P + P B exp ( b2 2 ) C 1 ( T T c )

4.
d S4
dz ( a
T
a
T ) ( a
T ( a
)) (( a a
= B2 exp ( b1 1 )+ B3 exp ( b3 3 ) S 1+ B3 exp ( b2 2 )B2 exp b2 2 S 2+ B2 P A exp ( b1 1 )
T T T

d S4
dz ( ( )[
a a
T ] ( )[a
T
a
T ]) ( ( )[
a
T
a
=B 2 exp b 1 1 S 1 + 12 P A S4 exp b2 2 S 2+ 22 P B S 4 + B3 exp b3 3 S 1+ 32 P A S 4 + exp ( b 2
T T ]
d S5
5. =D1 ( S 4S5 )
dz