ORG./INO.

CHEMISTRY

TARGET : JEE (Main) 2017

Course : AADHAAR(EB) NO. 10

This DPP is to be discussed in the week (20-07-2015 to 25-07-2015)

DPP No. # 10
Total Marks : 72 Max. Time : 48 min.
Single choice Objective ('1' negative marking) Q.1 to Q.24 (3 marks, 2 min.) [72, 48]

1. The electronegativity of H and Cl are 2.1 and 3.0 respectively. The correct statement about the nature of
HCl is:
(1*) 17% ionic (2) 83% ionic (3) 50% ionic (4) 100% ionic
H rFkk Cl ijek.kq dh fo|qr_.krk e'k% 2.1 rFkk 3.0 gSA HCl dh izd`fr ds fy, lgh dFku gS :
(1*) 17% vk;fud (2) 83% vk;fud (3) 50% vk;fud (4) 100% vk;fud
Sol. % ionic character = 16(XA XB) + 3.5 (XA XB)2
(% vk;fud y{k.k) = 16(3.0 2.1) + 3.5 (3.0 2.1)2
= 17.235
= 17%
2. Among the following oxides, the least acidic is :
fuEu esa ls dkSu lk vkWDlkbM fuEure vEyh; gS %
(1) P4O6 (2) P4O10 (3*) As4O6 (4) As4O10
Sol. Down the group non-metalic character decreases & by increase of oxidation number acidic charaeter of
oxide increases.
oxZ esa uhps dh vksj tkus ij]vkkfRod izdf` r ?kVrh gS rFkk vkWDlhdj.k voLFkk c<+us ds dkj.k] vkWDlkbMksa dh vEyh; izdf` r c<+rh
gSA

3. Which of the following statement is incorrect ?

(1) Oxide of aluminium (Al2O3), and arsenic (As2O3) are amphoteric.
(2*) Oxide of chlorine (Cl2O7) is less acidic than oxide of nitrogen (N2O5).
(3) Oxide of carbon (CO2) is more acidic than oxide of silica (SiO2).
(4) The correct increasing order of basic character of various oxides is H2O < CuO < MgO < CaO.
fuEu esa ls dkSulk dFku lR; ugha gSa \
(1) ,sY;qfefu;e (Al2O3) rFkk vklsZfud (As2O3) ds vkWDlkbM mHk;/kehZ izd`fr ds gksrs gSA
(2*) Dyksjhu ds vkWDlkbM (Cl2O7) ukbVkstu ds vkWDlkbM (N2O5) dh rqyuk esa de vEyh; gksrs gSA
(3) dkcZu ds vkWDlkbM (CO2) flfydkWu ds vkWDlkbM (SiO2) dh vis{kk T;knk vEyh; gksrs gSA
(4) fofHkUu izdkj ds vkWDlkbMksa ds {kkjh; xq.k/keZ dk c<+rk gqvk lgh e H2O < CuO < MgO < CaO gSA
7 5
Sol. (2) Cl2 O7 having higher oxidation state is more acidic than N2 O5 having lower oxidation state.

4. Which of the following is the INCORRECT order of acidic strength :

fuEu esa ls fdlesa] vEyh; lkeF;Z dk e xyr gS %
(1) H2O < H2S < H2Se < H2Te (2) HIO4 < HBrO4 < HClO4
(3) HNO2 < HNO3 (4*) HI < HBr < HCl < HF
Sol. (4) HI > HBr > HCl > HF

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5. The chemical name of NaAlO2 is -
(1) Sodium Aluminite (2*) Sodium Metaaluminate
(3) Sodium pyroaluminate (4) Sodium hypoaluminate
NaAlO2 dk jklk;fud uke gS %
(1) lksfM;e ,Y;wfeukbV (2*) lksfM;e esVk,Y;wfeusV
(3) lksfM;e ik;jks,Y;wfeusV (4) lksfM;e gk;iks,Y;wfeusV

6. The chemical name of K2ZnO2 is -

(1*) Potassium zincate (2) Potassium metazincate
(3) Potassium zincite (4) Potassium zincide
K2ZnO2dk jklk;fud uke gS %
(1*) iksVsf'k;e ftadsV (2) iksVsf'k;e esVkftadsV
(3) iksVsf'k;e ftadkbV (4) iksVsf'k;e ftadkbM

