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Data Booklet
Appendix
Data
Booklet
Cambridge International A & AS Level Chemistry 9701. Examination in June and November 2012.
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6. Appendix
Cambridge International A & AS Level Chemistry 9701. Examination in June and November 2012.
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6. Appendix
Cambridge International A & AS Level Chemistry 9701. Examination in June and November 2012.
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6. Appendix
Cambridge International A & AS Level Chemistry 9701. Examination in June and November 2012.
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6. Appendix
Bond energies
(a) Diatomic molecules (b) Polyatomic molecules
Cambridge International A & AS Level Chemistry 9701. Examination in June and November 2012.
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6. Appendix
Electrode reaction
E /V
Ag+ + e Ag +0.80
Al 3+ + 3e Al 1.66
Ba2+ + 2e Ba 2.90
Br2 + 2e
2Br
+1.07
Ca2+ + 2e Ca 2.87
Cl 2 + 2e 2Cl +1.36
2HOCl + 2H+ + 2e Cl2 + 2H2O +1.64
2+
Co + 2e
Co 0.28
Co3+ + e Co2+ +1.82
[Co(NH3)6]2+ + 2e Co + 6NH3 0.43
2+
Cr + 2e
Cr 0.91
Cr3+ + 3e Cr 0.74
3+
Cr + e
Cr 2+
0.41
2
Cr2O7 + 14H + 6e +
3+
2Cr + 7H2O +1.33
Cu+ + e Cu +0.52
2+
Cu + 2e
Cu +0.34
Cu2+ + e Cu+ +0.15
[Cu(NH3)4]2+ + 2e Cu + 4NH3 0.05
F2 + 2e
2F
+2.87
Fe2+ + 2e Fe 0.44
Fe3+ + 3e Fe 0.04
3+
Fe + e
Fe 2+
+0.77
Cambridge International A & AS Level Chemistry 9701. Examination in June and November 2012.
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6. Appendix
Electrode reaction
E /V
[Fe(CN)6]3 + e [Fe(CN)6]4 +0.36
Fe(OH)3 + e Fe(OH)2 + OH 0.56
+
2H + 2e
H2 0.00
I2 + 2e 2I +0.54
K+ + e K 2.92
+
Li + e
Li 3.04
Mg2+ + 2e Mg 2.38
Mn2+ + 2e Mn 1.18
3+
Mn + e
Mn 2+
+1.49
MnO2 + 4H+ + 2e Mn2+ + 2H2O +1.23
MnO + e 4
MnO 4
2
+0.56
MnO4 + 4H + 3e +
MnO2 + 2H2O +1.67
MnO4 + 8H+ + 5e Mn2+ + 4H2O +1.52
NO3 + 2H + e +
NO2 + H2O +0.81
NO3 + 3H+ + 2e HNO2 + H2O +0.94
NO3 + 10H+ + 8e NH4+ + 3H2O +0.87
Na + e+
Na 2.71
Ni2+ + 2e Ni 0.25
[Ni(NH3)6]2+ + 2e Ni + 6NH3 0.51
H2O2 + 2H + 2e +
2H2O +1.77
O2 + 4H+ + 4e 2H2O +1.23
O2 + 2H2O + 4e
4OH
+0.40
O2 + 2H + 2e +
H2O2 +0.68
2H2O + 2e H2 + 2OH 0.83
2+
Pb + 2e
Pb 0.13
Pb4+ + 2e Pb2+ +1.69
PbO2 + 4H+ + 2e Pb2+ + 2H2O +1.47
2
SO4 + 4H + 2e +
SO2 + 2H2O +0.17
S2O82+ 2e 2SO42 +2.01
Cambridge International A & AS Level Chemistry 9701. Examination in June and November 2012.
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6. Appendix
Electrode reaction
E /V
S4O62+ 2e 2S2O32 +0.09
Sn2+ + 2e Sn 0.14
4+
Sn + 2e
Sn 2+
+0.15
V2+ + 2e V 1.20
3+
V +e
V 2+
0.26
2+
VO + 2H + e +
3+
V + H2O +0.34
VO2+ + 2H+ + e VO2+ + H2O +1.00
VO3 + 4H + e +
2+
VO + 2H2O +1.00
Zn2+ + 2e Zn 0.76
All ionic states refer to aqueous ions but other state symbols have been omitted.
