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  • Kimia Kapita Selekta

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    Ita Asfuriyah
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    The document summarizes the pH calculations for two chemical reactions: 1) Mixing 100 ml of 0.2 M CH3COOH and 100 ml of 0.1 M NH4OH, which results in a pH of 3.651. 2) Mixing 100 ml of 0.1 M CH3COOH and 100 ml of 0.2 M NH4OH, which is calculated to have a pH of 10.8496. The calculations involve determining the initial concentrations of H+ and OH- ions from each solution, adding them together, and calculating the final pH.

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    The document summarizes the pH calculations for two chemical reactions: 1) Mixing 100 ml of 0.2 M CH3COOH and 100 ml of 0.1 M NH4OH, which results in a pH of 3.651. 2) Mixing 100 ml of 0.1 M CH3COOH and 100 ml of 0.2 M NH4OH, which is calculated to have a pH of 10.8496. The calculations involve determining the initial concentrations of H+ and OH- ions from each solution, adding them together, and calculating the final pH.

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    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
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    13 views2 pages

    Kimia Kapita Selekta

    Uploaded by

    Ita Asfuriyah
    The document summarizes the pH calculations for two chemical reactions: 1) Mixing 100 ml of 0.2 M CH3COOH and 100 ml of 0.1 M NH4OH, which results in a pH of 3.651. 2) Mixing 100 ml of 0.1 M CH3COOH and 100 ml of 0.2 M NH4OH, which is calculated to have a pH of 10.8496. The calculations involve determining the initial concentrations of H+ and OH- ions from each solution, adding them together, and calculating the final pH.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as docx, pdf, or txt
    of 2

    12.

    100 ml 0,2 M CH3COOH + 100 ml 0,1 M NH4OH


    a. pH asam b. pH basa
    100 ml 0,2 M CH3COOH 100 ml 0,1 M NH4OH
    CH3COOH(aq) CH3COO (aq) + H (aq)
    - +
    NH4OH(aq) NH4+(aq) + OH- (aq)
    [H ] = K a x M a
    +
    [OH-] =
    K b x [ NH 4 OH ]
    [H ] = 10 x 2 x 10
    + 6 1
    [OH ] = 105 x 101
    -

    [H+] = 4,47 x 10-4 [OH-] = 10-3


    pH = -log H+ pOH = - log [OH-]
    pH = - log 4,47 x 10-3 pOH = - log 10-3
    pH = 3 log 4,47 pOH = 3 pH = 11

    c. pH setelah dicampur
    CH3COOH(aq) + NH4OH(aq) NH4CH3COO(aq) + H2O(l)
    m 20 10 0 0
    r 10 10 10 10
    s 10 0 10 10

    [H+]1 = Ka M [H+]2 =
    Kw x Ka
    Kb
    =
    106

    = 5. 108
    10
    200
    =
    =
    1014 x 106

    10 x 1016
    10
    5

    -4
    = 2.24 . 10 M = 3,16 x 10-8 M
    [H+] total = [H+]1 + [H+]2
    = 2.24 . 10-4 + 3,16 x 10-8
    = 22363.16 x 10-8
    pH = - log [H+]
    = - log (22363.16 x 10-8)
    = 8 log 22363.16
    = 8 4.349
    = 3.651

    13.100 ml 0,1 M CH3COOH + 100 ml 0,2 M NH4OH


    a. pH asam b. pH basa
    100 ml 0,1 M CH3COOH 100 ml 0,2 M NH4OH
    CH3COOH(aq) CH3COO-(aq) + H+(aq) NH4OH(aq) NH4+(aq) + OH- (aq)
    [H+] = K a x M a [OH-] =
    K b x [ NH 4 OH ]
    [H+] = 106 x 101 [OH-] = 105 x 2 x 101
    [H+] = 10-3,5 [OH-] = 1,14 x 10-4
    pH = -log H+ pOH = - log [OH-]
    pH = - log 10-3,5 pOH = - log 1,14 x 10-4
    pH = 3,5 pOH = 4 log 1,14 pH = 10 +
    log 1,14

    c. pH setelah dicampur
    CH3COOH(aq) + NH4OH(aq) NH4CH3COO(aq) + H2O(l)
    m 10 20 0 0
    r 10 10 10 10
    s 0 10 10 10
    [OH-]1 = Kb. M [OH-]2 =
    Kw x Kb
    Ka

    10 x 105
    14
    10
    = 105 =
    200 10
    6

    = 50. 108 = 10 x 1014


    = 7.07 x 10-4 = 3.16 x 10-7
    [OH-] total = [OH-]1 + [OH-]2
    = 7.07 x 10-4 + 3.16 x 10-7
    = 7073.16 x 10-7
    pOH = - log [OH-]
    = - log (7073.16 x 10-7)
    = 7 log 7073.16
    pH = 7 + log 7073.16
    = 7 + 3.8496
    = 10.8496

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