7. The chemical name of Rb2Cr2O7 is -

(1) Rubidium chromate (2*) Rubidium dichromate
(3) Rubidium chromite (4) Rubidium dichromite
Rb2Cr2O7 dk jklk;fud uke gS %
(1) :fcMh;e ksesV (2*) :fcMh;e MkbZksesV
(3) :fcMh;e ksekbV (4) :fcMh;e MkbZksekbV

8. The chemical name of Mg(ClO3)2 is :

(1) Magnesium chlorite (2) Magnesium perchlorate
(3*) Magnesium chlorate (4) Magnesium chloride
Mg(ClO3)2 dk jklk;fud uke gS %
(1) esXuhf'k;e DyksjkbV (2) esXuhf'k;e ijDyksjsV
(3*) esXuhf'k;e DyksjsV (4) esXuhf'k;e DyksjkbM

9. The chemical name of Ca(ClO2)2 is :

(1) Calcium chloride (2*) Calcium chlorite (3) Calcium chlorate (4) Calcium perchlorate
Ca(ClO2) dk jklk;fud uke gS %
(1) dSfY'k;e DyksjkbM (2*) dSfY'k;e DyksjkbV (3) dSfY'k;e DyksjsV (4) dSfY'k;e ijDyksjsV

10. The chemical name of BaCrO4 is -

(1) Barium metachromite (2) Barium chromite
(3) Barium dichromate (4*) Barium chromate
BaCrO4 dk jklk;fud uke gS %
(1) csfj;e esVkksekbV (2) csfj;e ksekbV (3) csfj;e MkbZksekbV (4*)csfj;e ksesV
11. In third row of periodic table the atomic radii from Na to CI
(1*) Continuously decreases (2) Continuously increases
(3) Remains constant (4) Increases but not continuously
vkorZ lkj.kh dh r`rh; iaf esa ijek.kq f=kT;k;sa Na ls CI rd&
(1*) yxkrkj de gksrh gSa (2) yxkrkj c<+rh gSA
(3) fLFkj jgrh gSA (4) c<+rh gS] ysfdu yxkrkj ugha

12. Which statement is correct

(1) For potassium, the atomic radius < ionic radius ; but for bromine, the atomic radius > ionic radius
(2) For potassium and bromine both, the atomic radii > ionic radii
(3) For potassium and bromine both, the atomic radii < ionic radii
(4*) For potassium, the atomic radius > ionic radius but for bromine, the atomic radius < ionic radius
lgh dFku dkSulk gS
(1) iksVsf'k;e ds fy,, ijek.kq f=kT;k < vk;fud f=kT;k ijUrq czksehu ds fy, ijek.kq f=kT;k > vk;fud f=kT;k
(2) iksVsf'k;e vkSj czksehu nksuksa ds fy;s ijek.kq f=kT;k > vk;fud f=kT;k
(3) iksVsf'k;e vkSj czksehu nksuksa ds fy;s ijek.kq f=kT;k < vk;fud f=kT;k
(4*) iksVsf'k;e ds fy,, ijek.kq f=kT;k > vk;fud f=kT;k ijUrq czksehu ds fy, ijek.kq f=kT;k < vk;fud f=kT;k
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13. The correct order of radii is
f=kT;k dk lgh e gS %
(1) N <Be < B (2*) F <O2 < N3 (3) Na < Li < K (4) Fe3+ < Fe2+< Fe4+

14. Radius of the isoelectronic species

(1) Increases with the increase of nuclear charge. (2*) Decreases with the increase of nuclear charge.
(3) Is the same for all (4) First increases and then decreases
lebysDVkWfud tkfr;ksa dh f=kT;k&
(1) ukfHkdh; vkos'k ds c<+us ds lkFk c<+rh gSA (2*) ukfHkdh;vkos'k ds c<+us ds lkFk ?kVrh gSA
(3) lHkh ds lkFk leku gksrh gSA (4) igys c<+rh gS rFkk fQj ?kVrh gSA

15. Al3+ has a lower ionic radius than Mg2+ because

(1) Mg atom has less number of neutrons than Al (2*) Al3+ has higher nuclear charge than Mg2+
(3) Their electronegativities are different (4) Al has a lower ionisation potential than Mg atom
Al3+ dh vk;fud f=kT;k Mg2+ ls de gS D;ksafd&
(1) Mg ijek.kq esa Al ijek.kq dh rqyuk esa de U;wVkWu gSa
(2*) Al dk ukfHkdh; vkos'k Mg2+ ls mPp gksrk gS
3+