Cambridge International A & AS Level Chemistry 9701. Examination in June and November 2012.
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6. Appendix
Electrode reaction E /V
F2 + 2e 2F +2.87
S2O82+ 2e 2SO42 +2.01
H2O2 + 2H + 2e +
2H2O +1.77
MnO4 + 8H+ + 5e Mn2+ + 4H2O +1.52
PbO2 + 4H+ + 2e Pb2+ + 2H2O +1.47
Cl 2 + 2e
2Cl
+1.36
Cr2O72 + 14H+ + 6e 2Cr3+ + 7H2O +1.33
Br2 + 2e 2Br +1.07
NO3 + 2H + e +
NO2 + H2O +0.81
Ag+ + e Ag +0.80
Fe3+ + e Fe2+ +0.77
I2 + 2e
2I
+0.54
O2 + 2H2O + 4e 4OH +0.40
Cu2+ + 2e Cu +0.34
2
SO4 + 4H + 2e +
SO2 + 2H2O +0.17
Sn4+ + 2e Sn2+ +0.15
2
S4O6 + 2e
2S2O 3
2
+0.09
+
2H + 2e
H2 0.00
Pb2+ + 2e Pb 0.13
2+
Sn + 2e
Sn 0.14
2+
Fe + 2e
Fe 0.44
Zn2+ + 2e Zn 0.76
2+
Mg + 2e
Mg 2.38
Ca2+ + 2e Ca 2.87
K+ + e K 2.92
Cambridge International A & AS Level Chemistry 9701. Examination in June and November 2012.
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6. Appendix
(b) Group II
metallic Be 0.112 Be2+ 0.031
Mg 0.160 Mg2+ 0.065
2+
Ca 0.197 Ca 0.099
2+
Sr 0.215 Sr 0.113
Ba 0.217 Ba2+ 0.135
2+
Ra 0.220 Ra 0.140
(c) Group IV
single covalent C 0.077
Si 0.117 Si4+ 0.041
2+
Ge 0.122 Ge 0.093
Cambridge International A & AS Level Chemistry 9701. Examination in June and November 2012.
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6. Appendix
Cambridge International A & AS Level Chemistry 9701. Examination in June and November 2012.
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6. Appendix
Cambridge International A & AS Level Chemistry 9701. Examination in June and November 2012.
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The Periodic Table of the Elements
Group
I II III IV V VI VII 0
1.0 4.0
H He
hydrogen helium
Key 1 2
6.9 9.0 relative atomic mass 10.8 12.0 14.0 16.0 19.0 20.2
Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
3 4 atomic number 5 6 7 8 9 10
23.0 24.3 27.0 28.1 31.0 32.1 35.5 39.9
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfurchlorine argon
11 12 13 14 15 16 17 18
39.1 40.1 45.0 47.9 50.9 52.0 54.9 55.8 58.9 58.7 63.5 65.4 69.7 72.6 74.9 79.0 79.9 83.8
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
85.5 87.6 88.9 91.2 92.9 95.9 101 103 106 108 112 115 119 122 128 127 131
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd n Sn Sb Te Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
133 137 139 178 181 184 186 190 192 195 197 201 204 207 209
Cs Ba La Hf Ta W Re Os r Pt Au Hg Tl Pb Bi Po At Rn
caesium barium lanthanum hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
55 56 57 * 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Fr Ra Ac Rf Db Sg Bh Hs Mt Uun Uuu Uub Uuq Uuh Uuo
francium radium actinium * rutherfordium dubnium seaborgium bohrium hassium meitnerium ununnilium unununium ununbium ununquadium ununhexium ununoctium
87 88 89 * 104 105 106 107 108 109 110 111 112 114 116 118
140 141 144 150 152 157 159 163 165 167 169 173 175
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
anthanides
* cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
58 59 60 61 62 63 64 65 66 67 68 69 70 71
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinides *
* thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
90 91 92 93 94 95 96 97 98 99 100 101 102 103