Professional Documents
Culture Documents
Class Xii Solution 3
Class Xii Solution 3
Class Xii Solution 3
Vapour pressure
1. At 300 K the vapour pressure of an ideal solution containing one mole of A and 3 moles of B is 550 mm of Hg.At
the same temperature , if one mole of B is added to this solution , the vapour pressure of solution increases by 10
mm of Hg. Calculate the V.P. of A and B in their pure state. ( 400,600 mm )
2.The vapour pressure of pure water at 250C is 23.62 mm. What will be the vapour pressure of a solution of 1.5 g
of urea in 50 g of water ? ( 23.41 mm )
3.What weight of solute ( m wt 60 ) is required to dissolve in 180 g of water to reduce the vapour pressure to 4/5 th
of pure water ? (150 g )
4.At 500C the vapour pressure of pure water and ethyl alcohol are 92.5 and 219.9 mm of Hg respectively. If 6 g
of non-volatile solute of m wt 120 are dissolved in 150 g of each of these solvent , what will be the ratio of relative
lowering in two solvents ? ( 0.3949 )
5.What wt of non-volatile solute urea needs to be dissolved in 100 g of water in order to decrease the vapour
pressure of water by 25% ? What will be the molality of solution ? ( 111.11 g , 18.52 m )
Important questions
1.Give one example each for (a) gas in liquid type solution (b) solid solution
2.Methanol and water are completely miscible but water and benzene are immisible . Explain.
3.Why do we prefer molality over molarity ?
4.Why does the molality of the solution remains unchanged with temperature ?
5.State Henrys law with mathematical form .
6.List the factors on which the Henrys law constant depends .
7.How does the temperature affect the solubility of a gas in liquid ?
8.Why are the aquatic species more comfortable in cold water rather than warm water ?
9.What do you mean by vapour pressure of liquid ?
10. What are the factors on which the vapour pressure of a liquid depends ?
11.Two liquids X and Y boil at 1100C and 1400C respectively. Which of them has higher vapour pressure at 50 0C ?
12.State Raoults law for a solution containing two miscible volatile liquids.
13.State Raoults law for a solution in which the solvent alone is volatile .
14.How is relative lowering of vapour pressure is related to molefraction of solute ?
15.State the conditions under which the Raoults law holds good.
16.What are ideal liquid solutions ?
17. Draw a labelled diagram to express the relationships at constant temperature between vapour pressure and mole fraction of ideal solutions .
18. Which of the mixture containing the following pairs is / are expected to obey Raoults law (i) n-hexane n-heptane (ii) chloroform acetone
19.When does a solution deviate from ideal behaviour ?
20.What type of nonidealities exhibited by (i) acetic acid pyridine (ii) Cyclohexanol-water mixture ?
21. Give an example of a solution where A-B interaction is greater than A-A or B-B interaction.
22.When two liquids X and Y are mixed the solution becomes hot . When pair of liquids Y and z are mixed , the solution becomes cold. Which of
these solutions will exhibit negative deviations from Raoults law ?
23. Why do gases nearly always tend to be less soluble in liquids as the temperature is raised ?
24.Why is the vapour pressure of a solvent lowered by the addition of non-volatile solute ?
25.What happens to the vapour pressure of a liquid when (i) volatile solute dissolves in it (ii) a non-volatile solute dissolves in it .
26.Why do some solutions show positive deviations from ideal behaviour ? Illustrate your answer with diagram.
27.With the help of suitable diagrams , illustrate the two types of nonideal solution..
Set-2
1-a , 2-a , 3-b , 4-d , 5-c , 6-b , 7-d , 8-c , 9-d ,10-a , 11-a , 12-a , 13-d , 14-a , 15-b
Set-3
1-b, 2-a , 3-d , 4-a , 5-d , 6-a , 7-b , 8-a , 9-a , 10-b
Set-4
1-d , 2-b , 3-a , 4-c , 5-a , 6-b , 7-b , 8-c , 9-d , 10-c
Set-5
1-c , 2-b , 3-d, 4-a , 5-a , 6-d , 7-c , 8-c , 9-b , 10-d
Set-6
1-d , 2-d , 3-b , 4-d , 5-a , 6-d , 7-b , 8-a , 9-d , 10-c
Set-7
1-d , 2-d , 3-d , 4-b , 5-c , 6-b , 7-a , 8-b , 9-c , 10-a
Set-8
1-b , 2-c , 3-c , 4-c , 5-a , 6-a , 7-c , 8-b , 9-a , 10-a
2.
3.
4.
5.
6.
7.
8.
9.
10.
12.
13.
14.
15.
16.
17.
1. A sample of drinking water contains 15 ppm of CHCI 3 (by mass) Express this in % mass.Also find out
the molality of the solution.
2. Concentrated H2SO4 is 49% by mass. Density of the solution is 1.5 g/ cm3. Determine the molality and
molarity of the solution.(Molar mass of H2S04 = 98)
3. Concentated HN03 is 68% by mass. Density of the solution is 1.5 g/ cm3. Calculate the volume of the
solution containing 20 grams of HN03.
4. Na2C03 and NaHC03 mixture containing 1 gram is completely neutralised by 0.1 M HCI. Determine the
volume of HCI needed if the mixture contains equimolar mixture of Na 2C03 and NaHC03.
5. Calulate the molality of 1M solution of NaN0 3.Density of solution is 1.25 g/ cm3. Molar mass of NaN0 3 =
85.
6. Calculate the number of moles of CH 30H in 5 litres of 2 molal solution. Density of the solution is 0.981
g/ cm3
7. Calculate the molality , molarity and mole fraction of KI if the density of 20% (mass/mass) aqueous
solution of KI is 1.2 g/ cm3
8. I f the solubility product of CuS is 6x10-6. Calculate the maximum molarity of CuS in aqueous solution.
9. Calculate the volume of 80% H2SO4 (D= 1.8 g/ cm3) needed to prepare 1 litre of 20% H 2 S04 (D=1.25
g/cm3.)
10. I f the density of lake water is 1.25 g/ cm3 and contains 92 grams of Na+ ion per Kg of water,
determine the molality of Na+ ion in solution.