(3) budh fo|qr _.kkRedrk fHkUu&fHkUu gksrh gS

(4) Al dk vk;uu foHko Mg ijek.kq ls fuEu gksrk gSA

16. When a neutral atom is converted into cation, there is

(1) Decrease in the atomic number (2) An increase in the atomic number
(3*) A decrease in size (4) An increase in size
tc ,d mnklhu ijek.kq /kuk;u esa ifjofrZr gksrk gS rks&
(1) ijek.kq ekad esa deh gksrh gS (2) ijek.kq ekad esa o`f+) gksrh gS
(3*) vkdkj es deh gksrh gS (4) vkdkj es o`f+) gksrh gS

17. Order for Zeff

Zeff dk e gS
(1) Na+ > Mg2+ > O2 > F (2) Na+ > Mg2+ >F >O2
(3) Mg2+ > Na+ > O2 > F (4*) Mg2+ > Na+ >F >O2

18. Ionisation potential is lowest for

(1) Halogens (2) Inert gases (3) Alkaline earth metals (4*) Alkali metals
vk;uu foHko dk eku U;wure gS
(1) gSykstUk dk (2) vf; xSlksa dk (3) {kkjh; e`nk /kkrqvksa dk (4*) {kkj /kkrqvksa dk

19. The ionisation energy of nitrogen is more than that of oxygen because
(1*) Nitrogen has half filled p-orbitals
(2) Nitrogen is left to the oxygen in the same period of the periodic table
(3) Nitrogen contains less number of electrons
(4) Nitrogen is less electronegative
ukbVkstu dh vk;uu tkZ vkWDlhtu dh vk;uu tkZ ls vf/kd gS]D;ksafd
(1*) ukbVkstu esa v/kZ&iwfjr p- d{kd gS
(2) vkorZ lkj.kh esa ukbVkstu ,d gh vkorZ esa vkWDlhtu ds ck;ha vksj gSA
(3) ukbVkstu esa bysDVkWuksa dh la[;k de gS
(4) ukbVkstu de fo|qr&_.kkRed gS

20. The correct order of ionisation energy of C,N, O, F is

C,N, O, F dh vk;uu tkZ dk lgh e gS
(1) F<N<C<O (2) C<N<O<F (3*) C<O<N<F (4) F<O<N<C

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21. Which of the following does not exist at room temparature ?
fuEu esa ls dkSu dejsa ds rki ij vfLrRoghu gS \
(1) SnCl2 (2) SnCl4 (3) PbCl2 (4*) Pb4

22. Which of the following oxides is not amphoteric in nature :

(1) ZnO (2) Al2O3 (3*) MgO (4) SnO
izfr ls dkSulk vkWDlkbM mHk;/kehZ ugha gS %
(1) ZnO (2) Al2O3 (3*) MgO (4) SnO
Sol. MgO is basic in nature.
MgO izfr esa {kkjh; gksrk gSaA

23. The correct order of acidic strength of halogen acids HX is :

(1) HF > HCl > HBr > HI (2*) HI > HBr > HCl > HF
(3) HCl > HF > HBr > HI (4) HI > HBr > HF > HCl
gSykstu vEyksa HX ds fy, vEyh; lkeF;Z dk lgh e fuEu gS %
(1) HF > HCl > HBr > HI (2*) HI > HBr > HCl > HF
(3) HCl > HF > HBr > HI (4) HI > HBr > HF > HCl
Sol. Refer notes.
uksV~l ns[ksaA

24. For elements belonging to the same period, first ionization energy is maximum for :
(1) halogen (2*) inert gas
(3) alkaline earth metal (4) alkali metal
leku vkorZ ls lEcfU/kr rRoksa ds fy,] izFke vk;uu tkZ fuEu esa vf/kdre gksrh gS %
(1) gSykstu esa (2*) vf; xSl esa
(3) {kkjh; e`nk /kkrq esa (4) {kkj /kkrq esa
Sol. Inert gases have stable noble gas configuration. So, they have maximum first ionization energy in a period.
vf; xSlsa LFkk;h mR"V xSl foU;kl j[krh gSaA blfy,] ,d vkorZ esa izFke vk;uu tkZ vf/kdre j[krk gSA

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