(Scrubbing)

(Chemical Scrubbing Process)

(Ammonia) (Trimethylamine)
(Acid Solution)
(Hydrogen
Sulfide) (Methyl Mercaptan)
(Alkaline Solution)

(Cross-Flow)

(Packings)

(Venturi)

1.


Amine
5%
Amine

2. 0.9-1.22

0.2-0.25
1

3. 21.1-
42.2 /
63.34-84.46 /

 25
th
US EPA, EPA Air Pollution Cost Control Manual, 6 Ed US
EPA,Research Triangle Park, NC,USA, January 2002
 26 Three Bed Cross Flow Packed Tower

27 Countercurrent Packed Tower

1.

2.
 3.

4.

1.

Gm (y1-y2) = Lm (x2-x1)
Gm (/ )
Lm (
/ )
Y1 = 1,000
ppm 0.001
Y2 = 10 ppm
0.00001

X2 =

Solubility

X1
0.0018
1 1,000/. 18 = 1,000/18 = 55.5
0.1 (1.7 )
X1 = 0.1/55.5 = 0.0018
 X1 = X1

0 X2 0

X2 = 0.000

Gm(0.001-0.00001) = Lm (0.0018 - 0)
Gm/Lm = 0.0018/0.00099 ~ 1.8

1.8 ( /)

Actual Operating Line

 28

2.

10

10 ./ 10 ./ (
1 . 1 . 2.2 1 .) 1
29

10 ./ = 10,000/29 = 341 /
 1,000 ppm
= 341 x 1000 x 10^- 6 = 0.341 / (5.8 /
)
1) Lm = Gm/ 1.8
= 341/1.8 190 / = 190 x 18 = 3,420 /
= 3.42 /

3.

Fp = Packing Factor
MW ( L) (G)
= 18 = 29
2
g = 32.2 /
u /-

(Abscissa)

(Ordinate)
G
( /-
) (A)

Gmol,I Molecular Flow Rate

/ Gsfr,i G f
Flooding Factor 0.60-0.75 3600

4.

HCl () H2O () 0.18-0.34

Cl2 () NaOH () 0.24-0.37
NH3 () H2O () 0.09-0.21
OH () H2O () 0.24-0.39
H2S () NaOH () 0.24-0.39
NH3 () H2SO4 () 0.9-0.16

1 Transfer Unit
Transfer Unit
Transfer Unit NTU NTU

y1 = 1,000 ppm
0.001
y 0 = 10 ppm
0.00001

Lmol,i Gmol,i Molecular Flow Rate

/
m 0 NTU ln y1/y 0

= NTU x 1 Transfer Unit

0.5-1
1

15 Packing Factors
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