.

150 75

90 60

r Gm K

1.

B( g ) G m , B

1
 f Gm r Gm

2.

1 B( g ) G m , B

2 r Gm

4 f Gm f Gm

r Gm

5 E r Gm

1.

2.

1.

2.

1.

sol Gm ( B ) B sol G B

2.

1 sol G B sol G B

2 r G m

1.

2.

2 Ea k 0

1.

2.

1.

2.

1.

2.

3
 1

1.

2.

1.

2.

1.

2.

1.

2.

1.

2.

1.

CaO-SiO2-Al2O3 CaO-SiO2-FeO

2.

1 CaO-SiO2-Al2O3 CaO

2 CaO-SiO2-FeO FeO

1.

2.

C-H-O

1.

2.

5
 1

1.

2.

CHO

1.

2.

1.

CO

100
MO CO CO H 2
1 K 3

2.

1.

2.

1 CO-CO2 Fe

1.

(SiO2)

2.

2(SiO2)

1.

S S S

2.

1 S S

2 S

1.

2.

MnSiCr

7
1.

Mn Si Cr

2.

1 Mn Mn

2 Si Si

3 Cr

1.

2.

1.

2.

2 [P][C]

1.

2.

1.

Mn Si Al

2.

2 Mn Si Al

8
 .


75

150

6 15 90

5 CO H 2

3 20 60

1 3C()+TiO2(s)=TiC(s)+2CO(g)

f Gm( CO )=(-11440085.77T)Jmol-1

f Gm( TiC )=(-18480012.55T)Jmol-1

f Gm( TiO2 )=(-941000177.57T)Jmol-1

2 [C ] 5.0% [ S ] 0.05% [ Mn] 2.0% [ Si ] 1%

S Si C Mn
1873K e S 0.028 e S =0.063 e S =0.112 e S =0.026

3 100KPa SiO2(s) 0.1 1%

SiO2(s) CO SiO2

2C() O2 2CO r G m (1) (228800 171.54T ) J mol 1 1

[ Si ] O2 SiO2 ( s ) r G m ( 2) (814850 215.25T ) J mol 1 2

15 90

1 r G 0 5

r G 0 5

r G 0 5

2 or

10

3CaO 7

2CaO SiO2 8

p B ( Am Bn ) 7

5 t 810C CO H 2 8

t 810C H 2 CO 7

6
5

20 60

rGm =2f Gm(CO)+f Gm(TiC) -f Gm(TiO2) 8

=(527400-336.56T)Jmol-1 2

rGm=-RTlnK=-19.147TlgK 8

lgK=-527400/(19.147T)+336.56/(19.147T)

=(-27545/T+17.58)Jmol-1 2

2 lg f S e SS [ S ] e SSi [ Si ] e SC [C ] e SMn [ Mn]

0.028 0.05 0.063 1 0.112 5 0.026 2 0.57 8

f S 3.71 4

10
 a S (%) f S [ S ] 3.71 0.05 0.186 8

3(1)-(2)

SiO2 ( s ) 2C ( ) [ Si ] 2CO r G m (3) (586050 386.79T ) J mol 1 3

6

a[ Si ] ( PCO / P ) 2 0 . 1 12
r G(3) r G m (3) RT ln 586050 386.79T RT ln 6
a SiO2 a C( ) 11

r G( 3 ) 0 T T1444 K 8

11

.

150 75

10 5 10 2 10

2 60

1.

2.

1.

2.

12
1

1.

2.

1.

5 5

2.

10

1.

2.

13


1.

2.

1.

2.

10

11

1.

2.

14
3

1.

2.

1.

2.

1.

2.

1.

2.

15
1

4 CO

7-

9 MnSi

10 Mn [Si]

11

1.

2.

1.

16


2.

1.

2.

1.

2.

7P/H

1.

17


2.

1.

CO

2.

3CO

1.

2.

1.

2.

18
1

1.

2.

1.

2.

1.

2.

19
2

1.

2.

1.

2.

1.

2.

1.

20
2.

1.

2.

1.

2.

1.

2.

1.

2.

21
1.

2.

1.

2.

1.

2.

1.

2.

1.

2.

22
 1

1.

2.

1.

2.

1.

2.

23
1.

2.

1.

2.

1.

DH RH ASE-ASKF VAD LF VOD AOD

CLU

2.

1.

2.

1.

2.

24
1.

2.

1.

2.

25
 .


75

150

10 5 50

8RH

10

10 2 20

__________

2 FexO __________ FexO

Fe3O4+-Fe

__________

4__________

5__________

6__________

7__________

8__________

26
 9__________

10__________

10 2 20

ABCD

ABCD

ABCD

4[Si]

A3%B30%C0.3%D0.03%

A85%B25%C50%D100%

A B C D

A B C D

A B C D

9FeO

A3-5% B8-15% C1525% D25-35%

10

A B C D

4 15 60

27

10 5 50

1 t/m3d

4 CO

9m/min

10

10 2 20 2 0

125703//45

678 S910

10 2 20 2

1C2B3C4C5A6B7A8B9B10D

4 15 60 .

1 1

25

28
 3

2 1

2 1kg 4

33

4 CO+H2 4

314

24

34

43

413

23

33

43

53

29