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Decarburization: From Wikipedia, The Free Encyclopedia
Decarburization: From Wikipedia, The Free Encyclopedia
Decarburization: From Wikipedia, The Free Encyclopedia
FromWikipedia,thefreeencyclopedia
Decarburization(ordecarbonization)istheprocessoppositetocarburization,namelythereductionofcarbon
content.
Thetermistypicallyusedinmetallurgy,describingthereductionofthecontentofcarboninmetals(usually
steel).Decarburizationoccurswhenthemetalisheatedtotemperaturesof700Corabovewhencarboninthe
metalreactswithgasescontainingoxygenorhydrogen.[1]Theremovalofcarbonremoveshardcarbidephases
resultinginasofteningofthemetal,primarilyatthesurfacewhichareincontactwiththedecarburizinggas.
Decarburizationcanbeeitheradvantageousordetrimental,dependingontheapplicationforwhichthemetal
willbeused.Itisthusbothsomethingthatcanbedoneintentionallyasastepinamanufacturingprocess,or
somethingthathappensasasideeffectofaprocess(suchasrolling)andmustbeeitherpreventedorlater
reversed(suchasviaacarburizationstep).
Thedecarburizationmechanismcanbedescribedasthreedistinctevents:thereactionatthesteelsurface,the
interstitialdiffusionofcarbonatomsandthedissolutionofcarbideswithinthesteel.[2]
Contents
1 Chemicalreactions
2 Electricalsteel
3 Stainlesssteel
4 Asasecondaryeffect
5 Seealso
6 References
7 Externallinks
Chemicalreactions
Themostcommonreactionsare:
alsocalledtheBoudouardreaction
Otherreactionsare[1]
Electricalsteel
Electricalsteelisonematerialthatusesdecarburizationinitsproduction.Topreventtheatmosphericgases
fromreactingwiththemetalitself,electricalsteelisannealedinanatmosphereofnitrogen,hydrogen,and
watervapor,whereoxidationoftheironisspecificallypreventedbytheproportionsofhydrogenandwater
vaporsothattheonlyreactingsubstanceiscarbonbeingmadeintocarbonmonoxide.[1]
Stainlesssteel
Becausethecomponents(likechromiumandmolybdenum)ofsomestainlesssteelsareveryoxidizable,these
steelscanonlybedecarburizedbyreactingwithdryhydrogen,whichhasnowatercontent,unlikewet
hydrogen,whichisproducedinawaythatincludessomewaterandcanotherwisebeusedfor
decarburization.[1]
Asasecondaryeffect
Incidentaldecarburizationcanbedetrimentaltosurfacepropertiesinproducts(wherecarboncontentis
desirable)whendoneduringheattreatmentorafterrollingorforging,becausethematerialisonlyaffectedtoa
certaindepthaccordingtothetemperatureanddurationofheating.[1]Thiscanbepreventedbyusinganinertor
reducedpressureatmosphere,applyingresistiveheatingforashortduration,bylimitingthetimethatmaterial
isunderhighheat,asisdoneinawalkingbeamfurnace,orthroughrestorativecarburization,whichusesa
hydrocarbonatmospheretotransfercarbonintothesurfaceofthematerialduringannealing.[1]The
decarburizedsurfacematerialcanalsoberemovedusingagrindingmachine.[1]
Seealso
Historyofferrousmetallurgy
Steelmaking
References
1.Shvartsman,L.A.(1973)."Decarburization".TheGreatSovietEncyclopedia(Print)(3rded.).NewYork:Macmillan.
AvailableinEnglishhere(http://encyclopedia2.thefreedictionary.com/Decarburization)andintheoriginalRussian
here.(http://slovari.yandex.ru/%D0%BE%D0%B1%D0%B5%D0%B7%D1%83%D0%B3%D0%BB%D0%B5%D1%
80%D0%BE%D0%B6%D0%B8%D0%B2%D0%B0%D0%BD%D0%B8%D1%8F/%D0%91%D0%A1%D0%AD/%D
0%9E%D0%B1%D0%B5%D0%B7%D1%83%D0%B3%D0%BB%D0%B5%D1%80%D0%BE%D0%B6%D0%B8%
D0%B2%D0%B0%D0%BD%D0%B8%D0%B5)
2.AlvarengaHD,VandePutteT,VanSteenbergeN,SietsmaJ,TerrynH(Apr2009)."InfluenceofCarbide
MorphologyandMicrostructureontheKineticsofSuperficialDecarburizationofCMnSteels".MetalMaterTrans
A.doi:10.1007/s116610142600y.
Externallinks
ProtectingAgainstDecarburizationwithCressFurnaces(http://www.epsovens.com/heattreatheadlines/
protectingagainstdecarburizationwithcressfurnaces/19)
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