D. Gevaa/ Chemistry 26.

1 Page | 1
(2017)

CALCULATIONS
1. molarity of the standard HCl solution and report it as M M

Trial 1

Vinitial HCl = (0 0.05) mL V = 0.052+ 0.052=0.0707106 7812 0.07 mL

Vfinal HCl = (38.6 0.05) mL
Vnet HCl = 38.6 mL
2 mol HCl
mole HCl x 0.1012 g Na2 CO3 x 0.999
x g Na2 CO 3 x purity 1 mol Na 2 CO 3
MHCl = mole Na2 CO 3 = =
g
mL HCl x MW of Na 2 CO3 0.0386 L x 105.988 Na 2 CO 3
mole
0.04942332899 = 0.04942 M

( 0.0002 2 0.07 2
M = 0.04942332899 M HCl x
0.1012 )( )
+
38.6
= 1.325649373 x 10-4

0.0001 M

M HCl M HCl =( 0.04942 0. 0001 ) M HCl

Trial 2

Vinitial HCl = (0 0.05) mL V = 0.052+ 0.052=0.0707106 7812 0.07 mL

Vfinal HCl = (38.3 0.05) mL
Vnet HCl = 38.3 mL

2 mol HCl
mole HCl x 0.1010 g Na2 CO3 x 0.999
x g Na2 CO 3 x purity 1 mol Na 2 CO 3
MHCl = mole Na2 CO 3 = =
g
mL HCl x MW of Na 2 CO3 0.0386 L x 105.988 Na2 CO 3
mole
0.04932565442 = 0.04933 M

( 0.0002 2 0.07 2
M = 0.04932565442 M HCl x
0.1010 )( )
+
38.3
= 1.329194568 x 10-4

0.0001 M

M HCl M HCl =( 0.0493 3 0. 0001 ) M HCl

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0.049 42332899+0.049 32565442

Ave. MHCl = = 0.04937449171 M
2
M = (0.0001 325649373)2 +(0.0001329194568)2 = 1.877259827 x 10-4
0.0002 M

Ave. M HCl M HCl = 0.04937 0.000 2 M HCl

2. percentage composition of the sample and report it as %A A

Trial 1
a. Na2CO3

Vinitial HCl = (0 0.05) mL

Vfinal HCl = (16.1 0.05) mL

Vnet HCl (phenolphthalein endpoint) = 16.1 mL

V = 0.052+ 0.052=0.07071067812 0.07 mL

Vph = (16.1 0.07) mL = (0.0161 0.00007)L

Ave M HCl x V pH x MW of Na2 CO3 g Na 2 CO3

%A = =
g of soda ash g of soda ash
g
0.04937449171 M x 0.0161 L x 1 05.988 Na CO 3
mole 2
0.5003 g of soda ash

A=0.0842529684 g x
( 0.0002 2 0.00007 2
0.04937)(+
0.0161 )
=0.0005006820266 0.00050 g

A A=( 0. 08425 0.0005 ) g

g
0.04937449171 M x 0.0161 L x 1 05.988 Na CO 3
%A = mole 2 = 0.1684048939 = 16.84 %
0.5003 g of soda ash
%A + A = 16.84 % 0.0005
b. NaHCO3

Vinitial HCl = (16.1 0.05) mL

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Vfinal HCl = (42.3 0.05) mL

Vnet HCl (methyl orange endpoint) = 26.2 mL

V = 0.052+ 0.052=0.07071067812 0.07 mL

Vmo = (26.2 0.07) mL = (0.0262 0.00007) L

VHCl = Vmo - VpH = 26.2 mL 16.1 mL = 10.1 mL = 0.0101 L

V = 0.072 +0.072 =0.0 9899494937 0.10 mL

VHCl = (10.1 0.10) mL = (0.0101 0.0001) L

Ave M HCl x V pH x MW of NaH CO3 g NaH CO3

%A = =
g of soda ash g of soda ash
g
0.04937449171 M x 0.01 01 L x 84.008 NaH CO 3
mole
0.5003 g of soda ash

A=0.0 4189330823 g x
( 0.0002 2 0.0001 2
0.04937 ) (
+
0.0101) =0.000 4481615934 0.0004 g

A A=( 0. 0 4189 0. 000 4 ) g

g
0.04937449171 M x 0.0161 L x 1 05.988 Na CO 3
%A = mole 2 = 0. 08373637463 = 8.37
0.5003 g of soda ash
%
%A + A = 8.37 % 0.000 4

Trial 2

a. Na2CO3

Vinitial HCl = (0 0.05) mL

Vfinal HCl = (16.1 0.05) mL

Vnet HCl (phenolphthalein endpoint) = 16.1 mL

V = 0.052+ 0.052=0.07071067812 0.07 mL

Vph = (16.1 0.07) mL = (0.0161 0.00007)L
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Ave M HCl x V pH x MW of Na2 CO3 g Na 2 CO3

%A = =
g of soda ash g of soda ash
g
0.04937449171 M x 0.0161 L x 1 05.988 Na CO 3
mole 2
0.5003 g of soda ash

A=0.0842529684 g x
( 0.0002 2 0.00007 2
0.04937 )(
+
0.0161 )
=0.0005006820266 0.00050 g

A A=( 0. 08425 0.0005 ) g

g
0.04937449171 M x 0.0161 L x 1 05.988 Na CO 3
%A = mole 2 = 0.1684048939 = 16.84 %
0.5003 g of soda ash
%A + A = 16.84 % 0.0005
b. NaHCO3

Vinitial HCl = (16.1 0.05) mL

Vfinal HCl = (41.7 0.05) mL

Vnet HCl (methyl orange endpoint) = 25.6 mL

V = 0.052+ 0.052=0.07071067812 0.07 mL

Vmo = (25.6 0.07) mL = (0.0256 0.00007) L

VHCl = Vmo - VpH = 25.6 mL 16.1 mL = 9.5 mL = 0.0095 L

V = 0.072 +0.072 =0.0 9899494937 0.10 mL

VHCl = (9.5 0.10) mL = (0.0095 0.0001) L

Ave M HCl x V pH x MW of NaH CO3 g NaH CO3

%A = =
g of soda ash g of soda ash
g
0.04937449171 M x 0. 0095 L x 84.008 NaH CO3
mole
0.5003 g of soda ash

A=0.0 3940459685 g x
( 0.0002 2 0.0001 2
0.04937)(+
0.0095 )
=0.000 44 44417117 0.0004 g

A A=( 0. 0 3094 0. 0004 ) g

g
0.04937449171 M x 0.0161 L x 1 05.988 Na CO 3
%A = mole 2 = 0. 07876193653 = 7.88
0.5003 g of soda ash
%
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%A + A = 7.88 % 0.000 4

16.84 +16.84
Average of % Na2CO3 = =16.84
2

8.37 +7.88
Average of % NaHCO3 = =8.125
2
3. Relative standard deviation (in ppt) and confidence limits (95%
confidence level)

16.8416.84 2

21
SD, Na2CO3 =
16.84 16.84 2+

RSD= 0 ppt

ts (12.7)(0)
CL= x = 16.84 % = 16.84 %
n 2

Interval: 4.36790214 4.241289226

7.888.125 2

21
SD, NaHCO3 =
8.37 8.125 2+ .3464823228

0.3464823228
RSD= 1000 ppt = 42.64397819 ppt
8.125

ts ( 12.7)(0.3464823228)
CL= x = 8.125 % = 8.125 % 3.1115
n 2

Interval: 5.0135 11.2365

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